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Ca and O ion implantation doping of GaN

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.115634· OSTI ID:279718
 [1];  [2];  [3];  [4]
  1. Sandia National Laboratories, Albuquerque, New Mexico 87185-0603 (United States)
  2. Hughes Research Laboratories, Malibu, California 90265 (United States)
  3. Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States)
  4. EMCORE Corporation, Somerset, New Jersey 08873 (United States)

{ital p}- and {ital n}-type doping of GaN have been realized by ion implantation of Ca and O, respectively. Rapid thermal annealing at 1100{degree}C or higher is required to achieve {ital p}-type conduction in Ca or Ca+P implanted samples with an estimated ionization level of 169 meV and a corresponding activation efficiency of {approximately}100{percent}. This is the first experimental report of an acceptor species in GaN, other than Mg, with an ionization energy level less than 180 meV. O-implanted GaN displays an ionization level of {approximately}29 meV but with an activation efficiency of only 3.6{percent} after a 1050{degree}C anneal that may result from insufficient vacancy generation for the lighter O ion or from the existence of a second, deeper O energy level. Neither Ca or O displayed measurable redistribution, based on secondary ion mass spectrometry measurements, even after a 1125{degree}C anneal. {copyright} {ital 1996 American Institute of Physics.}

Research Organization:
Sandia National Laboratory
DOE Contract Number:
AC04-94AL85000
OSTI ID:
279718
Journal Information:
Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 14 Vol. 68; ISSN APPLAB; ISSN 0003-6951
Country of Publication:
United States
Language:
English

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