Relating structure and composition with accessibility of a single catalyst particle using correlative 3-dimensional micro-spectroscopy
Abstract
To understand how hierarchically structured functional materials operate, analytical tools are needed that can reveal small structural and chemical details in large sample volumes. Often, a single method alone is not sufficient to get a complete picture of processes happening at multiple length scales. Here we present a correlative approach combining three-dimensional X-ray imaging techniques at different length scales for the analysis of metal poisoning of an individual catalyst particle. The correlative nature of the data allowed establishing a macro-pore network model that interprets metal accumulations as a resistance to mass transport and can, by tuning the effect of metal deposition, simulate the response of the network to a virtual ageing of the catalyst particle. In conclusion, the developed approach is generally applicable and provides an unprecedented view on dynamic changes in a material’s pore space, which is an essential factor in the rational design of functional porous materials.
- Authors:
-
[2];
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Utrecht Univ., Utrecht (The Netherlands)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1312961
- Grant/Contract Number:
- AC02-76SF00515
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 7; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Liu, Yijin, Meirer, Florian, Krest, Courtney M., Webb, Samuel, and Weckhuysen, Bert M. Relating structure and composition with accessibility of a single catalyst particle using correlative 3-dimensional micro-spectroscopy. United States: N. p., 2016.
Web. doi:10.1038/ncomms12634.
Liu, Yijin, Meirer, Florian, Krest, Courtney M., Webb, Samuel, & Weckhuysen, Bert M. Relating structure and composition with accessibility of a single catalyst particle using correlative 3-dimensional micro-spectroscopy. United States. https://doi.org/10.1038/ncomms12634
Liu, Yijin, Meirer, Florian, Krest, Courtney M., Webb, Samuel, and Weckhuysen, Bert M. Tue .
"Relating structure and composition with accessibility of a single catalyst particle using correlative 3-dimensional micro-spectroscopy". United States. https://doi.org/10.1038/ncomms12634. https://www.osti.gov/servlets/purl/1312961.
@article{osti_1312961,
title = {Relating structure and composition with accessibility of a single catalyst particle using correlative 3-dimensional micro-spectroscopy},
author = {Liu, Yijin and Meirer, Florian and Krest, Courtney M. and Webb, Samuel and Weckhuysen, Bert M.},
abstractNote = {To understand how hierarchically structured functional materials operate, analytical tools are needed that can reveal small structural and chemical details in large sample volumes. Often, a single method alone is not sufficient to get a complete picture of processes happening at multiple length scales. Here we present a correlative approach combining three-dimensional X-ray imaging techniques at different length scales for the analysis of metal poisoning of an individual catalyst particle. The correlative nature of the data allowed establishing a macro-pore network model that interprets metal accumulations as a resistance to mass transport and can, by tuning the effect of metal deposition, simulate the response of the network to a virtual ageing of the catalyst particle. In conclusion, the developed approach is generally applicable and provides an unprecedented view on dynamic changes in a material’s pore space, which is an essential factor in the rational design of functional porous materials.},
doi = {10.1038/ncomms12634},
journal = {Nature Communications},
number = ,
volume = 7,
place = {United States},
year = {2016},
month = {8}
}
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Works referenced in this record:
Fluid catalytic cracking: recent developments on the grand old lady of zeolite catalysis
journal, January 2015
- Vogt, E. T. C.; Weckhuysen, B. M.
- Chemical Society Reviews, Vol. 44, Issue 20
Porous materials in catalysis: challenges for mesoporous materials
journal, January 2013
- Perego, Carlo; Millini, Roberto
- Chem. Soc. Rev., Vol. 42, Issue 9
From powder to technical body: the undervalued science of catalyst scale up
journal, January 2013
- Mitchell, Sharon; Michels, Nina-Luisa; Pérez-Ramírez, Javier
- Chemical Society Reviews, Vol. 42, Issue 14
Effect of framework Si/Al ratio and extra-framework aluminum on the catalytic activity of Y zeolite
journal, December 2007
- Xu, Bin; Bordiga, Silvia; Prins, Roel
- Applied Catalysis A: General, Vol. 333, Issue 2
Designing FCC catalysts with high-silica Y zeolites
journal, August 1991
- Scherzer, Julius
- Applied Catalysis, Vol. 75, Issue 1
Ion-Exchanged Ultrastable Y Zeolites. 3. Gas Oil Cracking over Rare Earth-Exchanged Ultrastable Y Zeolites
journal, September 1978
- Scherzer, Julius; Ritter, Ronald E.
