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P- and N-type implantation doping of GaN with Ca and O

Technical Report ·
DOI:https://doi.org/10.2172/238549· OSTI ID:238549
 [1];  [2];  [3];  [4]
  1. Sandia National Labs., Albuquerque, NM (United States)
  2. Hughes Research Lab., Malibu, CA (United States)
  3. Univ. of Florida, Gainesville, FL (United States). Dept. of Materials Science and Engineering
  4. Emcore Corp., Somerset, NJ (United States)

III-N photonic devices have made great advances in recent years following the demonstration of doping of GaN p-type with Mg and n-type with Si. However, the deep ionization energy level of Mg in GaN ({approximately} 160 meV) limits the ionized of acceptors at room temperature to less than 1.0% of the substitutional Mg. With this in mind, the authors used ion implantation to characterize the ionization level of Ca in GaN since Ca had been suggested by Strite to be a shallow acceptor in GaN. Ca-implanted GaN converted from n-to-p type after a 1,100 C activation anneal. Variable temperature Hall measurements give an ionization level at 169 meV. Although this level is equivalent to that of Mg, Ca-implantation may have advantages (shallower projected range and less straggle for a given energy) than Mg for electronic devices. In particular, the authors report the first GaN device using ion implantation doping. This is a GaN junction field effect transistor (JFET) which employed Ca-implantation. A 1.7 {micro}m JFET had a transconductance of 7 mS/mm, a saturation current at 0 V gate bias of 33 mA/mm, a f{sub t} of 2.7 GHz, and a f{sub max} of 9.4 GHz. O-implantation was also studied and shown to create a shallow donor level ({approximately} 25 meV) that is similar to Si. SIMS profiles of as-implanted and annealed samples showed no measurable redistribution of either Ca or O in GaN at 1,125 C.

Research Organization:
Sandia National Labs., Albuquerque, NM (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States); National Science Foundation, Washington, DC (United States); Office of Naval Research, Washington, DC (United States)
DOE Contract Number:
AC04-94AL85000
OSTI ID:
238549
Report Number(s):
SAND--96-1053C; CONF-960401--25; ON: DE96010745; CNN: Grant NSF DMR-9421109; Grant ONR N00014-92-5-1895
Country of Publication:
United States
Language:
English

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