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Telomerization of acrylic monomers with iodoform

Journal Article · · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
OSTI ID:7151121

This paper studies the homolytic addition and telomerization reactions of iodoform with CHI/sub 3/. It is shown that together with dimethylformamide, iron pentacarbonyl initiates the telomerization of acrylonitrile, methyl acrylate, and methyl methacrylate with idoform, resulting in the formation of telomeric homologs of the series CHI/sub 2/ (CH/sub 2/CRI) /SUB n/ /SUP R/ (n = 1, 2; R = H, Ch/sub 3/; R' = CN, COOCH/sub 3/).

Research Organization:
A.N. Nesmeyanov Institute of Heteroorganic Chemistry, Moscow
OSTI ID:
7151121
Journal Information:
Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:10,PT.1; ISSN BACCA
Country of Publication:
United States
Language:
English