- Industrial & Engineering Chemistry Product Research and Development, Vol. 17, Issue 3
Deactivation of FCC catalysts
journal, September 2008
- Cerqueira, H. S.; Caeiro, G.; Costa, L.
- Journal of Molecular Catalysis A: Chemical, Vol. 292, Issue 1-2
The role of rare earth elements in zeolites and cracking catalysts
journal, December 2013
- Sousa-Aguiar, Eduardo Falabella; Trigueiro, Flávia Elias; Zotin, Fatima Maria Zanon
- Catalysis Today, Vol. 218-219
The role of polyvalent cations in developing strong acidity: A study of lanthanum-exchanged zeolites
journal, September 1990
- Carvajal, R.
- Journal of Catalysis, Vol. 125, Issue 1
Current views on the mechanism of catalytic cracking
journal, April 2000
- Corma, A.; Orchillés, A. V.
- Microporous and Mesoporous Materials, Vol. 35-36
Structural analysis of hierarchically organized zeolites
journal, October 2015
- Mitchell, Sharon; Pinar, Ana B.; Kenvin, Jeffrey
- Nature Communications, Vol. 6, Issue 1
Recommendations for the characterization of porous solids (Technical Report)
journal, January 1994
- Rouquerol, J.; Avnir, D.; Fairbridge, C. W.
- Pure and Applied Chemistry, Vol. 66, Issue 8, p. 1739-1758
Mesopore quality determines the lifetime of hierarchically structured zeolite catalysts
journal, May 2014
- Milina, Maria; Mitchell, Sharon; Crivelli, Paolo
- Nature Communications, Vol. 5, Issue 1
Mapping Metals Incorporation of a Whole Single Catalyst Particle Using Element Specific X-ray Nanotomography
journal, January 2015
- Meirer, Florian; Morris, Darius T.; Kalirai, Sam
- Journal of the American Chemical Society, Vol. 137, Issue 1
Life and death of a single catalytic cracking particle
journal, April 2015
- Meirer, Florian; Kalirai, Sam; Morris, Darius
- Science Advances, Vol. 1, Issue 3
Agglutination of single catalyst particles during fluid catalytic cracking as observed by X-ray nanotomography
journal, January 2015
- Meirer, F.; Kalirai, S.; Weker, J. Nelson
- Chemical Communications, Vol. 51, Issue 38
Study of the accessibility effect on the irreversible deactivation of FCC catalysts from contaminant feed metals
journal, September 2007
- Psarras, A. C.; Iliopoulou, E. F.; Nalbandian, L.
- Catalysis Today, Vol. 127, Issue 1-4
Visualization of the Equilibrium FCC Catalyst Surface by AFM and SEM–EDS
journal, October 2003
- Bayraktar, Oguz; Kugler, Edwin L.
- Catalysis Letters, Vol. 90, Issue 3/4
Novel lab-scale deactivation method for FCC catalyst: inducing realistic accessibility responses to iron poisoning
journal, August 2003
- Rainer, D. R.; Rautiainen, E.; Imhof, P.
- Applied Catalysis A: General, Vol. 249, Issue 1
Back Cover: Characterization of a Fluidized Catalytic Cracking Catalyst on Ensemble and Individual Particle Level by X-ray Micro- and Nanotomography, Micro-X-ray Fluorescence, and Micro-X-ray Diffraction (ChemCatChem 5/2014)
journal, May 2014
- Bare, Simon R.; Charochak, Meghan E.; Kelly, Shelly D.
- ChemCatChem, Vol. 6, Issue 5
Assessment of the 3 D Pore Structure and Individual Components of Preshaped Catalyst Bodies by X-Ray Imaging
journal, December 2014
- da Silva, Julio C.; Mader, Kevin; Holler, Mirko
- ChemCatChem, Vol. 7, Issue 3
Hard and soft X-ray microscopy and tomography in catalysis: bridging the different time and length scales
journal, January 2010
- Grunwaldt, Jan-Dierk; Schroer, Christian G.
