Iron pentacarbonyl-halogen-initiated reaction of ethyl acetoacetate and acetylacetone with acrylic monomers

Journal Article · Mon May 20 00:00:00 EDT 1985 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

OSTI ID:7251730

Amriev, R A; Abdulkina, Z A; Friedlina, R K; Velichko, F K

The authors have found that ethyl acetoacentate (EAA) and acetylacetone add to the double bond of acrylic monomers in the presence of the initiating system Fe(CO)/sub 5/ + Br/sub 2/(IS). The iron pentacarbonyl-bromine system initiates the addition reactions of ethyl acetoacetate and acetylacetone with the double bonds of acrylic monomers.

• Research Organization: A.N. Nesmeyanov Institute of Heterooganic Compounds, Academy of Sciences, Moscow
• OSTI ID: 7251730
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 33:11, PT. 2; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETOACETIC ACID ESTERS
ACETYLACETONE
ACRYLATES
BROMINE COMPOUNDS
CARBON 13
CARBON ISOTOPES
CARBONYLS
CARBOXYLIC ACID ESTERS
CARBOXYLIC ACID SALTS
CATALYSIS
CATALYTIC EFFECTS
CHELATING AGENTS
CHEMICAL BONDS
CHEMICAL REACTION KINETICS
ESTERS
EVEN-ODD NUCLEI
HALOGEN COMPOUNDS
HETEROGENEOUS CATALYSIS
IODINE COMPOUNDS
IRON COMPOUNDS
ISOTOPES
KETONES
KINETICS
LIGHT NUCLEI
METHACRYLATES
MONOMERS
NMR SPECTRA
NUCLEI
ORGANIC COMPOUNDS
REACTION KINETICS
REAGENTS
SPECTRA
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
TRANSITION ELEMENT COMPOUNDS
VINYL MONOMERS