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Title: Introducing Nonstructural Ligands to Zirconia-like Metal–Organic Framework Nodes To Tune the Activity of Node-Supported Nickel Catalysts for Ethylene Hydrogenation [Introducing Nonstructural Ligands to Zirconia-like MOF Nodes To Tune the Activity of Node-Supported Nickel Catalysts for Ethylene Hydrogenation]

Abstract

Previous work has shown that introduction of hexafluoroacetylacetone (Facac) units as nonstructural ligands for the zirconia-like nodes of the eight-connected metal-organic framework (MOF), NU-1000, greatly alters the selectivity of node-supported oxy-nickel clusters for ethylene dimerization vs oligomerization. Here we i explore a related concept: tuning of support/catalyst interactions, and therefore, catalyst activity, via parallel installation of organic modifiers on the support itself. As modifiers we focused on para-substituted benzoates (R-BA; R = -NH2, -OCH3, -CH3, -H, -F, and -NO2) where the substituents were chosen to present similar steric demand, but varying electron-donating or electron-withdrawing properties. R-benzoate-engendered shifts in the node-based aqua O-H stretching frequency for NU-1000, as measured by DRIFTS (diffuse-reflectance infrared Fourier-transform spectroscopy), together with systematic shifts in Ni 2p peak energies, as measured by X-ray photoelectron spectroscopy, show that the electronic properties of the support can be modulated. The vibrational and electronic peak shifts correlate with the putative electron-withdrawing vs electron-donating strength of the para-substituted benzoate modifiers. Subsequent installation of node-supported, oxy-Ni(II) clusters for ethylene hydrogenation yield a compelling correlation between log (catalyst turnover frequency) and the electron donating or withdrawing character of the substituent of the benzoate units. Single crystal X-ray diffraction measurements reveal that each organicmore » modifier makes use of only one of two available carboxylate oxygens to accomplish grafting. The remaining oxygen atom is, in principle, well positioned to coordinate directly to an installed Ni(II) ion. We postulate that the unanticipated direct coordination of the catalyst by the node-modifier (rather than indirect modifier-based tuning of support(node)/catalyst electronic interactions) is the primary source of the observed systematic tuning of hydrogenation activity. Here we suggest, however, that regardless of mechanism for communication with active-sites of MOF-supported catalysts, intentional elaboration of nodes via grafted, nonstructural organic species could prove to be a valuable general strategy for fine-tuning supported-catalyst activity and/or selectivity.« less

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [1]
  1. Northwestern Univ., Evanston, IL (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. Univ. of New South Wales, Sydney, NSW (Australia)
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC); Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1509897
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
ACS Catalysis
Additional Journal Information:
Journal Volume: 9; Journal Issue: 4; Journal ID: ISSN 2155-5435
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Hammett constant; ethylene hydrogenation; heterogeneous catalysis; ligand modification; metal-organic framework; zirconia-like node

