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STUDY OF THE REACTION OF PLUTONIUM (IV) WITH ARSENAZO III (in Russian)

Journal Article · · Zh. Analit. Khim.
OSTI ID:4699474
Two series of complexes are formed by the interaction of plutonium(IV) with arsenazo III depending on the concentration of nitric acid. At the low nitric acid concentration ( ontrol migra- 0.1N) complexes with plutonium/ arsenazo III ratios of 1: 1 and 1: 2 are formed, whereas in solutions of high acidity (4 to 7 N) the ratios are 1:1, 1:2, and 1:3. Optimum conditions for the photometric determination of Pu are not less than the three-fold excess of arsenazo III and the concentration of nitric acid of 4 to 7 N. The molar extinction coefficient of the complex (with the component ratio of 1: 3) formed under these conditions is 136000. (auth)
Research Organization:
Originating Research Org. not identified
NSA Number:
NSA-17-025143
OSTI ID:
4699474
Journal Information:
Zh. Analit. Khim., Journal Name: Zh. Analit. Khim. Vol. Vol: 18
Country of Publication:
Country unknown/Code not available
Language:
Russian

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