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Title: Metal complexes based on a bis(2-pyridylmethyl)amine-based scaffold and methods of making the same

Abstract

A catalyst includes a bis(2-pyridylmethyl)amine-based ligand. A method of forming a catalyst, may include: reacting bis(2-pyridylmethyl)amine-based compound with a terminal azide and/or a terminal alkyne in the presence of Cu(I) to form a bis(2-pyridylmethyl)amine-based ligand. A method of using such catalysts may include neutralizing toxicity of at least one organophosphorus-based compound by reacting the organophosphorus-based compound with a bis(2-pyridylmethyl)amine-based ligand-metal complex.

Inventors:
; ;
Issue Date:
Research Org.:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1500054
Patent Number(s):
10189864
Application Number:
15/048,921
Assignee:
Lawrence Livermore National Security, LLC (Livermore, CA)
Patent Classifications (CPCs):
A - HUMAN NECESSITIES A62 - LIFE-SAVING A62D - CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
DOE Contract Number:  
AC52-07NA27344
Resource Type:
Patent
Resource Relation:
Patent File Date: 2016 Feb 19
Country of Publication:
United States
Language:
English

Citation Formats

Valdez, Carlos, Lau, Edmond Y., and Mayer, Brian P.. Metal complexes based on a bis(2-pyridylmethyl)amine-based scaffold and methods of making the same. United States: N. p., 2019. Web.
Valdez, Carlos, Lau, Edmond Y., & Mayer, Brian P.. Metal complexes based on a bis(2-pyridylmethyl)amine-based scaffold and methods of making the same. United States.
Valdez, Carlos, Lau, Edmond Y., and Mayer, Brian P.. Tue . "Metal complexes based on a bis(2-pyridylmethyl)amine-based scaffold and methods of making the same". United States. https://www.osti.gov/servlets/purl/1500054.
@article{osti_1500054,
title = {Metal complexes based on a bis(2-pyridylmethyl)amine-based scaffold and methods of making the same},
author = {Valdez, Carlos and Lau, Edmond Y. and Mayer, Brian P.},
abstractNote = {A catalyst includes a bis(2-pyridylmethyl)amine-based ligand. A method of forming a catalyst, may include: reacting bis(2-pyridylmethyl)amine-based compound with a terminal azide and/or a terminal alkyne in the presence of Cu(I) to form a bis(2-pyridylmethyl)amine-based ligand. A method of using such catalysts may include neutralizing toxicity of at least one organophosphorus-based compound by reacting the organophosphorus-based compound with a bis(2-pyridylmethyl)amine-based ligand-metal complex.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}

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Works referenced in this record:

Dilazep analogues for the study of equilibrative nucleoside transporters 1 and 2 (ENT1 and ENT2)
journal, December 2014


Copper-catalyzed regioselective hydroboration of terminal alkynes in aqueous medium
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Highly Sensitive Fluorescent Probes for Zinc Ion Based on Triazolyl-Containing Tetradentate Coordination Motifs
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