Citation Formats

Liu, Jian, Li, Zhanyong, Zhang, Xuan, Otake, Ken-ichi, Zhang, Lin, Peters, Aaron W., Young, Matthias J., Bedford, Nicholas M., Letourneau, Steven P., Mandia, David J., Elam, Jeffrey W., Farha, Omar K., and Hupp, Joseph T.. Introducing Nonstructural Ligands to Zirconia-like Metal–Organic Framework Nodes To Tune the Activity of Node-Supported Nickel Catalysts for Ethylene Hydrogenation [Introducing Nonstructural Ligands to Zirconia-like MOF Nodes To Tune the Activity of Node-Supported Nickel Catalysts for Ethylene Hydrogenation]. United States: N. p., 2019. Web. https://doi.org/10.1021/acscatal.8b04828.
Liu, Jian, Li, Zhanyong, Zhang, Xuan, Otake, Ken-ichi, Zhang, Lin, Peters, Aaron W., Young, Matthias J., Bedford, Nicholas M., Letourneau, Steven P., Mandia, David J., Elam, Jeffrey W., Farha, Omar K., & Hupp, Joseph T.. Introducing Nonstructural Ligands to Zirconia-like Metal–Organic Framework Nodes To Tune the Activity of Node-Supported Nickel Catalysts for Ethylene Hydrogenation [Introducing Nonstructural Ligands to Zirconia-like MOF Nodes To Tune the Activity of Node-Supported Nickel Catalysts for Ethylene Hydrogenation]. United States. https://doi.org/10.1021/acscatal.8b04828
Liu, Jian, Li, Zhanyong, Zhang, Xuan, Otake, Ken-ichi, Zhang, Lin, Peters, Aaron W., Young, Matthias J., Bedford, Nicholas M., Letourneau, Steven P., Mandia, David J., Elam, Jeffrey W., Farha, Omar K., and Hupp, Joseph T.. Fri . "Introducing Nonstructural Ligands to Zirconia-like Metal–Organic Framework Nodes To Tune the Activity of Node-Supported Nickel Catalysts for Ethylene Hydrogenation [Introducing Nonstructural Ligands to Zirconia-like MOF Nodes To Tune the Activity of Node-Supported Nickel Catalysts for Ethylene Hydrogenation]". United States. https://doi.org/10.1021/acscatal.8b04828. https://www.osti.gov/servlets/purl/1509897.
@article{osti_1509897,
title = {Introducing Nonstructural Ligands to Zirconia-like Metal–Organic Framework Nodes To Tune the Activity of Node-Supported Nickel Catalysts for Ethylene Hydrogenation [Introducing Nonstructural Ligands to Zirconia-like MOF Nodes To Tune the Activity of Node-Supported Nickel Catalysts for Ethylene Hydrogenation]},
author = {Liu, Jian and Li, Zhanyong and Zhang, Xuan and Otake, Ken-ichi and Zhang, Lin and Peters, Aaron W. and Young, Matthias J. and Bedford, Nicholas M. and Letourneau, Steven P. and Mandia, David J. and Elam, Jeffrey W. and Farha, Omar K. and Hupp, Joseph T.},
abstractNote = {Previous work has shown that introduction of hexafluoroacetylacetone (Facac) units as nonstructural ligands for the zirconia-like nodes of the eight-connected metal-organic framework (MOF), NU-1000, greatly alters the selectivity of node-supported oxy-nickel clusters for ethylene dimerization vs oligomerization. Here we i explore a related concept: tuning of support/catalyst interactions, and therefore, catalyst activity, via parallel installation of organic modifiers on the support itself. As modifiers we focused on para-substituted benzoates (R-BA–; R = -NH2, -OCH3, -CH3, -H, -F, and -NO2) where the substituents were chosen to present similar steric demand, but varying electron-donating or electron-withdrawing properties. R-benzoate-engendered shifts in the node-based aqua O-H stretching frequency for NU-1000, as measured by DRIFTS (diffuse-reflectance infrared Fourier-transform spectroscopy), together with systematic shifts in Ni 2p peak energies, as measured by X-ray photoelectron spectroscopy, show that the electronic properties of the support can be modulated. The vibrational and electronic peak shifts correlate with the putative electron-withdrawing vs electron-donating strength of the para-substituted benzoate modifiers. Subsequent installation of node-supported, oxy-Ni(II) clusters for ethylene hydrogenation yield a compelling correlation between log (catalyst turnover frequency) and the electron donating or withdrawing character of the substituent of the benzoate units. Single crystal X-ray diffraction measurements reveal that each organic modifier makes use of only one of two available carboxylate oxygens to accomplish grafting. The remaining oxygen atom is, in principle, well positioned to coordinate directly to an installed Ni(II) ion. We postulate that the unanticipated direct coordination of the catalyst by the node-modifier (rather than indirect modifier-based tuning of support(node)/catalyst electronic interactions) is the primary source of the observed systematic tuning of hydrogenation activity. Here we suggest, however, that regardless of mechanism for communication with active-sites of MOF-supported catalysts, intentional elaboration of nodes via grafted, nonstructural organic species could prove to be a valuable general strategy for fine-tuning supported-catalyst activity and/or selectivity.},
doi = {10.1021/acscatal.8b04828},
journal = {ACS Catalysis},
number = 4,
volume = 9,
place = {United States},
year = {2019},
month = {3}
}

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Works referenced in this record:

