InxGa1-xAs Nanowires on Silicon: One-Dimensional Heterogeneous Epitaxy, Bandgap Engineering, and Photovoltaics

Shin, Jae Cheol; Kim, Kyou Hyun; Yu, Ki Jun; Hu, Hefei; Yin, Leijun; Ning, Cun-Zheng; Rogers, John A.; Zuo, Jian-Min; Li, Xiuling

doi:10.1021/nl202676b

In_xGa_1-xAs Nanowires on Silicon: One-Dimensional Heterogeneous Epitaxy, Bandgap Engineering, and Photovoltaics

Journal Article · Mon Oct 03 00:00:00 EDT 2011 · Nano Letters

DOI:https://doi.org/10.1021/nl202676b· OSTI ID:1875522

Shin, Jae Cheol ^[1]; Kim, Kyou Hyun ^[2]; Yu, Ki Jun ^[2]; Hu, Hefei ^[2]; Yin, Leijun ^[3]; Ning, Cun-Zheng ^[3]; Rogers, John A. ^[2]; Zuo, Jian-Min ^[2]; Li, Xiuling ^[2]

Univ. of Illinois, Urbana, IL (United States); Arizona State Univ., Tempe, AZ (United States); University of Illinois
Univ. of Illinois, Urbana, IL (United States); Arizona State Univ., Tempe, AZ (United States)
Arizona State Univ., Tempe, AZ (United States)

We report on the one-dimensional (1D) heteroepitaxial growth of In_xGa_1-xAs (x = 0.2–1) nanowires (NWs) on silicon (Si) substrates over almost the entire composition range using metalorganic chemical vapor deposition (MOCVD) without catalysts or masks. The epitaxial growth takes place spontaneously producing uniform, nontapered, high aspect ratio NW arrays with a density exceeding 1 × 10⁸/cm². NW diameter (~30–250 nm) is inversely proportional to the lattice mismatch between In_xGa_1-xAs and Si (~4–11%), and can be further tuned by MOCVD growth condition. Remarkably, no dislocations have been found in all composition In_xGa_1-xAs NWs, even though massive stacking faults and twin planes are present. Indium rich NWs show more zinc-blende and Ga-rich NWs exhibit dominantly wurtzite polytype, as confirmed by scanning transmission electron microscopy (STEM) and photoluminescence spectra. Solar cells fabricated using an n-type In_0.3Ga_0.7As NW array on a p-type Si(111) substrate with a ~ 2.2% area coverage, operates at an open circuit voltage, V_oc, and a short circuit current density, J_sc, of 0.37 V and 12.9 mA/cm², respectively. Furthermore, this work represents the first systematic report on direct 1D heteroepitaxy of ternary In_xGa_1-xAs NWs on silicon substrate in a wide composition/bandgap range that can be used for wafer-scale monolithic heterogeneous integration for high performance photovoltaics.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: NSF STC; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: FG02-01ER45923; FG02-07ER46453; FG02-07ER46471

OSTI ID:: 1875522

Journal Information:: Nano Letters, Journal Name: Nano Letters Journal Issue: 11 Vol. 11; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

77 NANOSCIENCE AND NANOTECHNOLOGY
III-V on Si
InAs nanowire
InGaAs nanowire
electrical conductivity
epitaxy
heterogeneous integration
indium arsenide
nanowire
nanowire arrays
silicon
solar cell