Mechanisms and temperature dependence of the rates of reactions between NF/sub 2/ radicals and oxygen and nitrogen atoms

Journal Article · Fri Jul 01 04:00:00 EDT 1988 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:6084876

Rozenshtein, V B; Bedzhanyan, Yu R; Politenkova, G G

Reactions of NF/sub 2/ with O and N under flow conditions were investigated using a combined ESR/LMR spectrometer. For the reaction O + NF/sub 2/ ..-->.. F + FNO k/sub o/ = (1.25 +- 0.25) exp ((0 +- 90)/T), cm/sup 3//sec for T = 300-750 K, for the reaction N + NF/sub 2/ ..-->.. F + N/sub 2/F k/sub N/ = (1.4 /times/ 0.2) /times/ 10/sup /minus/11/ /times/ exp ((/minus/95 +- 60)/T), cm/sup 3//sec for T = 300-795 K.

• Research Organization: Institute of Chemical Physics, Moscow (USSR)
• OSTI ID: 6084876
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 29:1; ISSN KICAA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
42 ENGINEERING
420300* -- Engineering-- Lasers-- (-1989)
ATOMS
CATALYSIS
CHALCOGENIDES
CHEMICAL LASERS
CHEMICAL REACTION KINETICS
CHEMICAL REACTORS
ELECTRON SPIN RESONANCE
ELEMENTS
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HETEROGENEOUS CATALYSIS
KINETICS
LASER MATERIALS
LASERS
MAGNETIC RESONANCE
MATERIALS
MATERIALS TESTING
MINERALS
NITROGEN
NITROGEN COMPOUNDS
NITROGEN FLUORIDES
NONMETALS
OXIDE MINERALS
OXIDES
OXYGEN
OXYGEN COMPOUNDS
QUARTZ
RADICALS
REACTION KINETICS
RECOMBINATION
RESONANCE
SILICON COMPOUNDS
SILICON OXIDES
TEMPERATURE DEPENDENCE
TESTING