Oxidation of CS sub 2 by reaction with OH. 2. Yields of HO sub 2 and SO sub 2 in oxygen

Journal Article · Thu Mar 22 04:00:00 EST 1990 · Journal of Physical Chemistry; (USA)

DOI:https://doi.org/10.1021/j100369a037· OSTI ID:6540005

Lovejoy, E R; Murrells, T P; Ravishankara, A R; Howard, C J ^[1]

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1. National Oceanic and Atmospheric Administration, Boulder, CO (USA) Univ. of Colorado, Boulder (USA)

The products of the OH-initiated oxidation of CS{sub 2} have been investigated. Analysis of the OH loss and the HS production using a laser magnetic resonance (LMR) discharge-flow apparatus yielded k{sub 1} < 3 {times} 10{sup {minus}15} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1} for the reaction OH + CS{sub 2} {yields} HS + OCS (1) (340 K and 5 Torr (He)). HO{sub 2} was identified by LMR detection as a major product from this chemistry.

• OSTI ID: 6540005
• Journal Information: Journal of Physical Chemistry; (USA), Journal Name: Journal of Physical Chemistry; (USA) Vol. 94:6; ISSN JPCHA; ISSN 0022-3654
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical &amp; Physicochemical Properties
54 ENVIRONMENTAL SCIENCES
540110*
ATMOSPHERIC CHEMISTRY
CARBON COMPOUNDS
CARBON SULFIDES
CHALCOGENIDES
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
DATA
DATA ANALYSIS
DECOMPOSITION
EARTH ATMOSPHERE
EXPERIMENTAL DATA
INFORMATION
MEASURING INSTRUMENTS
MEASURING METHODS
NUMERICAL DATA
OXIDATION
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
SULFIDES
SULFUR COMPOUNDS
TROPOSPHERE
YIELDS