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Title: Method of photocatalytic conversion of C-H organics

Abstract

The present invention is the addition of a semiconductor material and energy to the reaction mixture of organic, acid (for example, trifluoroacetate), and oxygen. A transition metal ion may be added to the reaction mixture. The semiconductor material converts energy to oxidants thereby promoting oxidation of the organic. Alternatively, using metal in combination with exposure to light may be used.

Inventors:
 [1];  [1]
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  1. Richland, WA
Issue Date:
Research Org.:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
OSTI Identifier:
871328
Patent Number(s):
5708246
Assignee:
Battelle Memorial Institute (Richland, WA)
Patent Classifications (CPCs):
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
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DOE Contract Number:  
AC06-76RL01830
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
method; photocatalytic; conversion; c-h; organics; addition; semiconductor; material; energy; reaction; mixture; organic; acid; example; trifluoroacetate; oxygen; transition; metal; added; converts; oxidants; promoting; oxidation; alternatively; combination; exposure; light; semiconductor material; transition metal; reaction mixture; photocatalytic conversion; catalytic conversion; /204/

Citation Formats

Camaioni, Donald M, and Lilga, Michael A. Method of photocatalytic conversion of C-H organics. United States: N. p., 1998. Web.
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Camaioni, Donald M, & Lilga, Michael A. Method of photocatalytic conversion of C-H organics. United States.
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Camaioni, Donald M, and Lilga, Michael A. Tue . "Method of photocatalytic conversion of C-H organics". United States. https://www.osti.gov/servlets/purl/871328.
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@article{osti_871328,
title = {Method of photocatalytic conversion of C-H organics},
author = {Camaioni, Donald M and Lilga, Michael A},
abstractNote = {The present invention is the addition of a semiconductor material and energy to the reaction mixture of organic, acid (for example, trifluoroacetate), and oxygen. A transition metal ion may be added to the reaction mixture. The semiconductor material converts energy to oxidants thereby promoting oxidation of the organic. Alternatively, using metal in combination with exposure to light may be used.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 13 00:00:00 EST 1998},
month = {Tue Jan 13 00:00:00 EST 1998}
}
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Works referenced in this record:

Novel approach taken for methane activation
journal, January 1988

Carbon-hydrogen bond activation by electrophilic transition-metal compounds. Palladium(II)-mediated oxidation of arenes and alkanes including methane
journal, December 1987

Aerial Oxidation of Benzene in the Presence of Electrochemically Generated Cuprous Ions
journal, June 1983

Carbon-hydrogen vs. carbon-carbon bond cleavage of 1,2-diarylethane radical cations in acetonitrile-water
journal, May 1984

Products and mechanism of the oxidation of 9-methylanthracene by peroxydisulfate. Proton loss and nucleophile addition reactions of the 9-methylanthracene radical cation
journal, September 1986

Anodic processes on n-titania with and without illumination in trifluoromethanesulfonic acid monohydrate saturated with alkanes
journal, October 1988

Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution
journal, March 1995

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