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Title: Robust, transformable, and crystalline single-node organometallic networks constructed from ditopic m-terphenyl isocyanides

Abstract

Here, the preparation of 3D and 2D Cu(I) coordination networks using ditopic m-terphenyl isocyanides is described. The incorporation of sterically encumbering substituents enables the controlled, solid-state preparation of Cu(I) tris-isocyanide nodes with a labile solvent ligand in a manner mirroring solution-phase chemistry of monomeric complexes. The protection afforded by the m-terphenyl groups is also shown to engender significant stability towards heat as well as acidic or basic conditions, resulting in robust single-metal-node networks that can transition from 3D to 2D extended structures.

Authors:
 [1];  [1];  [1];  [1];  [1]
  1. Univ. of California, San Diego, La Jolla, CA (United States)
Publication Date:
Research Org.:
Univ. of California, San Diego, La Jolla, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1331227
Alternate Identifier(s):
OSTI ID: 1334169
Grant/Contract Number:  
SC0008058
Resource Type:
Published Article
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 138; Journal Issue: 46; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Agnew, Douglas W., Gembicky, Milan, Moore, Curtis E., Rheingold, Arnold L., and Figueroa, Joshua S. Robust, transformable, and crystalline single-node organometallic networks constructed from ditopic m-terphenyl isocyanides. United States: N. p., 2016. Web. doi:10.1021/jacs.6b10460.
Agnew, Douglas W., Gembicky, Milan, Moore, Curtis E., Rheingold, Arnold L., & Figueroa, Joshua S. Robust, transformable, and crystalline single-node organometallic networks constructed from ditopic m-terphenyl isocyanides. United States. doi:10.1021/jacs.6b10460.
Agnew, Douglas W., Gembicky, Milan, Moore, Curtis E., Rheingold, Arnold L., and Figueroa, Joshua S. Tue . "Robust, transformable, and crystalline single-node organometallic networks constructed from ditopic m-terphenyl isocyanides". United States. doi:10.1021/jacs.6b10460.
@article{osti_1331227,
title = {Robust, transformable, and crystalline single-node organometallic networks constructed from ditopic m-terphenyl isocyanides},
author = {Agnew, Douglas W. and Gembicky, Milan and Moore, Curtis E. and Rheingold, Arnold L. and Figueroa, Joshua S.},
abstractNote = {Here, the preparation of 3D and 2D Cu(I) coordination networks using ditopic m-terphenyl isocyanides is described. The incorporation of sterically encumbering substituents enables the controlled, solid-state preparation of Cu(I) tris-isocyanide nodes with a labile solvent ligand in a manner mirroring solution-phase chemistry of monomeric complexes. The protection afforded by the m-terphenyl groups is also shown to engender significant stability towards heat as well as acidic or basic conditions, resulting in robust single-metal-node networks that can transition from 3D to 2D extended structures.},
doi = {10.1021/jacs.6b10460},
journal = {Journal of the American Chemical Society},
number = 46,
volume = 138,
place = {United States},
year = {2016},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1021/jacs.6b10460

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Cited by: 2 works
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