Syntheses of 2,9-bis(halomethyl)-1,10-phenanthrolines: Potential robust ligands for metal oxidation catalysts
Journal Article
·
· Journal of Organic Chemistry; (United States)
- Univ. of Florida, Gainesville (United States)
Free radical halogenation of 2,9-dimethyl-1,10-phenanthroline with N-bromosuccinimide and N-chlorosuccinimide form the known [alpha]-methyl derivatives 2,9-bis(trihalomethyl)-1,10-phenanthrolines. The compound 2,9-bis(trichloromethyl)-1,10-phenanthroline can be used for one-step syntheses of oxidatively resistant fluoro-and partially reduced chloromethyl derivatives capable of coordination to metal oxidation catalysts. 7 refs., 1 fig.
- OSTI ID:
- 6078897
- Journal Information:
- Journal of Organic Chemistry; (United States), Journal Name: Journal of Organic Chemistry; (United States) Vol. 58:7; ISSN 0022-3263; ISSN JOCEAH
- Country of Publication:
- United States
- Language:
- English
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·
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AROMATICS
AZAARENES
CATALYSTS
CHEMICAL PREPARATION
CHEMICAL REACTIONS
ELEMENTS
HETEROCYCLIC COMPOUNDS
LIGANDS
METALS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDATION
PHENANTHROLINES
RADICALS
SYNTHESIS
400201* -- Chemical & Physicochemical Properties
AROMATICS
AZAARENES
CATALYSTS
CHEMICAL PREPARATION
CHEMICAL REACTIONS
ELEMENTS
HETEROCYCLIC COMPOUNDS
LIGANDS
METALS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDATION
PHENANTHROLINES
RADICALS
SYNTHESIS