Robust, Transformable, and Crystalline Single-Node Organometallic Networks Constructed from Ditopic m -Terphenyl Isocyanides
Abstract
Here, the preparation of 3D and 2D Cu(I) coordination networks using ditopic m-terphenyl isocyanides is described. The incorporation of sterically encumbering substituents enables the controlled, solid-state preparation of Cu(I) tris-isocyanide nodes with a labile solvent ligand in a manner mirroring solution-phase chemistry of monomeric complexes. The protection afforded by the m-terphenyl groups is also shown to engender significant stability towards heat as well as acidic or basic conditions, resulting in robust single-metal-node networks that can transition from 3D to 2D extended structures.
- Authors:
-
- Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, Mail Code 0358, La Jolla, California 92093, United States
- Publication Date:
- Research Org.:
- Univ. of California, San Diego, La Jolla, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1331227
- Alternate Identifier(s):
- OSTI ID: 1334169
- Grant/Contract Number:
- SC0008058
- Resource Type:
- Published Article
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Name: Journal of the American Chemical Society Journal Volume: 138 Journal Issue: 46; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Agnew, Douglas W., Gembicky, Milan, Moore, Curtis E., Rheingold, Arnold L., and Figueroa, Joshua S. Robust, Transformable, and Crystalline Single-Node Organometallic Networks Constructed from Ditopic m -Terphenyl Isocyanides. United States: N. p., 2016.
Web. doi:10.1021/jacs.6b10460.
Agnew, Douglas W., Gembicky, Milan, Moore, Curtis E., Rheingold, Arnold L., & Figueroa, Joshua S. Robust, Transformable, and Crystalline Single-Node Organometallic Networks Constructed from Ditopic m -Terphenyl Isocyanides. United States. https://doi.org/10.1021/jacs.6b10460
Agnew, Douglas W., Gembicky, Milan, Moore, Curtis E., Rheingold, Arnold L., and Figueroa, Joshua S. Tue .
"Robust, Transformable, and Crystalline Single-Node Organometallic Networks Constructed from Ditopic m -Terphenyl Isocyanides". United States. https://doi.org/10.1021/jacs.6b10460.
@article{osti_1331227,
title = {Robust, Transformable, and Crystalline Single-Node Organometallic Networks Constructed from Ditopic m -Terphenyl Isocyanides},
author = {Agnew, Douglas W. and Gembicky, Milan and Moore, Curtis E. and Rheingold, Arnold L. and Figueroa, Joshua S.},
abstractNote = {Here, the preparation of 3D and 2D Cu(I) coordination networks using ditopic m-terphenyl isocyanides is described. The incorporation of sterically encumbering substituents enables the controlled, solid-state preparation of Cu(I) tris-isocyanide nodes with a labile solvent ligand in a manner mirroring solution-phase chemistry of monomeric complexes. The protection afforded by the m-terphenyl groups is also shown to engender significant stability towards heat as well as acidic or basic conditions, resulting in robust single-metal-node networks that can transition from 3D to 2D extended structures.},
doi = {10.1021/jacs.6b10460},
journal = {Journal of the American Chemical Society},
number = 46,
volume = 138,
place = {United States},
year = {Tue Nov 08 00:00:00 EST 2016},
month = {Tue Nov 08 00:00:00 EST 2016}
}
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https://doi.org/10.1021/jacs.6b10460
https://doi.org/10.1021/jacs.6b10460
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Cited by: 12 works
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Works referencing / citing this record:
CCDC 1521778: Experimental Crystal Structure Determination: HAJQOB : 4,4'-bis(isocyano)-3,3',5,5'-tetramesitylbiphenyl diethyl ether solvate
dataset, December 2016
- Agnew, Douglas; Gembický, Milan; Moore, Curtis
- Cambridge Structural Database (CSD)
CCDC 1521779: Experimental Crystal Structure Determination: catena-[tris(μ-4,4'-bis(isocyano)-3,3',5,5'-tetramesitylbiphenyl)-bis(tetrahydrofuran)-di-copper(i) bis(hexafluorophosphate) tetrahydrofuran solvate]
dataset, September 2016
- Agnew, Douglas W.; Gembicky, Milan; Moore, Curtis E.
- The Cambridge Structural Database (CSD), vp
CCDC 1521780: Experimental Crystal Structure Determination
dataset, September 2016
- Agnew, Douglas W.; Gembický, Milan; Moore, Curtis E.
- Cambridge Crystallographic Data Centre, vp
CCDC 1521781: Experimental Crystal Structure Determination: HAJRES : catena-[bis(μ-4,4'-bis(isocyano)-3,3',5,5'-tetramesitylbiphenyl)-copper(i) hexafluorophosphate tetrahydrofuran solvate]
Space Group: F d d 2 (43), Cell: a 30.4380(14)Å b 44.985(2)Å c 30.3992(14)Å, α 90° β 90° γ 90°
dataset, December 2016
- Agnew, Douglas W.; Gembický, Milan; Moore, Curtis E.
- The Cambridge Crystallographic Data Centre, vp
Comparison of nucleophilic- and radical-based routes to the formation of manganese-main group element single bonds
journal, January 2017
- Agnew, Douglas W.; Moore, Curtis E.; Rheingold, Arnold L.
- Dalton Transactions, Vol. 46, Issue 20
Comparison of nucleophilic- and radical-based routes to the formation of manganese-main group element single bonds
journal, January 2017
- Agnew, Douglas W.; Moore, Curtis E.; Rheingold, Arnold L.
- Dalton Transactions, Vol. 46, Issue 20
A palladium–carbon-connected organometallic framework and its catalytic application
journal, January 2019
- Dong, Ying; Jv, Jing-Jing; Wu, Xiao-Wei
- Chemical Communications, Vol. 55, Issue 96
In situ formation and solid-state oxidation of a triselenane NSeN-pincer MOF
journal, January 2020
- He, Shichao; Allemond, Laynee L.; Dunning, Samuel G.
- Chemical Communications, Vol. 56, Issue 8