Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m -Terphenyl Diisocyanides

Agnew, Douglas W.; DiMucci, Ida M.; Arroyave, Alejandra; Gembicky, Milan; Moore, Curtis E.; MacMillan, Samantha N.; Rheingold, Arnold L.; Lancaster, Kyle M.; Figueroa, Joshua S.

doi:10.1021/jacs.7b09569

Title: Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m -Terphenyl Diisocyanides

Abstract

A permanently porous, three-dimensional metal–organic material formed from zero-valent metal nodes is presented. Combination of ditopic m-terphenyl diisocyanide, [CNAr^Mes2]₂, and the d¹⁰ Ni(0) precursor Ni(COD)₂, produces a porous metal–organic material featuring tetrahedral [Ni(CNAr^Mes2)₄]_n structural sites. X-ray absorption spectroscopy provides firm evidence for the presence of Ni(0) centers, whereas gas-sorption and thermogravimetric analysis reveal the characteristics of a robust network with a microdomain N₂-adsorption profile.

Authors:

Agnew, Douglas W. ^[1]; DiMucci, Ida M. ^[2]; Arroyave, Alejandra ^[1]; Gembicky, Milan ^[1]; Moore, Curtis E. ^[1]; MacMillan, Samantha N. ^[2]; Rheingold, Arnold L. ^[1];

^[2];

^[1]

Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive MC 0358, La Jolla, California 92093, United States
Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853, United States

Publication Date:: 2017-11-17

Research Org.:: Univ. of California, San Diego, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); USDOE Office of Science (SC), Biological and Environmental Research (BER)

OSTI Identifier:: 1409488

Alternate Identifier(s):: OSTI ID: 1413210

Grant/Contract Number:: SC0008058; AC02-76SF00515

Resource Type:: Published Article

Journal Name:: Journal of the American Chemical Society

Additional Journal Information:: Journal Name: Journal of the American Chemical Society Journal Volume: 139 Journal Issue: 48; Journal ID: ISSN 0002-7863

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Agnew, Douglas W., DiMucci, Ida M., Arroyave, Alejandra, Gembicky, Milan, Moore, Curtis E., MacMillan, Samantha N., Rheingold, Arnold L., Lancaster, Kyle M., and Figueroa, Joshua S. Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m -Terphenyl Diisocyanides.  United States: N. p., 2017. 
Web.  doi:10.1021/jacs.7b09569.

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                    Agnew, Douglas W., DiMucci, Ida M., Arroyave, Alejandra, Gembicky, Milan, Moore, Curtis E., MacMillan, Samantha N., Rheingold, Arnold L., Lancaster, Kyle M., & Figueroa, Joshua S. Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m -Terphenyl Diisocyanides.  United States.  https://doi.org/10.1021/jacs.7b09569

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                    Agnew, Douglas W., DiMucci, Ida M., Arroyave, Alejandra, Gembicky, Milan, Moore, Curtis E., MacMillan, Samantha N., Rheingold, Arnold L., Lancaster, Kyle M., and Figueroa, Joshua S. Fri .  
"Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m -Terphenyl Diisocyanides".  United States.  https://doi.org/10.1021/jacs.7b09569.

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@article{osti_1409488,

  title        = {Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m -Terphenyl Diisocyanides},

  author       = {Agnew, Douglas W. and DiMucci, Ida M. and Arroyave, Alejandra and Gembicky, Milan and Moore, Curtis E. and MacMillan, Samantha N. and Rheingold, Arnold L. and Lancaster, Kyle M. and Figueroa, Joshua S.},

  abstractNote = {A permanently porous, three-dimensional metal–organic material formed from zero-valent metal nodes is presented. Combination of ditopic m-terphenyl diisocyanide, [CNArMes2]2, and the d10 Ni(0) precursor Ni(COD)2, produces a porous metal–organic material featuring tetrahedral [Ni(CNArMes2)4]n structural sites. X-ray absorption spectroscopy provides firm evidence for the presence of Ni(0) centers, whereas gas-sorption and thermogravimetric analysis reveal the characteristics of a robust network with a microdomain N2-adsorption profile.},

  doi          = {10.1021/jacs.7b09569},

  journal      = {Journal of the American Chemical Society},

  number       = 48,

  volume       = 139,

  place        = {United States},

  year         = {2017},

  month        = {11}

}

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Works referencing / citing this record:

CCDC 1814535: Experimental Crystal Structure Determination: WETKAK : catena-[bis(μ-4,4'-diisocyano-3,3',5,5'-tetramesitylbiphenyl)-nickel(0) 4,4'-diisocyano-3,3',5,5'-tetramesitylbiphenyl tetrahydrofuran unknown solvate]
dataset, January 2018

Agnew, Douglas; DiMucci, Ida; Arroyave, Alejandra
Cambridge Structural Database (CSD)
DOI: 10.5517/ccdc.csd.cc1yx5df

CCDC 1814536: Experimental Crystal Structure Determination: WETKEO : tetrakis(2,2'',4,4'',6,6''-hexamethyl-1,1':3',1''-terphenyl-2'-yl isocyanide)-nickel(i) trifluoromethanesulfonate toluene solvate
dataset, January 2018

Agnew, Douglas; DiMucci, Ida; Arroyave, Alejandra
Cambridge Structural Database (CSD)
DOI: 10.5517/ccdc.csd.cc1yx5fg

A palladium–carbon-connected organometallic framework and its catalytic application
journal, January 2019

Dong, Ying; Jv, Jing-Jing; Wu, Xiao-Wei
Chemical Communications, Vol. 55, Issue 96
DOI: 10.1039/c9cc07829k

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dataset (2)

Title: Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m -Terphenyl Diisocyanides

Abstract

Citation Formats

CCDC 1814535: Experimental Crystal Structure Determination: WETKAK : catena-[bis(μ-4,4'-diisocyano-3,3',5,5'-tetramesitylbiphenyl)-nickel(0) 4,4'-diisocyano-3,3',5,5'-tetramesitylbiphenyl tetrahydrofuran unknown solvate] dataset, January 2018

CCDC 1814536: Experimental Crystal Structure Determination: WETKEO : tetrakis(2,2'',4,4'',6,6''-hexamethyl-1,1':3',1''-terphenyl-2'-yl isocyanide)-nickel(i) trifluoromethanesulfonate toluene solvate dataset, January 2018

A palladium–carbon-connected organometallic framework and its catalytic application journal, January 2019

CCDC 1814535: Experimental Crystal Structure Determination: WETKAK : catena-[bis(μ-4,4'-diisocyano-3,3',5,5'-tetramesitylbiphenyl)-nickel(0) 4,4'-diisocyano-3,3',5,5'-tetramesitylbiphenyl tetrahydrofuran unknown solvate]
dataset, January 2018

CCDC 1814536: Experimental Crystal Structure Determination: WETKEO : tetrakis(2,2'',4,4'',6,6''-hexamethyl-1,1':3',1''-terphenyl-2'-yl isocyanide)-nickel(i) trifluoromethanesulfonate toluene solvate
dataset, January 2018

A palladium–carbon-connected organometallic framework and its catalytic application
journal, January 2019