A history of industrial catalysis
journal, April 2011


Catalytic control of emissions from cars
journal, April 2011


Atomic layer deposition of Pt@CsH2PO4 for the cathodes of solid acid fuel cells
journal, October 2018


The Rise of Hydrogen Peroxide as the Main Product by Metal‐Free Catalysis in Oxygen Reductions
journal, August 2018

  • Melchionna, Michele; Fornasiero, Paolo; Prato, Maurizio
  • Advanced Materials, Vol. 31, Issue 13
  • DOI: 10.1002/adma.201802920

Nanoscale Engineering of Efficient Oxygen Reduction Electrocatalysts by Tailoring the Local Chemical Environment of Pt Surface Sites
journal, November 2016


Highly Selective Nonoxidative Coupling of Methane over Pt-Bi Bimetallic Catalysts
journal, February 2018


Mild oxidation of methane to methanol or acetic acid on supported isolated rhodium catalysts
journal, November 2017

  • Shan, Junjun; Li, Mengwei; Allard, Lawrence F.
  • Nature, Vol. 551, Issue 7682
  • DOI: 10.1038/nature24640

Viewpoint on the Partial Oxidation of Methane to Methanol Using Cu- and Fe-Exchanged Zeolites
journal, August 2018


Ethene oligomerization on nickel microporous and mesoporous-supported catalysts: Investigation of the active sites
journal, January 2018


Reticular Chemistry—Construction, Properties, and Precision Reactions of Frameworks
journal, November 2016

  • Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 138, Issue 48
  • DOI: 10.1021/jacs.6b11821

Metal–Organic Frameworks as A Tunable Platform for Designing Functional Molecular Materials
journal, August 2013

  • Wang, Cheng; Liu, Demin; Lin, Wenbin
  • Journal of the American Chemical Society, Vol. 135, Issue 36
  • DOI: 10.1021/ja308229p

Introduction to Metal–Organic Frameworks
journal, September 2011

  • Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 673-674
  • DOI: 10.1021/cr300014x

Reticular Chemistry at Its Best: Directed Assembly of Hexagonal Building Units into the Awaited Metal-Organic Framework with the Intricate Polybenzene Topology, pbz-MOF
journal, September 2016

  • Alezi, Dalal; Spanopoulos, Ioannis; Tsangarakis, Constantinos
  • Journal of the American Chemical Society, Vol. 138, Issue 39
  • DOI: 10.1021/jacs.6b08176

Soft porous crystals
journal, November 2009

  • Horike, Satoshi; Shimomura, Satoru; Kitagawa, Susumu
  • Nature Chemistry, Vol. 1, Issue 9, p. 695-704
  • DOI: 10.1038/nchem.444

Zeolite-like metal–organic frameworks (ZMOFs): design, synthesis, and properties
journal, January 2015

  • Eddaoudi, Mohamed; Sava, Dorina F.; Eubank, Jarrod F.
  • Chemical Society Reviews, Vol. 44, Issue 1
  • DOI: 10.1039/C4CS00230J

Hybrid porous solids past, present, future
journal, January 2008

  • Férey, Gérard
  • Chem. Soc. Rev., Vol. 37, Issue 1, p. 191-214
  • DOI: 10.1039/B618320B

A facile synthesis of UiO-66, UiO-67 and their derivatives
journal, January 2013

  • Katz, Michael J.; Brown, Zachary J.; Colón, Yamil J.
  • Chemical Communications, Vol. 49, Issue 82
  • DOI: 10.1039/c3cc46105j

Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012

  • Morris, William; Volosskiy, Boris; Demir, Selcuk
  • Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445
  • DOI: 10.1021/ic300825s

Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination
journal, October 2013

  • Feng, Dawei; Chung, Wan-Chun; Wei, Zhangwen
  • Journal of the American Chemical Society, Vol. 135, Issue 45
  • DOI: 10.1021/ja408084j

A Series of Highly Stable Mesoporous Metalloporphyrin Fe-MOFs
journal, August 2014

  • Wang, Kecheng; Feng, Dawei; Liu, Tian-Fu
  • Journal of the American Chemical Society, Vol. 136, Issue 40
  • DOI: 10.1021/ja507269n

Nanoscale Metal–Organic Framework for Highly Effective Photodynamic Therapy of Resistant Head and Neck Cancer
journal, November 2014

