Laser spectroscopy of hydrocarbon radicals
Conference
·
OSTI ID:139859
- Harvard Univ., Cambridge, MA (United States)
The author reports the application of supersonic jet flash pyrolysis to the specific preparation of a range of organic radicals, biradicals, and carbenes in a skimmed molecular beam. Each species was produced cleanly and specifically, with little or no secondary reactions by the thermal dissociation of appropriately designed and synthesized organic precursors. Photoelectron spectra of the three isomeric C{sub 3}H{sub 2} carbenes, ortho-benzyne, and the {alpha},3-dehydrotoluene biradical, were used to establish adiabatic ionization potentials for use in thermochemical determinations.
- Research Organization:
- Brookhaven National Lab., Upton, NY (United States)
- DOE Contract Number:
- FG02-90ER14132
- OSTI ID:
- 139859
- Report Number(s):
- BNL--48923; CONF-9306172--; ON: DE93015758
- Country of Publication:
- United States
- Language:
- English
Similar Records
[Laser spectroscopy of hydrocarbon radicals]
[Laser spectroscopy of hydrocarbon radicals]
Rotationally resolved threshold photoelectron spectrum of the methyl radical
Technical Report
·
Sat May 01 00:00:00 EDT 1993
·
OSTI ID:10143556
[Laser spectroscopy of hydrocarbon radicals]
Technical Report
·
Thu Dec 31 23:00:00 EST 1992
·
OSTI ID:6666694
Rotationally resolved threshold photoelectron spectrum of the methyl radical
Journal Article
·
Sun Feb 14 23:00:00 EST 1993
· Journal of Chemical Physics; (United States)
·
OSTI ID:6881508