polyMOF Formation from Kinked Polymer Ligands via ortho -Substitution

Palomba, Joseph M.; Ayala, Sergio; Cohen, Seth M.

doi:10.1002/ijch.201800094

polyMOF Formation from Kinked Polymer Ligands via ortho -Substitution

Journal Article · Thu Sep 20 00:00:00 EDT 2018 · Israel Journal of Chemistry

DOI:https://doi.org/10.1002/ijch.201800094· OSTI ID:1780602

Palomba, Joseph M. ^[1]; Ayala, Sergio ^[2]; ^[2]

Univ. of California, San Diego, CA (United States); U.C. San Diego
Univ. of California, San Diego, CA (United States)

Reticular chemistry is an important tool in the crystal engineering of metal-organic frameworks (MOFs). Isoreticular chemistry allows for the preparation of MOFs of the same topology from ligands with related geometries. Here in this work, reticular chemistry is used to explore the scope of polyMOFs, which are frameworks synthesized from polymer ligands. “Linked” ortho-substituted benzene dicarboxylate polymer ligands with varying length alkyl spacers were used to synthesize polyMOFs and elucidate the effects of polymer architecture on resulting crystal formation. It was found that these “kinked” polymer ligands were able to form polyIRMOF architectures, but did not readily form polyUiO-66 topologies.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, San Diego, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-08ER46519

OSTI ID:: 1780602

Alternate ID(s):: OSTI ID: 1610001

Journal Information:: Israel Journal of Chemistry, Journal Name: Israel Journal of Chemistry Journal Issue: 9-10 Vol. 58; ISSN 0021-2148

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
ligand design
metal-organic frameworks
organic inorganic hybrid materials
polymers
reticular chemistry

polyMOF Formation from Kinked Polymer Ligands via ortho -Substitution

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References (17)

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