ANION EXCHANGE OF METAL COMPLEXES. THE INDIUM-CHLORIDE SYSTEM COMPARISON OF RESIN AND LIQUID ANION EXCHANGE

Technical Report · Sat Sep 01 04:00:00 EDT 1962

OSTI ID:4765005

Maydan, D; Marcus, Y

Distribution measurements were made of tracer indium ions between Dowex- 1 quaternary ammonium anion exchange resin chloride, and aqueous solutions of sodium chloride. Correcting the distribution data for electrolyte invasion permitted calculation of complex formation parameters for the indium-- chloride system. The same set of parameters also describes the liquid distribution data obtained with triisooctylammonium chloride in zylene and sodium chloride and dtlute hydrochloric acid solutions. The species predominant in the resin phase is InCl/sub 4/, those in the liquid amine phases are RInCl/sub 4/ and R/sub 3/ InCl/sub 6/, depending on concentration. The difference is attributed to differences in the effective dielectric constants of the media. (auth)

• Research Organization: Israel. Atomic Energy Commission, Rehovoth
• NSA Number: NSA-17-006181
• OSTI ID: 4765005
• Report Number(s): IA-780
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

AMINES
AMMONIUM COMPOUNDS
CHEMISTRY
DISTRIBUTION
DOWEX
HYDROCHLORIC ACID
INDIUM CHLORIDES
INDIUM COMPLEXES
ION EXCHANGE
ION EXCHANGE MATERIALS
MEASURED VALUES
RESINS
SEPARATION PROCESSES
SODIUM CHLORIDES
SOLUTIONS
WATER
XYLENE