Base metal dehydrogenation of amine-boranes
Abstract
A method of dehydrogenating an amine-borane having the formula R.sup.1H.sub.2N--BH.sub.2R.sup.2 using base metal catalyst. The method generates hydrogen and produces at least one of a [R.sup.1HN--BHR.sup.2].sub.m oligomer and a [R.sup.1N--BR.sup.2].sub.n oligomer. The method of dehydrogenating amine-boranes may be used to generate H.sub.2 for portable power sources, such as, but not limited to, fuel cells.
- Inventors:
-
- Ottawa, CA
- Pearland, TX
- Los Alamos, NM
- Issue Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 972292
- Patent Number(s):
- 7544837
- Application Number:
- 11/590,136
- Assignee:
- Los Alamos National Security, LLC (Los Alamos, NM)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- DOE Contract Number:
- W-7405-ENG-36; AC52-06NA25396
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Blacquiere, Johanna Marie, Keaton, Richard Jeffrey, and Baker, Ralph Thomas. Base metal dehydrogenation of amine-boranes. United States: N. p., 2009.
Web.
Blacquiere, Johanna Marie, Keaton, Richard Jeffrey, & Baker, Ralph Thomas. Base metal dehydrogenation of amine-boranes. United States.
Blacquiere, Johanna Marie, Keaton, Richard Jeffrey, and Baker, Ralph Thomas. Tue .
"Base metal dehydrogenation of amine-boranes". United States. https://www.osti.gov/servlets/purl/972292.
@article{osti_972292,
title = {Base metal dehydrogenation of amine-boranes},
author = {Blacquiere, Johanna Marie and Keaton, Richard Jeffrey and Baker, Ralph Thomas},
abstractNote = {A method of dehydrogenating an amine-borane having the formula R.sup.1H.sub.2N--BH.sub.2R.sup.2 using base metal catalyst. The method generates hydrogen and produces at least one of a [R.sup.1HN--BHR.sup.2].sub.m oligomer and a [R.sup.1N--BR.sup.2].sub.n oligomer. The method of dehydrogenating amine-boranes may be used to generate H.sub.2 for portable power sources, such as, but not limited to, fuel cells.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jun 09 00:00:00 EDT 2009},
month = {Tue Jun 09 00:00:00 EDT 2009}
}
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