THE ANION EXCHANGE OF METAL COMPLEXES. XII. THE CADMIUM AND MERCURY-HALIDE SYSTEMS

Journal Article · Mon Jul 01 04:00:00 EDT 1963 · Journal of Inorganic and Nuclear Chemistry (England) Merged with Inorg. Nucl. Chem. Lett. to form Polyhedron

DOI:https://doi.org/10.1016/0022-1902(63)80374-7· OSTI ID:4694713

Marcus, Y; Eliezer, I

The distribution of trace cadmium and mercury ions between Dowex-1 strong-base anion exchanger, and solutions of hydrochloric acid, lithium chloride and bromide, and sodium chloride, bromide, and iodide was measured. Resin ligand activity functions for these electrolyte-resin systems were obtained and used to show that the predominant complex species in both solution and resin, over the halide concentration range one M to saturation, is the tetrahalide. Only in hydrochloric acid but not in hydrobromic acid) is there evidence for other species, which may be the undissociated acids, as suggested in the literature. The results for the other electrolytes indicate the validity of the eifective ligand activity concept also in bromide and iodide solutions. (auth)

• Research Organization: Israel Atomic Energy Commission, Rehovoth
• NSA Number: NSA-17-028860
• OSTI ID: 4694713
• Report Number(s): IA-794; 0022-1902
• Journal Information: Journal of Inorganic and Nuclear Chemistry (England) Merged with Inorg. Nucl. Chem. Lett. to form Polyhedron, Journal Name: Journal of Inorganic and Nuclear Chemistry (England) Merged with Inorg. Nucl. Chem. Lett. to form Polyhedron Vol. Vol: 25; ISSN JINCA
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

CADMIUM COMPLEXES
CHEMISTRY
COMPLEXES
DISTRIBUTION
DOWEX
ELECTROLYTES
HYDROCHLORIC ACID
ION EXCHANGE
ION EXCHANGE MATERIALS
LIGANDS
LITHIUM BROMIDES
LITHIUM CHLORIDES
MEASURED VALUES
MERCURY COMPLEXES
RESINS
SODIUM BROMIDES
SODIUM CHLORIDES
SODIUM IODIDES
SOLUTIONS