[Laser spectroscopy of hydrocarbon radicals]

Technical Report · Fri Jan 01 04:00:00 EST 1993

DOI:https://doi.org/10.2172/6666694· OSTI ID:6666694

Several hydrocarbon reactive intermediates (carbenes, biradicals, etc.) were prepared in a supersonic jet expansion. heats of formation were determined for the isosmeric C[sub 3]H[sub 2] carbenes. Fits were made to the photoelectron spectra of c-C[sub 3]H[sub 2] and c- C[sub 4]H[sub 4]. Resonant MPI (multi-photon ionization ) spectra were obtained for allyl radical and its deuterated isotopomers.

• Research Organization: Harvard Univ., Boston, MA (United States)
• Sponsoring Organization: DOE; USDOE, Washington, DC (United States)
• DOE Contract Number: FG02-90ER14132
• OSTI ID: 6666694
• Report Number(s): DOE/ER/14132-3; ON: DE93012555
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKYL RADICALS
ALLYL RADICALS
CARBENES
ELECTRON SPECTROSCOPY
ENERGY LEVELS
ENTHALPY
EXCITED STATES
FLUID FLOW
FORMATION HEAT
HYDROCARBONS
LASER SPECTROSCOPY
ORGANIC COMPOUNDS
PHOTOELECTRON SPECTROSCOPY
PHYSICAL PROPERTIES
RADICALS
REACTION HEAT
REACTION INTERMEDIATES
RESEARCH PROGRAMS
SPECTROSCOPY
SUPERSONIC FLOW
THERMODYNAMIC PROPERTIES
VIBRATIONAL STATES