Kinetic model of the decomposition of azobisisobutyronitrilein the presence of organoaluminum compounds

Journal Article · Mon Sep 01 00:00:00 EDT 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00953208· OSTI ID:6772294

Matkovskii, P E

An analysis of the kinetic mechanisms of the liberation of gaseous products and the determination of the quantitative characteristics of the basic stages of decomposition of azobisisobutyronitrile (AIBN) in the presence of organoaluminum compounds (OAC) are reported. Calculations were performed on a computer, and it was shown by the calculations that the proposed kinetic model of the decomposition of AIBN in the presence of organoaluminum compounds permits quantitatively explaining all of the kinetic effects observed.

• Research Organization: Institute of Physical Chemistry, Chernogolovka
• OSTI ID: 6772294
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 35:3; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKANES
ALKENES
ALUMINIUM COMPOUNDS
AZO COMPOUNDS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
COMPARATIVE EVALUATIONS
CYCLOALKANES
DECALIN
DECOMPOSITION
EQUATIONS
ETHYLENE
FLUIDS
GASES
HYDROCARBONS
KINETIC EQUATIONS
KINETICS
MATHEMATICAL MODELS
MEDIUM TEMPERATURE
NITRILES
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
QUANTITY RATIO
REACTION KINETICS
TEMPERATURE EFFECTS
YIELDS