Effect of the nature of the organoaluminum compound on the direction of the reaction with xenon difluoride

Journal Article · Wed Aug 20 04:00:00 EDT 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00952953· OSTI ID:6476072

Bulgakov, R G; Yakovlev, V N; Maistrenko, G Ya; Tolstikov, G A; Kazakov, V P

In the authors previous work, they reported the chemiluminescence of organoaluminum compounds (OAC) upon oxidation by XeF/sub 2/ in solution. In the present work, gas-liquid chromatography, elemental and gas volumetric analysis, F- and Cl-electrode-selective potentiometry, and chemiluminescence were used to determine that the attack by XeF/sub 2/ in the reaction of XeF/sub 2/ with OAC such as Et/sub 3/Al (I), (EtO)/sub 2/AlEt (II), Et/sub 2/AlCl (III), and (t-Bu)/sub 2/AIH (IV) proceeds only at the Al-R bond. The C-H bonds of the alkyl groups of OAC do not participate in this reaction, which indicates the possibility of using the reaction of OAC and XeF/sub 2/ for the synthesis of OAC with an Al-F bond.

• Research Organization: Institute of Chemistry, Ufa, USSR
• OSTI ID: 6476072
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 35:2; ISSN BACCA
• Country of Publication: United States
• Language: Russian

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKANES
ALUMINIUM CHLORIDES
ALUMINIUM COMPLEXES
ALUMINIUM COMPOUNDS
ALUMINIUM FLUORIDES
CHEMICAL ANALYSIS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMILUMINESCENCE
CHLORIDES
CHLORINE COMPOUNDS
CHROMATOGRAPHY
COMPLEXES
ETHANE
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
ION SELECTIVE ELECTRODE ANALYSIS
KINETICS
LUMINESCENCE
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDATION
QUANTITATIVE CHEMICAL ANALYSIS
QUANTITY RATIO
RARE GAS COMPOUNDS
REACTION KINETICS
REDOX POTENTIAL
SEPARATION PROCESSES
SYNTHESIS
VOLUMETRIC ANALYSIS
XENON COMPOUNDS
XENON FLUORIDES
YIELDS