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Title: A porous, electrically conductive hexa-zirconium( iv ) metal–organic framework

Journal Article · · Chemical Science
DOI: https://doi.org/10.1039/C8SC00961A · OSTI ID:1433741
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [1];  [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [1]
  1. Department of Chemistry, Northwestern University, Evanston, USA
  2. Department of Chemistry, Chemical Theory Center, Minnesota Supercomputing Institute, University of Minnesota, Minneapolis
  3. Department of Chemistry, Northwestern University, Evanston, USA, Department of Chemistry

Electrical conductivity is engendered in a pyrene containing hexa-zirconium( iv ) metal–organic framework by physically encapsulating fullerenes within MOF cavity.

Research Organization:
Univ. of Minnesota, Minneapolis, MN (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division
Grant/Contract Number:
SC0008688
OSTI ID:
1433741
Journal Information:
Chemical Science, Journal Name: Chemical Science Journal Issue: 19 Vol. 9; ISSN 2041-6520; ISSN CSHCBM
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United Kingdom
Language:
English

References (59)

Metal-Organic Frameworks as Cathode Materials for Li-O 2 Batteries journal February 2014
Presence versus Proximity: The Role of Pendant Amines in the Catalytic Hydrolysis of a Nerve Agent Simulant journal January 2018
Hydrogen Storage in Microporous Metal-Organic Frameworks with Exposed Metal Sites journal August 2008
Contrasting Photodynamics between C 60 -Dithiapyrene and C 60 -Pyrene Dyads journal September 2007
EPR Spectroscopy in Polymer Science book January 2011
Charge separated states and singlet oxygen generation of mono and bis adducts of C60 and C70 journal February 2016
Transparent-to-Dark Electrochromic Behavior in Naphthalene-Diimide-Based Mesoporous MOF-74 Analogs journal August 2016
Postsynthetic Tuning of Metal–Organic Frameworks for Targeted Applications journal February 2017
Bias-Switchable Permselectivity and Redox Catalytic Activity of a Ferrocene-Functionalized, Thin-Film Metal–Organic Framework Compound journal February 2015
Computational Prediction of Metal Organic Frameworks Suitable for Molecular Infiltration as a Route to Development of Conductive Materials journal April 2015
Predicting Band Gaps with Hybrid Density Functionals journal October 2016
Electric Transport Properties of Surface-Anchored Metal–Organic Frameworks and the Effect of Ferrocene Loading journal April 2015
Toward Metal–Organic Framework-Based Solar Cells: Enhancing Directional Exciton Transport by Collapsing Three-Dimensional Film Structures journal November 2016
Rendering High Surface Area, Mesoporous Metal–Organic Frameworks Electronically Conductive journal March 2017
Lowering Band Gap of an Electroactive Metal–Organic Framework via Complementary Guest Intercalation journal September 2017
Fe-Porphyrin-Based Metal–Organic Framework Films as High-Surface Concentration, Heterogeneous Catalysts for Electrochemical Reduction of CO 2 journal September 2015
Computational Design of Functionalized Metal–Organic Framework Nodes for Catalysis journal December 2017
Rational Design, Synthesis, Purification, and Activation of Metal−Organic Framework Materials journal August 2010
Zr- and Hf-Based Metal–Organic Frameworks: Tracking Down the Polymorphism journal February 2013
Synthesis and Stability of Tagged UiO-66 Zr-MOFs journal December 2010
Metal–Organic Framework Thin Films Composed of Free-Standing Acicular Nanorods Exhibiting Reversible Electrochromism journal December 2013
Computation-Ready, Experimental Metal–Organic Frameworks: A Tool To Enable High-Throughput Screening of Nanoporous Crystals journal October 2014
Metal–Organic Framework Materials as Chemical Sensors journal September 2011
Metal–Organic Frameworks for Light Harvesting and Photocatalysis journal November 2012
Metal Organic Framework Catalysis: Quo vadis ? journal December 2013
Energy Transfer Dynamics in Metal−Organic Frameworks journal September 2010
Mn 2 (2,5-disulfhydrylbenzene-1,4-dicarboxylate): A Microporous Metal–Organic Framework with Infinite (−Mn–S−) Chains and High Intrinsic Charge Mobility journal May 2013
Solvothermal Preparation of an Electrocatalytic Metalloporphyrin MOF Thin Film and its Redox Hopping Charge-Transfer Mechanism journal January 2014
High Electrical Conductivity in Ni 3 (2,3,6,7,10,11-hexaiminotriphenylene) 2 , a Semiconducting Metal–Organic Graphene Analogue journal April 2014
Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks journal January 2015
Concentration Dependent Dimensionality of Resonance Energy Transfer in a Postsynthetically Doped Morphologically Homologous Analogue of UiO-67 MOF with a Ruthenium(II) Polypyridyl Complex journal June 2015
Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide journal October 2015
Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks journal October 2015
Nanostructuration of PEDOT in Porous Coordination Polymers for Tunable Porosity and Conductivity journal August 2016
Porous Field-Effect Transistors Based on a Semiconductive Metal–Organic Framework journal November 2016
Ground-State versus Excited-State Interchromophoric Interaction: Topology Dependent Excimer Contribution in Metal–Organic Framework Photophysics journal April 2017
Guest-Induced Emergent Properties in Metal–Organic Frameworks journal March 2015
Supercapacitors of Nanocrystalline Metal–Organic Frameworks journal June 2014
Chemical, thermal and mechanical stabilities of metal–organic frameworks journal February 2016
Computational development of the nanoporous materials genome journal July 2017
A route to high surface area, porosity and inclusion of large molecules in crystals journal February 2004
Large-scale screening of hypothetical metal–organic frameworks journal November 2011
Soft porous crystals journal November 2009
De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities journal September 2010
Porous metal–organic-framework nanoscale carriers as a potential platform for drug delivery and imaging journal December 2009
Conductive MOF electrodes for stable supercapacitors with high areal capacitance journal October 2016
Hybrid porous solids past, present, future journal January 2008
Energy and charge transfer by donor–acceptor pairs confined in a metal–organic framework: a spectroscopic and computational investigation journal January 2014
Controlling charge separation in a novel donor–acceptor metal–organic framework via redox modulation journal January 2014
Zr-based metal–organic frameworks: design, synthesis, structure, and applications journal January 2016
Benchmarking density functional theory predictions of framework structures and properties in a chemically diverse test set of metal–organic frameworks journal January 2015
Modulating the electrical conductivity of metal–organic framework films with intercalated guest π-systems journal January 2016
Exploiting redox activity in metal–organic frameworks: concepts, trends and perspectives journal January 2016
Potential of microporous metal–organic frameworks for separation of hydrocarbon mixtures journal January 2016
Selective gas adsorption and separation in metal–organic frameworks journal January 2009
Metal–organic framework materials as catalysts journal January 2009
Understanding band gaps of solids in generalized Kohn–Sham theory journal March 2017
The Chemistry and Applications of Metal-Organic Frameworks journal August 2013
Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices journal December 2013