The Adsorption of Zinc(II) on Anion-exchange Resins. I. The Secondary Cation Effect

Journal Article · Sun Dec 01 00:00:00 EST 1957 · Journal of Physical Chemistry

DOI:https://doi.org/10.1021/j150558a022· OSTI ID:4341439

Horne, R. A.

The adsorption of tracer quantities of zinc(II) on the anion-exchange resin Dowex l-X8 chloride from solutions of various chloride concentrations depends on the nature of the cation (secondary cation) of the supporting chloride electrolyte. Finally, the adsorption of zinc(ll) from LiCl, CaCl₂, MgCl₂, NaCl, LiCl and HCl, HCI, KCl, CsCl, NH₄Cl, and HONH₃Cl has been studied at 25 deg and the results interpreted in terms of ionic association of the secondary cation with anionic zinc(II) chloride complexes (a) in the resin and solution phases and (b) in the resin phase only.

• Research Organization: Massachusetts Inst. of Tech., Cambridge
• Sponsoring Organization: USDOE
• NSA Number: NSA-12-003613
• OSTI ID: 4341439
• Journal Information: Journal of Physical Chemistry, Vol. 61, Issue 12; Other Information: Orig. Receipt Date: 31-DEC-58; ISSN 0022-3654
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

CHEMISTRY
ADSORPTION
AMINES
AMMONIUM COMPOUNDS
ANIONS
CALCIUM CHLORIDES
CATIONS
CESIUM CHLORIDES
CHLORIDES
DOWEX
ELECTROLYTES
HYDROCHLORIC ACID
HYDROXIDES
HYDROXYLAMINE
ION EXCHANGE MATERIALS
LITHIUM CHLORIDES
MAGNESIUM CHLORIDES
POTASSIUM CHLORIDES
QUANTITY RATIO
RESINS
SODIUM CHLORIDES
SOLUTIONS
TRACE AMOUNTS
ZINC
ZINC COMPLEXES