ANION EXCHANGE OF METAL COMPLEXES. VIII. THE EFFECT OF THE SECONDARY CATION. THE ZINC-CHLORIDE SYSTEM

Technical Report · Sat Sep 01 04:00:00 EDT 1962

OSTI ID:4723592

Marcus, Y; Maydan, D

Distribution measurements were made of tracer radioactive zinc ions between Dowex-1 quaternary ammonium anion exchange resin, crosslinked by various amounts (2, 4, 8, 10, and 18%) of divinyl benzene, and aqueous solutions of chlorides of lithium, sodium, ammonium, potassium, and cesium and hydrochloric acid. The invasion of the various electrolytes into the resins was also measured. Expressing the electrolyte concertrations in terms of activity functions a = m gamma plus or minus and correcting the distribution coefficients for the electrolyte invasion yielded parallel curves for the various crosslinked resins. These may be described by a single set of complex formation parameters for the aqueous solutions, the same set for all alkali metal chlorides, and one parameter dependert on the crosslinking. (auth)

• Research Organization: Israel. Atomic Energy Commission, Rehovoth
• NSA Number: NSA-17-010588
• OSTI ID: 4723592
• Report Number(s): IA-764
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

AMMONIUM COMPOUNDS
BENZENE
CESIUM CHLORIDES
CHEMISTRY
CHLORIDES
CROSS- LINKING
DISTRIBUTION
DOWEX
ELECTROLYTES
HYDROCHLORIC ACID
ION EXCHANGE MATERIALS
LITHIUM CHLORIDES
MEASURED VALUES
POTASSIUM CHLORIDES
RESINS
SODIUM CHLORIDES
SOLUTIONS
VINYL RADICALS
WATER