  • Lu, Kuangda; He, Chunbai; Lin, Wenbin
  • Journal of the American Chemical Society, Vol. 136, Issue 48
  • DOI: 10.1021/ja508679h

Metal–organic frameworks with Lewis acidity: synthesis, characterization, and catalytic applications
journal, January 2017


Metal–Organic Frameworks for Heterogeneous Basic Catalysis
journal, May 2017


Stabilized Vanadium Catalyst for Olefin Polymerization by Site Isolation in a Metal–Organic Framework
journal, July 2018

  • Comito, Robert J.; Wu, Zhenwei; Zhang, Guanghui
  • Angewandte Chemie International Edition, Vol. 57, Issue 27
  • DOI: 10.1002/anie.201803642

Effect of Redox “Non-Innocent” Linker on the Catalytic Activity of Copper-Catecholate-Decorated Metal–Organic Frameworks
journal, December 2017

  • Zhang, Xuan; Vermeulen, Nicolaas A.; Huang, Zhiyuan
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 1
  • DOI: 10.1021/acsami.7b15326

CO 2 Hydrogenation over Pt-Containing UiO-67 Zr-MOFs—The Base Case
journal, June 2017

  • Gutterød, Emil Sebastian; Øien-Ødegaard, Sigurd; Bossers, Koen
  • Industrial & Engineering Chemistry Research, Vol. 56, Issue 45
  • DOI: 10.1021/acs.iecr.7b01457

Computational Design of Functionalized Metal–Organic Framework Nodes for Catalysis
journal, December 2017


Size effect of the active sites in UiO-66-supported nickel catalysts synthesized via atomic layer deposition for ethylene hydrogenation
journal, January 2017

  • Li, Zhanyong; Peters, Aaron W.; Liu, Jian
  • Inorganic Chemistry Frontiers, Vol. 4, Issue 5
  • DOI: 10.1039/C7QI00056A

Electrospun metal–organic framework polymer composites for the catalytic degradation of methyl paraoxon
journal, January 2017

  • McCarthy, Danielle L.; Liu, Jian; Dwyer, Derek B.
  • New Journal of Chemistry, Vol. 41, Issue 17
  • DOI: 10.1039/C7NJ00525C

Titration of Zr3(μ-OH) Hydroxy Groups at the Cornerstones of Bulk MOF UiO-67, [Zr6O4(OH)4(biphenyldicarboxylate)6], and Their Reaction with [AuMe(PMe3)]
journal, May 2012

  • Larabi, Cherif; Quadrelli, Elsje Alessandra
  • European Journal of Inorganic Chemistry, Vol. 2012, Issue 18, p. 3014-3022
  • DOI: 10.1002/ejic.201200033

Stable Metal-Organic Frameworks: Design, Synthesis, and Applications
journal, February 2018


Defining the Proton Topology of the Zr6-Based Metal–Organic Framework NU-1000
journal, October 2014

  • Planas, Nora; Mondloch, Joseph E.; Tussupbayev, Samat
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 21, p. 3716-3723
  • DOI: 10.1021/jz501899j

Symmetry-Guided Synthesis of Highly Porous Metal-Organic Frameworks with Fluorite Topology
journal, November 2013

  • Zhang, Muwei; Chen, Ying-Pin; Bosch, Mathieu
  • Angewandte Chemie International Edition, Vol. 53, Issue 3
  • DOI: 10.1002/anie.201307340

Zr- and Hf-Based Metal–Organic Frameworks: Tracking Down the Polymorphism
journal, February 2013

  • Bon, Volodymyr; Senkovska, Irena; Baburin, Igor A.
  • Crystal Growth & Design, Vol. 13, Issue 3, p. 1231-1237
  • DOI: 10.1021/cg301691d

MOF Functionalization via Solvent-Assisted Ligand Incorporation: Phosphonates vs Carboxylates
journal, February 2015

  • Deria, Pravas; Bury, Wojciech; Hod, Idan
  • Inorganic Chemistry, Vol. 54, Issue 5
  • DOI: 10.1021/ic502639v

Electroactive Ferrocene at or near the Surface of Metal–Organic Framework UiO-66
journal, March 2018