- Chemical Society Reviews, Vol. 39, Issue 12
Chemical imaging of catalytic solids with synchrotron radiation
journal, January 2010
- Beale, Andrew M.; Jacques, Simon D. M.; Weckhuysen, Bert M.
- Chemical Society Reviews, Vol. 39, Issue 12
Heterogeneities of individual catalyst particles in space and time as monitored by spectroscopy
journal, October 2012
- Buurmans, Inge L. C.; Weckhuysen, Bert M.
- Nature Chemistry, Vol. 4, Issue 11
Hard x-ray nanofocusing by multilayer Laue lenses
journal, June 2014
- Yan, Hanfei; Conley, Ray; Bouet, Nathalie
- Journal of Physics D: Applied Physics, Vol. 47, Issue 26
Ultra-high aspect ratio high-resolution nanofabrication for hard X-ray diffractive optics
journal, June 2014
- Chang, Chieh; Sakdinawat, Anne
- Nature Communications, Vol. 5, Issue 1
Progress towards five dimensional diffraction imaging of functional materials under process conditions
journal, October 2014
- Beale, Andrew M.; Jacques, Simon D. M.; Gibson, Emma K.
- Coordination Chemistry Reviews, Vol. 277-278
Correlating Metal Poisoning with Zeolite Deactivation in an Individual Catalyst Particle by Chemical and Phase-Sensitive X-ray Microscopy
journal, April 2013
- Ruiz-Martínez, Javier; Beale, Andrew M.; Deka, Upakul
- Angewandte Chemie International Edition, Vol. 52, Issue 23
The Bionanoprobe: hard X-ray fluorescence nanoprobe with cryogenic capabilities
journal, December 2013
- Chen, S.; Deng, J.; Yuan, Y.
- Journal of Synchrotron Radiation, Vol. 21, Issue 1
X-ray Fluorescence Tomography of Aged Fluid-Catalytic-Cracking Catalyst Particles Reveals Insight into Metal Deposition Processes
journal, September 2015
- Kalirai, Sam; Boesenberg, Ulrike; Falkenberg, Gerald
- ChemCatChem, Vol. 7, Issue 22
Effect of metals poisoning on FCC products yields: studies in an FCC short contact time pilot plant unit
journal, February 2001
- Lappas, A. A.; Nalbandian, L.; Iatridis, D. K.
- Catalysis Today, Vol. 65, Issue 2-4
Evaluation of vanadium traps occluded in resid fluidized catalytic cracking (RFCC) catalyst for high gasoline yield
journal, June 2006
- Jeon, Hee Jung; Park, Sang Ku; Woo, Seong Ihl
- Applied Catalysis A: General, Vol. 306
Extraction of pore-morphology and capillary pressure curves of porous media from synchrotron-based tomography data
journal, June 2015
- Yang, Feifei; Hingerl, Ferdinand F.; Xiao, Xianghui
- Scientific Reports, Vol. 5, Issue 1
Percolation and Conduction
journal, October 1973
- Kirkpatrick, Scott
- Reviews of Modern Physics, Vol. 45, Issue 4, p. 574-588
Network Modeling of Diffusion Coefficients for Porous Media: I. Theory and Model Development
journal, September 1994
- Steele, D. D.; Nieber, J. L.
- Soil Science Society of America Journal, Vol. 58, Issue 5
Towards the 3D modeling of the effective conductivity of solid oxide fuel cell electrodes: I. Model development
journal, August 2013
- Rhazaoui, K.; Cai, Q.; Adjiman, C. S.
- Chemical Engineering Science, Vol. 99
Single and combined Fluidized Catalytic Cracking (FCC) catalyst deactivation by iron and calcium metal–organic contaminants
journal, January 2014
- Mathieu, Yannick; Corma, Avelino; Echard, Michaël
- Applied Catalysis A: General, Vol. 469
3D elemental sensitive imaging using transmission X-ray microscopy
journal, February 2012
- Liu, Yijin; Meirer, Florian; Wang, Junyue
- Analytical and Bioanalytical Chemistry, Vol. 404, Issue 5
Fourier shell correlation threshold criteria
journal, September 2005
- van Heel, Marin; Schatz, Michael
- Journal of Structural Biology, Vol. 151, Issue 3
A multiplatform code for the analysis of energy-dispersive X-ray fluorescence spectra
journal, January 2007
- Solé, V. A.; Papillon, E.; Cotte, M.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 62, Issue 1
TXM-Wizard : a program for advanced data collection and evaluation in full-field transmission X-ray microscopy
journal, January 2012
- Liu, Yijin; Meirer, Florian; Williams, Phillip A.
