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Addition of iodoform to vinyl chloride in the presence of iron pentacarbonyl

Journal Article · · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
OSTI ID:7222510

The authors found that iodoform adds to vinyl chloride in the presence of Fe(CO)/sub 5/ + DMF systems to form 1,1,3-triiodo-3chloropropane and 1,1,3,3-tetraiodopropane. The replacement of chlorine by iodine occurs in 1,1,3-triiodo-3-chloropropane in a mixture of this compound and iodoform in the presence of iron pentacarbonyl to form 1,1,3,3-tetraiodopropane.

Research Organization:
A.N. Nesmeyanov Institute of Heteroorganic Compounds, Moscow
OSTI ID:
7222510
Journal Information:
Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 33:11, PT. 2; ISSN BACCA
Country of Publication:
United States
Language:
English