Hierarchical structure and porosity in UiO-66 polyMOFs

Ayala, Jr., Sergio; Zhang, Zhenjie; Cohen, Seth M.

doi:10.1039/c6cc10225e

Hierarchical structure and porosity in UiO-66 polyMOFs

Journal Article · Tue Feb 21 00:00:00 EST 2017 · ChemComm

DOI:https://doi.org/10.1039/c6cc10225e· OSTI ID:1780606

Ayala, Jr., Sergio ^[1]; Zhang, Zhenjie ^[2]; ^[2]

Univ. of California, San Diego, La Jolla, CA (United States); U.C. San Diego
Univ. of California, San Diego, La Jolla, CA (United States)

The first polymer–MOF hybrid material (polyMOF) with a UiO-66 architecture is reported, prepared from polymers with varying alkyl spacers, molecular weights, and dispersities. Here, with appropriate spacing, mesoporous UiO-66 polyMOF can be obtained having an uncommon, interlaced crystal morphology, suggesting that polyMOFs can be used to generate MOF materials with hierarchical architectures.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, San Diego, La Jolla, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: FG02-08ER46519

OSTI ID:: 1780606

Alternate ID(s):: OSTI ID: 1535114

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 21 Vol. 53; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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