- Journal of Synchrotron Radiation, Vol. 19, Issue 2
Works referencing / citing this record:
Nickel Poisoning of a Cracking Catalyst Unravelled by Single‐Particle X‐ray Fluorescence‐Diffraction‐Absorption Tomography
journal, January 2020
- Gambino, Marianna; Veselý, Martin; Filez, Matthias
- Angewandte Chemie, Vol. 132, Issue 10
Magnetophoretic Sorting of Single Catalyst Particles
journal, August 2018
- Solsona, Miguel; Nieuwelink, Anne‐Eva; Meirer, Florian
- Angewandte Chemie International Edition, Vol. 57, Issue 33
Nickel Poisoning of a Cracking Catalyst Unravelled by Single‐Particle X‐ray Fluorescence‐Diffraction‐Absorption Tomography
journal, January 2020
- Gambino, Marianna; Veselý, Martin; Filez, Matthias
- Angewandte Chemie International Edition, Vol. 59, Issue 10
Correlative Multiscale 3D Imaging of a Hierarchical Nanoporous Gold Catalyst by Electron, Ion and X-ray Nanotomography
journal, May 2018
- Fam, Yakub; Sheppard, Thomas L.; Diaz, Ana
- ChemCatChem, Vol. 10, Issue 13
One‐Shot Measurement of Effectiveness Factors of Chemical Conversion in Porous Catalysts
journal, December 2018
- Chmelik, Christian; Liebau, Michael; Al‐Naji, Majd
- ChemCatChem
Accurate 3D Characterization of Catalytic Bodies Surface by Scanning Electron Microscopy
journal, June 2019
- Gontard, Lionel C.; Cauqui, Miguel Ángel; Yeste, María Pilar
- ChemCatChem, Vol. 11, Issue 14
Visualizing pore architecture and molecular transport boundaries in catalyst bodies with fluorescent nanoprobes
journal, November 2018
- Whiting, Gareth T.; Nikolopoulos, Nikolaos; Nikolopoulos, Ioannis
- Nature Chemistry, Vol. 11, Issue 1
Spatial and temporal exploration of heterogeneous catalysts with synchrotron radiation
journal, August 2018
- Meirer, Florian; Weckhuysen, Bert M.
- Nature Reviews Materials, Vol. 3, Issue 9
Efficient correction of wavefront inhomogeneities in X-ray holographic nanotomography by random sample displacement
journal, May 2018
- Hubert, Maxime; Pacureanu, Alexandra; Guilloud, Cyril
- Applied Physics Letters, Vol. 112, Issue 20
Multimodal x-ray and electron microscopy of the Allende meteorite
journal, September 2019
- Lo, Yuan Hung; Liao, Chen-Ting; Zhou, Jihan
- Science Advances, Vol. 5, Issue 9
Structural Evolution of Highly Active Multicomponent Catalysts for Selective Propylene Oxidation
journal, August 2018
- Sprenger, Paul; Sheppard, Thomas; Suuronen, Jussi-Petteri
- Catalysts, Vol. 8, Issue 9
High-speed raster-scanning synchrotron serial microcrystallography with a high-precision piezo-scanner
text, January 2018
- Gao, Yuan; Xu, Weihe; Shi, Wuxian
- International Union of Crystallography (IUCr)
Magnetophoretic Sorting of Single Catalyst Particles
journal, August 2018
- Solsona, Miguel; Nieuwelink, Anne‐Eva; Meirer, Florian
- Angewandte Chemie, Vol. 130, Issue 33
Structural evolution of highly active multicomponent catalysts for selective propylene oxidation
text, January 2018
- Sprenger, P.; Sheppard, T. L.; Suuronen, J. -P.
- Karlsruhe