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Title: A porous, electrically conductive hexa-zirconium( iv ) metal–organic framework

Electrical conductivity is engendered in a pyrene containing hexa-zirconium( iv ) metal–organic framework by physically encapsulating fullerenes within MOF cavity.
Authors:
ORCiD logo [1] ; ORCiD logo [2] ; ORCiD logo [1] ; ORCiD logo [1] ;  [1] ; ORCiD logo [1] ; ORCiD logo [1] ; ORCiD logo [1] ; ORCiD logo [2] ; ORCiD logo [3] ; ORCiD logo [1]
  1. Department of Chemistry, Northwestern University, Evanston, USA
  2. Department of Chemistry, Chemical Theory Center, Minnesota Supercomputing Institute, University of Minnesota, Minneapolis
  3. Department of Chemistry, Northwestern University, Evanston, USA, Department of Chemistry
Publication Date:
Grant/Contract Number:
FG02-17ER16362
Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 9 Journal Issue: 19; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1433741

Goswami, Subhadip, Ray, Debmalya, Otake, Ken-ichi, Kung, Chung-Wei, Garibay, Sergio J., Islamoglu, Timur, Atilgan, Ahmet, Cui, Yuexing, Cramer, Christopher J., Farha, Omar K., and Hupp, Joseph T.. A porous, electrically conductive hexa-zirconium( iv ) metal–organic framework. United Kingdom: N. p., Web. doi:10.1039/C8SC00961A.
Goswami, Subhadip, Ray, Debmalya, Otake, Ken-ichi, Kung, Chung-Wei, Garibay, Sergio J., Islamoglu, Timur, Atilgan, Ahmet, Cui, Yuexing, Cramer, Christopher J., Farha, Omar K., & Hupp, Joseph T.. A porous, electrically conductive hexa-zirconium( iv ) metal–organic framework. United Kingdom. doi:10.1039/C8SC00961A.
Goswami, Subhadip, Ray, Debmalya, Otake, Ken-ichi, Kung, Chung-Wei, Garibay, Sergio J., Islamoglu, Timur, Atilgan, Ahmet, Cui, Yuexing, Cramer, Christopher J., Farha, Omar K., and Hupp, Joseph T.. 2018. "A porous, electrically conductive hexa-zirconium( iv ) metal–organic framework". United Kingdom. doi:10.1039/C8SC00961A.
@article{osti_1433741,
title = {A porous, electrically conductive hexa-zirconium( iv ) metal–organic framework},
author = {Goswami, Subhadip and Ray, Debmalya and Otake, Ken-ichi and Kung, Chung-Wei and Garibay, Sergio J. and Islamoglu, Timur and Atilgan, Ahmet and Cui, Yuexing and Cramer, Christopher J. and Farha, Omar K. and Hupp, Joseph T.},
abstractNote = {Electrical conductivity is engendered in a pyrene containing hexa-zirconium( iv ) metal–organic framework by physically encapsulating fullerenes within MOF cavity.},
doi = {10.1039/C8SC00961A},
journal = {Chemical Science},
number = 19,
volume = 9,
place = {United Kingdom},
year = {2018},
month = {1}
}

Works referenced in this record:

A route to high surface area, porosity and inclusion of large molecules in crystals
journal, February 2004
  • Chae, Hee K.; Siberio-Pérez, Diana Y.; Kim, Jaheon
  • Nature, Vol. 427, Issue 6974, p. 523-527
  • DOI: 10.1038/nature02311

Metal–organic framework materials as catalysts
journal, January 2009
  • Lee, JeongYong; Farha, Omar K.; Roberts, John
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
  • DOI: 10.1039/b807080f

Rational Design, Synthesis, Purification, and Activation of Metal−Organic Framework Materials
journal, August 2010
  • Farha, Omar K.; Hupp, Joseph T.
  • Accounts of Chemical Research, Vol. 43, Issue 8, p. 1166-1175
  • DOI: 10.1021/ar1000617

Metal Organic Framework Catalysis: Quo vadis ?
journal, December 2013
  • Gascon, Jorge; Corma, Avelino; Kapteijn, Freek
  • ACS Catalysis, Vol. 4, Issue 2, p. 361-378
  • DOI: 10.1021/cs400959k

Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009
  • Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504
  • DOI: 10.1039/b802426j

Hydrogen Storage in Microporous Metal-Organic Frameworks with Exposed Metal Sites
journal, August 2008
  • Dincă, Mircea; Long, Jeffrey R.
  • Angewandte Chemie International Edition, Vol. 47, Issue 36, p. 6766-6779
  • DOI: 10.1002/anie.200801163

Hybrid porous solids past, present, future
journal, January 2008
  • Férey, Gérard
  • Chem. Soc. Rev., Vol. 37, Issue 1, p. 191-214
  • DOI: 10.1039/B618320B

De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities
journal, September 2010
  • Farha, Omar K.; Özgür Yazaydın, A.; Eryazici, Ibrahim
  • Nature Chemistry, Vol. 2, Issue 11, p. 944-948
  • DOI: 10.1038/nchem.834

Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices
journal, December 2013
  • Talin, A. Alec; Centrone, Andrea; Ford, Alexandra C.
  • Science, Vol. 343, Issue 6166, p. 66-69
  • DOI: 10.1126/science.1246738

Metal–Organic Framework Materials as Chemical Sensors
journal, September 2011
  • Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K.
  • Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125
  • DOI: 10.1021/cr200324t

Large-scale screening of hypothetical metal–organic frameworks
journal, November 2011
  • Wilmer, Christopher E.; Leaf, Michael; Lee, Chang Yeon
  • Nature Chemistry, Vol. 4, Issue 2, p. 83-89
  • DOI: 10.1038/nchem.1192

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013
  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444

Zr- and Hf-Based Metal–Organic Frameworks: Tracking Down the Polymorphism
journal, February 2013
  • Bon, Volodymyr; Senkovska, Irena; Baburin, Igor A.
  • Crystal Growth & Design, Vol. 13, Issue 3, p. 1231-1237
  • DOI: 10.1021/cg301691d

Soft porous crystals
journal, November 2009
  • Horike, Satoshi; Shimomura, Satoru; Kitagawa, Susumu
  • Nature Chemistry, Vol. 1, Issue 9, p. 695-704
  • DOI: 10.1038/nchem.444