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Temperature dependences of the rates of the radical-radical reactions OH+NF/sub 2/ and HO/sub 2/+NF/sub 2/

Journal Article · · Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:6083061
The reactions of NF/sub 2/ with HO/sub 2/ and OH radicals were investigated with the aid of a combination ESR/LMR spectrometer. For the reaction HO/sub 2/+NF/sub 2/..-->..F+OH+FNO k/sub HO/sub 2// = (2.4 +/- 0.8) x 10/sup -11/ (-680 +/- 150lt. slashtau), cm/sup 2//sec, at 300-615 K and for the reaction OH+NF/sub 2/..-->..FNO+HF k/sub OH/ = (6.8 +/- 0/4) x 1-/sup -12/ exp (230 +/- 30lt. slashtau), cm/sup 2//sec, at 300-820 K.
Research Organization:
Institute of Chemical Physics, Moscow (USSR)
OSTI ID:
6083061
Journal Information:
Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 29:2; ISSN KICAA
Country of Publication:
United States
Language:
English