Anion radicals of acrylic monomers in $gamma$-irradiated organic glasses at 77$sup 0$K

Journal Article · Tue May 01 00:00:00 EDT 1973 · J. Polym. Sci., Polym. Lett. Ed., v. 11, no. 5, pp. 309-312

DOI:https://doi.org/10.1002/pol.1973.130110503· OSTI ID:4367714

Gillbro, T

Electron spin resonance studies on methyl methacrylate, methyl acrylate, ethyl acrylate, allyl methacrylate, acrolein, acrylamide, acrylic acid, crotonic acid, and methyl crotonate are reported. Acrylic monomers gamma irradiated in the dark at 77 deg K in dried organic glasses give rise to ESR spectra that are easily photobleached. Study of these spectra suggests that anion radicals are formed from the acrylics in gamma-irradiated glasses of 2methyltetrahydrofuran, 3- methylpentane, and 3-methylhexane. (LK)

• Research Organization: Swedish Research Councils's Lab., Nykoeping, Sweden
• Sponsoring Organization: USDOE
• NSA Number: NSA-29-009952
• OSTI ID: 4367714
• Journal Information: J. Polym. Sci., Polym. Lett. Ed., v. 11, no. 5, pp. 309-312, Journal Name: J. Polym. Sci., Polym. Lett. Ed., v. 11, no. 5, pp. 309-312; ISSN JPYBA
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

*ACROLEIN-- CHEMICAL RADIATION EFFECTS
*ACRYLAMIDE-- CHEMICAL RADIATION EFFECTS
*ACRYLIC ACID ESTERS-- CHEMICAL RADIATION EFFECTS
*ACRYLIC ACID-- CHEMICAL RADIATION EFFECTS
*CROTONIC ACID-- CHEMICAL RADIATION EFFECTS
*METHACRYLIC ACID ESTERS-- CHEMICAL RADIATION EFFECTS
*METHYL METHACRYLATE-- CHEMICAL RADIATION EFFECTS
ALKANES
ELECTRON SPIN RESONANCE
FURANS
GAMMA RADIATION
LOW TEMPERATURE
N40300* --Chemistry--Radiation Chemistry
RADIATION CHEMISTRY
RADICALS
VISIBLE RADIATION METHYL METHACRYLATE