[Laser spectroscopy of hydrocarbon radicals]
Several hydrocarbon reactive intermediates (carbenes, biradicals, etc.) were prepared in a supersonic jet expansion. heats of formation were determined for the isosmeric C{sub 3}H{sub 2} carbenes. Fits were made to the photoelectron spectra of c-C{sub 3}H{sub 2} and c- C{sub 4}H{sub 4}. Resonant MPI (multi-photon ionization?) spectra were obtained for allyl radical and its deuterated isotopomers.
- Research Organization:
- Harvard Univ., Boston, MA (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG02-90ER14132
- OSTI ID:
- 10143556
- Report Number(s):
- DOE/ER/14132--3; ON: DE93012555
- Country of Publication:
- United States
- Language:
- English
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