Sintering-Resistant Single-Site Nickel Catalyst Supported by Metal–Organic Framework
journal, February 2016

  • Li, Zhanyong; Schweitzer, Neil M.; League, Aaron B.
  • Journal of the American Chemical Society, Vol. 138, Issue 6
  • DOI: 10.1021/jacs.5b12515

Stable Metal–Organic Framework-Supported Niobium Catalysts
journal, October 2016


Toward Inexpensive Photocatalytic Hydrogen Evolution: A Nickel Sulfide Catalyst Supported on a High-Stability Metal–Organic Framework
journal, August 2016

  • Peters, Aaron W.; Li, Zhanyong; Farha, Omar K.
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 32
  • DOI: 10.1021/acsami.6b04729

Stabilizing a Vanadium Oxide Catalyst by Supporting on a Metal-Organic Framework
journal, February 2018

  • Cui, Yuexing; Rimoldi, Martino; Platero-Prats, Ana E.
  • ChemCatChem, Vol. 10, Issue 8
  • DOI: 10.1002/cctc.201701658

Fine-Tuning the Activity of Metal–Organic Framework-Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane
journal, October 2017

  • Li, Zhanyong; Peters, Aaron W.; Platero-Prats, Ana E.
  • Journal of the American Chemical Society, Vol. 139, Issue 42
  • DOI: 10.1021/jacs.7b09365

Cooperative Cluster Metalation and Ligand Migration in Zirconium Metal-Organic Frameworks
journal, October 2015

  • Yuan, Shuai; Chen, Ying-Pin; Qin, Junsheng
  • Angewandte Chemie International Edition, Vol. 54, Issue 49
  • DOI: 10.1002/anie.201505625

Increased Electrical Conductivity in a Mesoporous Metal–Organic Framework Featuring Metallacarboranes Guests
journal, February 2018

  • Kung, Chung-Wei; Otake, Kenichi; Buru, Cassandra T.
  • Journal of the American Chemical Society, Vol. 140, Issue 11
  • DOI: 10.1021/jacs.8b00605

Modulating the rate of charge transport in a metal–organic framework thin film using host:guest chemistry
journal, January 2016

  • Hod, Idan; Farha, Omar K.; Hupp, Joseph T.
  • Chemical Communications, Vol. 52, Issue 8
  • DOI: 10.1039/C5CC09695B

The role of redox hopping in metal–organic framework electrocatalysis
journal, January 2018

  • Lin, Shaoyang; Usov, Pavel M.; Morris, Amanda J.
  • Chemical Communications, Vol. 54, Issue 51
  • DOI: 10.1039/C8CC01664J

A MOF platform for incorporation of complementary organic motifs for CO 2 binding
journal, January 2015

  • Deria, Pravas; Li, Song; Zhang, Hongda
  • Chemical Communications, Vol. 51, Issue 62
  • DOI: 10.1039/C5CC04808G

Detoxification of a Sulfur Mustard Simulant Using a BODIPY-Functionalized Zirconium-Based Metal–Organic Framework
journal, July 2017

  • Atilgan, Ahmet; Islamoglu, Timur; Howarth, Ashlee J.
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 29
  • DOI: 10.1021/acsami.7b05494

Dissection of Electronic Substituent Effects in Multielectron–Multistep Molecular Catalysis. Electrochemical CO 2 -to-CO Conversion Catalyzed by Iron Porphyrins
journal, December 2016

  • Azcarate, Iban; Costentin, Cyrille; Robert, Marc
  • The Journal of Physical Chemistry C, Vol. 120, Issue 51
  • DOI: 10.1021/acs.jpcc.6b09947

Understanding light-driven H 2 evolution through the electronic tuning of aminopyridine cobalt complexes
journal, January 2018

  • Call, Arnau; Franco, Federico; Kandoth, Noufal
  • Chemical Science, Vol. 9, Issue 9
  • DOI: 10.1039/C7SC04328G

Transition metal catalysis in confined spaces
journal, January 2015

  • Leenders, Stefan H. A. M.; Gramage-Doria, Rafael; de Bruin, Bas
  • Chemical Society Reviews, Vol. 44, Issue 2
  • DOI: 10.1039/C4CS00192C

