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Title: Metal-organic framework materials based on icosahedral boranes and carboranes

Abstract

Disclosed herein are metal-organic frameworks of metals and boron rich ligands, such as carboranes and icosahedral boranes. Methods of synthesizing and using these materials in gas uptake are disclosed.

Inventors:
; ; ; ;
Issue Date:
Research Org.:
Northwestern Univ., Evanston, IL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1176417
Patent Number(s):
7824473
Application Number:
12/180,074
Assignee:
Northwestern University (Evanston, IL)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
DOE Contract Number:  
FG02-01ER15244
Resource Type:
Patent
Resource Relation:
Patent File Date: 2008 Jul 25
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Mirkin, Chad A., Hupp, Joseph T., Farha, Omar K., Spokoyny, Alexander M., and Mulfort, Karen L. Metal-organic framework materials based on icosahedral boranes and carboranes. United States: N. p., 2010. Web.
Mirkin, Chad A., Hupp, Joseph T., Farha, Omar K., Spokoyny, Alexander M., & Mulfort, Karen L. Metal-organic framework materials based on icosahedral boranes and carboranes. United States.
Mirkin, Chad A., Hupp, Joseph T., Farha, Omar K., Spokoyny, Alexander M., and Mulfort, Karen L. Tue . "Metal-organic framework materials based on icosahedral boranes and carboranes". United States. https://www.osti.gov/servlets/purl/1176417.
@article{osti_1176417,
title = {Metal-organic framework materials based on icosahedral boranes and carboranes},
author = {Mirkin, Chad A. and Hupp, Joseph T. and Farha, Omar K. and Spokoyny, Alexander M. and Mulfort, Karen L.},
abstractNote = {Disclosed herein are metal-organic frameworks of metals and boron rich ligands, such as carboranes and icosahedral boranes. Methods of synthesizing and using these materials in gas uptake are disclosed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2010},
month = {11}
}

Works referenced in this record:

High H2 Adsorption in a Microporous Metal-Organic Framework with Open Metal Sites
journal, July 2005


Chemical Reduction of Metal−Organic Framework Materials as a Method to Enhance Gas Uptake and Binding
journal, August 2007


Novel 2D and 3D Indium Metal-Organic Frameworks:  Topology and Catalytic Properties
journal, May 2005


Functional Porous Coordination Polymers
journal, April 2004


Safe and Convenient Procedure for Solvent Purification
journal, January 1996


Synthesis and Ligand-Exchange Kinetics of the Solvated Trigonal-Prismatic Clusters [W6CCl12L6]2+ (L=dmf, py)
journal, May 2007


Crystal Engineering of Nonlinear Optical Materials Based on Interpenetrated Diamondoid Coordination Networks
journal, August 2001


Coordination Polymers Containing 1D Channels as Selective Luminescent Probes
journal, December 2004


Silver(I)−Polynitrile Network Solids for Anion Exchange:  Anion-Induced Transformation of Supramolecular Structure in the Crystalline State
journal, July 2000


Hydrogen Physisorption in Metal-Organic Porous Crystals
journal, March 2005


Immobilization of a Metallo Schiff Base into a Microporous Coordination Polymer
journal, May 2004


Chemically tailorable colloidal particles from infinite coordination polymers
journal, December 2005


A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation
journal, January 2006


Design, Chirality, and Flexibility in Nanoporous Molecule-Based Materials
journal, April 2005


Virial-type thermal equation of gas—solid adsorption
journal, January 1989


Designed Synthesis of 3D Covalent Organic Frameworks
journal, April 2007


Hydrogen Storage in a Microporous Metal−Organic Framework with Exposed Mn 2+ Coordination Sites
journal, December 2006


A Homochiral Porous Metal−Organic Framework for Highly Enantioselective Heterogeneous Asymmetric Catalysis
journal, June 2005


Multifunctionality and Crystal Dynamics of a Highly Stable, Porous Metal−Organic Framework [Zn 4 O(NTB) 2 ]
journal, May 2005


Zn(tbip) (H 2 tbip= 5- tert -Butyl Isophthalic Acid):  A Highly Stable Guest-Free Microporous Metal Organic Framework with Unique Gas Separation Capability
journal, April 2006


Assembly of Metal–Organic Frameworks (MOFs) Based on Indium-Trimer Building Blocks: A Porous MOF with soc Topology and High Hydrogen Storage
journal, April 2007


Hydrogen Storage in the Giant-Pore Metal–Organic Frameworks MIL-100 and MIL-101
journal, December 2006


Synthesis and Hydrogen Sorption Properties of Carborane Based Metal−Organic Framework Materials
journal, October 2007