Decomposition of a palladium cluster under the action of electrophilic reagents. Crystal and molecular structure of (N,N'-2,9-dimethyl-1,10-phenanthroline)(phenanthrene-9,10-diolato)palladium

Journal Article · Thu Jan 01 04:00:00 EST 1987 · Sov. J. Coordinat. Chem.; (United States)

OSTI ID:6158672

Yanovskii, A I; Zagorodnikov, V P; Struchkov, Yu T

The reaction of the cluster (Pd/sub 4/L(OAc)/sub 2/H/sub x/)/sub n/ (where L = 2,9-dimethyl-1,10-phenanthroline) with 9,10-phenanthrenequinone (phenQ) DMFA, 20/sup 0/C, 2 h) gives the mononuclear complex Pd(2+)LPd(phenQ) (I) (the yield was 60%). Compound I is a dark blue crystalline substance, which is stable in air and insoluble in ordinary solvents. The structure of compound I has been established by x-ray diffraction analysis (3406 reflections, refinement to R = 0.023 and R/sub w/ = 0.031). The crystals of compound I are monoclinic, and the unit-cell parameters are: a = 14.949, b = 7.942, c = 18.07 A, ..beta.. = 108.44/sup 0/, Z = 4, space group P2/sub 1//c. The phenanthrenequinone ligand in compound I is present in the form of the dianion of phenanthrenehydroquinone, and the Pd atom has a square-planar configuration. The mean distances are: Pd-O, 1.983 and 1.987 A; Pd-N, 2.053 and 2.061 A. The intrachelate OPdO and NPdN bond angles equal 83.41 and 82.21/sup 0/, respectively.

• Research Organization: A.N. Nesmeyanov Institute of Organometallic Compounds, USSR
• OSTI ID: 6158672
• Journal Information: Sov. J. Coordinat. Chem.; (United States), Journal Name: Sov. J. Coordinat. Chem.; (United States) Vol. 12:3; ISSN SJCCD
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360602 -- Other Materials-- Structure & Phase Studies
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AROMATICS
AZAARENES
BINDING ENERGY
BOND ANGLE
BOND LENGTHS
CATALYTIC EFFECTS
CHEMICAL REACTIONS
COHERENT SCATTERING
COMPLEXES
CONDENSED AROMATICS
COORDINATION VALENCES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DECOMPOSITION
DIFFRACTION
DIMENSIONS
DIMERIZATION
ELECTRONS
ELECTROSTATICS
ELEMENTARY PARTICLES
ENERGY
FERMIONS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYDROGENATION
ISOMERIZATION
LATTICE PARAMETERS
LENGTH
LEPTONS
LIGANDS
MOLECULAR STRUCTURE
MONOCLINIC LATTICES
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SOLVENTS
PALLADIUM COMPLEXES
PHENANTHRENE
PHENANTHROLINES
POLYMERIZATION
QUINONES
SCATTERING
SOLVENTS
SPACE GROUPS
TRANSITION ELEMENT COMPLEXES
VALENCE
X-RAY DIFFRACTION