Enhancing the catalytic activity of hydronium ions through constrained environments
journal, March 2017

  • Liu, Yuanshuai; Vjunov, Aleksei; Shi, Hui
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14113

Insights into proton-coupled electron transfer mechanisms of electrocatalytic H2 oxidation and production
journal, April 2012

  • Horvath, S.; Fernandez, L. E.; Soudackov, A. V.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 39
  • DOI: 10.1073/pnas.1118333109

Hydrogen Generation by Hangman Metalloporphyrins
journal, June 2011

  • Lee, Chang Hoon; Dogutan, Dilek K.; Nocera, Daniel G.
  • Journal of the American Chemical Society, Vol. 133, Issue 23
  • DOI: 10.1021/ja202136y

Electric Fields and Enzyme Catalysis
journal, June 2017


Size and Promoter Effects on Stability of Carbon-Nanofiber-Supported Iron-Based Fischer–Tropsch Catalysts
journal, May 2016


Heterogeneous Catalysis: A Central Science for a Sustainable Future
journal, March 2017


C–H Bond Activation on Bimetallic Two-Atom Co-M Oxide Clusters Deposited on Zr-Based MOF Nodes: Effects of Doping at the Molecular Level
journal, February 2018

  • Simons, Matthew C.; Ortuño, Manuel A.; Bernales, Varinia
  • ACS Catalysis, Vol. 8, Issue 4
  • DOI: 10.1021/acscatal.8b00012

Tuning Nickel with Lewis Acidic Group 13 Metalloligands for Catalytic Olefin Hydrogenation
journal, September 2015

  • Cammarota, Ryan C.; Lu, Connie C.
  • Journal of the American Chemical Society, Vol. 137, Issue 39
  • DOI: 10.1021/jacs.5b08313

Well-Defined Rhodium–Gallium Catalytic Sites in a Metal–Organic Framework: Promoter-Controlled Selectivity in Alkyne Semihydrogenation to E -Alkenes
journal, October 2018

  • Desai, Sai Puneet; Ye, Jingyun; Zheng, Jian
  • Journal of the American Chemical Society, Vol. 140, Issue 45
  • DOI: 10.1021/jacs.8b08550

Structure–activity relationships in catalysis by metals: some aspects of particle size, bimetallic and supports effects
journal, December 1998


Structural Assessment and Catalytic Consequences of the Oxygen Coordination Environment in Grafted Ti−Calixarenes
journal, February 2007

  • Notestein, Justin M.; Andrini, Leandro R.; Kalchenko, Vitaly I.
  • Journal of the American Chemical Society, Vol. 129, Issue 5
  • DOI: 10.1021/ja065830c

Beyond the Active Site: Tuning the Activity and Selectivity of a Metal–Organic Framework-Supported Ni Catalyst for Ethylene Dimerization
journal, August 2018

  • Liu, Jian; Ye, Jingyun; Li, Zhanyong
  • Journal of the American Chemical Society, Vol. 140, Issue 36
  • DOI: 10.1021/jacs.8b06006

Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies
journal, October 2013

  • Deria, Pravas; Mondloch, Joseph E.; Tylianakis, Emmanuel
  • Journal of the American Chemical Society, Vol. 135, Issue 45, p. 16801-16804
  • DOI: 10.1021/ja408959g

Bridging Zirconia Nodes within a Metal–Organic Framework via Catalytic Ni-Hydroxo Clusters to Form Heterobimetallic Nanowires
journal, July 2017

  • Platero-Prats, Ana E.; League, Aaron B.; Bernales, Varinia
  • Journal of the American Chemical Society, Vol. 139, Issue 30
  • DOI: 10.1021/jacs.7b04997

Supported Molecular Iridium Catalysts: Resolving Effects of Metal Nuclearity and Supports as Ligands
journal, October 2011

  • Lu, Jing; Serna, Pedro; Aydin, Ceren
  • Journal of the American Chemical Society, Vol. 133, Issue 40
  • DOI: 10.1021/ja206486j

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    journal, January 2020

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    • Chemical Science, Vol. 11, Issue 28
    • DOI: 10.1039/d0sc03053h