Bright chemiluminescence upon the oxidation of organoaluminum compounds by xenon difluoride
Journal Article
·
· Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
OSTI ID:7129173
Chemiluminescence was found in the reaction of XeF/sub 2/ with (C/sub 2/H/sub 5/)/sub 3/A1 (TEA), (i-C/sub 4/H/sub 9/)/sub 3/ X A1, (i-C/sub 4/H/sub 9/)/sub 2/A1H, and (C/sub 2/H/sub 5/)A1C1/sub 2/ in CH/sub 2/C1/sub 2/. The product composition indicates a redox reaction of XeF/sub 2/ with the A1-C bond. The kinetic curves for the chemiluminescence intensity which feature brightness maxima indicate luminescence excitation in reactions of unstable intermediates. Organoxenon compounds have been proposed for these intermediates.
- Research Organization:
- Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa
- OSTI ID:
- 7129173
- Journal Information:
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 33:11, PT. 2; ISSN BACCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALUMINIUM COMPOUNDS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMILUMINESCENCE
CHROMATOGRAPHY
FLUORIDES
FLUORINE COMPOUNDS
GAS CHROMATOGRAPHY
HALIDES
HALOGEN COMPOUNDS
KINETICS
LUMINESCENCE
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDATION
RARE GAS COMPOUNDS
REACTION INTERMEDIATES
REACTION KINETICS
REDOX REACTIONS
SEPARATION PROCESSES
XENON COMPOUNDS
XENON FLUORIDES
400201* -- Chemical & Physicochemical Properties
ALUMINIUM COMPOUNDS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMILUMINESCENCE
CHROMATOGRAPHY
FLUORIDES
FLUORINE COMPOUNDS
GAS CHROMATOGRAPHY
HALIDES
HALOGEN COMPOUNDS
KINETICS
LUMINESCENCE
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDATION
RARE GAS COMPOUNDS
REACTION INTERMEDIATES
REACTION KINETICS
REDOX REACTIONS
SEPARATION PROCESSES
XENON COMPOUNDS
XENON FLUORIDES