Syntheses of 2,9-bis(halomethyl)-1,10-phenanthrolines: Potential robust ligands for metal oxidation catalysts
Journal Article
·
· Journal of Organic Chemistry; (United States)
- Univ. of Florida, Gainesville (United States)
Free radical halogenation of 2,9-dimethyl-1,10-phenanthroline with N-bromosuccinimide and N-chlorosuccinimide form the known [alpha]-methyl derivatives 2,9-bis(trihalomethyl)-1,10-phenanthrolines. The compound 2,9-bis(trichloromethyl)-1,10-phenanthroline can be used for one-step syntheses of oxidatively resistant fluoro-and partially reduced chloromethyl derivatives capable of coordination to metal oxidation catalysts. 7 refs., 1 fig.
- OSTI ID:
- 6078897
- Journal Information:
- Journal of Organic Chemistry; (United States), Vol. 58:7; ISSN 0022-3263
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CATALYSTS
CHEMICAL PREPARATION
PHENANTHROLINES
LIGANDS
METALS
OXIDATION
RADICALS
AROMATICS
AZAARENES
CHEMICAL REACTIONS
ELEMENTS
HETEROCYCLIC COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
SYNTHESIS
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CATALYSTS
CHEMICAL PREPARATION
PHENANTHROLINES
LIGANDS
METALS
OXIDATION
RADICALS
AROMATICS
AZAARENES
CHEMICAL REACTIONS
ELEMENTS
HETEROCYCLIC COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
SYNTHESIS
400201* - Chemical & Physicochemical Properties