PHOTOMETRIC STUDY OF THE INTERACTION OF URANIUM(IV) WITH ARSENAZO III (in Russian)
Journal Article
·
· Zh. Analit. Khim.
OSTI ID:4699402
The interaction of uranium(IV) with arsenazo III in HCl solutions was studied by a photometric method. It is shown that U(IV) reacts with arsenazo III forming two series of complexes depending on the HCl concentration. The complexes are quite different in their optical characteristics. In about 0.1M HCl solutions complexes with the U/arsenazo III ratio equal to 1: 1 and 1: 2, and in 6 to 8M HCl solutions complexes with the U/arsenazo III ratio equal to 1: 1, 1:2, and 1:3 are formed. The photometric determination of U(IV) with arsenazo III is the most sensitive (the molar extinction coefficient at 665 m is 127000) when the HCl concentration is 6 to 8M, and the amount of arsenazo III is not less than 3 times as much as the amount of U present. (auth)
- Research Organization:
- Originating Research Org. not identified
- NSA Number:
- NSA-17-025151
- OSTI ID:
- 4699402
- Journal Information:
- Zh. Analit. Khim., Journal Name: Zh. Analit. Khim. Vol. Vol: 18
- Country of Publication:
- Country unknown/Code not available
- Language:
- Russian
Similar Records
STUDY OF THE REACTION OF PLUTONIUM (IV) WITH ARSENAZO III
EXTRACTION-PHOTOMETRIC METHOD FOR THE DETERMINATION OF PROTACTINIUM(V) WITH ARSENAZO III
INTERACTION OF URANIUM(VI) WITH ARSENAZO III STRONGLY ACID SOLUTIONS
Journal Article
·
Thu Feb 28 23:00:00 EST 1963
· Zh. Analit. Khim.
·
OSTI ID:4699474
EXTRACTION-PHOTOMETRIC METHOD FOR THE DETERMINATION OF PROTACTINIUM(V) WITH ARSENAZO III
Journal Article
·
Sun Jul 01 00:00:00 EDT 1962
· Zhur. Anal. Khim.
·
OSTI ID:4791455
INTERACTION OF URANIUM(VI) WITH ARSENAZO III STRONGLY ACID SOLUTIONS
Journal Article
·
Mon Dec 31 23:00:00 EST 1962
· Zhur. Analit. Khim.
·
OSTI ID:4727540