Acid-catalyzed dehydrogenation of amine-boranes
Abstract
A method of dehydrogenating an amine-borane using an acid-catalyzed reaction. The method generates hydrogen and produces a solid polymeric [R.sup.1R.sup.2B--NR.sup.3R.sup.4].sub.n product. The method of dehydrogenating amine-boranes may be used to generate H.sub.2 for portable power sources.
- Inventors:
-
- Santa Fe, NM
- Los Alamos, NM
- Issue Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1014074
- Patent Number(s):
- 7645902
- Application Number:
- US Patent Application 11/473,510
- Assignee:
- Los Alamos National Security, LLC (Los Alamos, NM)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- DOE Contract Number:
- W-7405-ENG-36
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Stephens, Frances Helen, and Baker, Ralph Thomas. Acid-catalyzed dehydrogenation of amine-boranes. United States: N. p., 2010.
Web.
Stephens, Frances Helen, & Baker, Ralph Thomas. Acid-catalyzed dehydrogenation of amine-boranes. United States.
Stephens, Frances Helen, and Baker, Ralph Thomas. Tue .
"Acid-catalyzed dehydrogenation of amine-boranes". United States. https://www.osti.gov/servlets/purl/1014074.
@article{osti_1014074,
title = {Acid-catalyzed dehydrogenation of amine-boranes},
author = {Stephens, Frances Helen and Baker, Ralph Thomas},
abstractNote = {A method of dehydrogenating an amine-borane using an acid-catalyzed reaction. The method generates hydrogen and produces a solid polymeric [R.sup.1R.sup.2B--NR.sup.3R.sup.4].sub.n product. The method of dehydrogenating amine-boranes may be used to generate H.sub.2 for portable power sources.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2010},
month = {1}
}
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Works referenced in this record:
Transition Metal-Catalyzed Formation of Boron−Nitrogen Bonds: Catalytic Dehydrocoupling of Amine-Borane Adducts to Form Aminoboranes and Borazines
journal, August 2003
- Jaska, Cory A.; Temple, Karen; Lough, Alan J.
- Journal of the American Chemical Society, Vol. 125, Issue 31
Proton Affinities of Borane−Amines: Consequences on Dihydrogen Bonding
journal, March 2005
- Patwari, G. Naresh
- The Journal of Physical Chemistry A, Vol. 109, Issue 10