Hierarchical structure and porosity in UiO-66 polyMOFs

Ayala, Sergio; Zhang, Zhenjie; Cohen, Seth M.

doi:10.1039/c6cc10225e

Hierarchical structure and porosity in UiO-66 polyMOFs

Journal Article · Sat Dec 31 23:00:00 EST 2016 · ChemComm

DOI:https://doi.org/10.1039/c6cc10225e· OSTI ID:1535114

Ayala, Sergio ^[1]; Zhang, Zhenjie ^[2]; ^[2]

Department of Chemistry and Biochemistry; University of California, San Diego; La Jolla; USA; DOE/OSTI
Department of Chemistry and Biochemistry; University of California, San Diego; La Jolla; USA

The first polymer–MOF hybrid material (polyMOF) with a UiO-66 architecture is reported, prepared from polymers with varying alkyl spacers, molecular weights, and dispersities.

Research Organization:: Univ. of California, San Diego, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: FG02-08ER46519

OSTI ID:: 1535114

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 21 Vol. 53; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (29)

Green synthesis of zirconium-MOFs Reinsch, Helge; Bueken, Bart; Vermoortele, Frederik CrystEngComm, Vol. 17, Issue 22 https://doi.org/10.1039/C5CE00618J	journal	January 2015
Polymer–Metal–Organic Frameworks (polyMOFs) as Water Tolerant Materials for Selective Carbon Dioxide Separations Zhang, Zhenjie; Nguyen, Ha Thi Hoang; Miller, Stephen A. Journal of the American Chemical Society, Vol. 138, Issue 3 https://doi.org/10.1021/jacs.5b11034	journal	January 2016
Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal–Organic Framework UiO-66 and Their Important Effects on Gas Adsorption Wu, Hui; Chua, Yong Shen; Krungleviciute, Vaiva Journal of the American Chemical Society, Vol. 135, Issue 28 https://doi.org/10.1021/ja404514r	journal	May 2013
Highly ordered alignment of a vinyl polymer by host–guest cross-polymerization Distefano, Gaetano; Suzuki, Hirohito; Tsujimoto, Masahiko Nature Chemistry, Vol. 5, Issue 4 https://doi.org/10.1038/nchem.1576	journal	February 2013
Preparation and Characterization of Mesoporous Zirconia Made by Using a Poly (methyl methacrylate) Template Duan, Guorong; Zhang, Chunxiang; Li, Aimei Nanoscale Research Letters, Vol. 3, Issue 3 https://doi.org/10.1007/s11671-008-9123-7	journal	February 2008
A Modulator-Induced Defect-Formation Strategy to Hierarchically Porous Metal-Organic Frameworks with High Stability Cai, Guorui; Jiang, Hai-Long Angewandte Chemie International Edition, Vol. 56, Issue 2 https://doi.org/10.1002/anie.201610914	journal	December 2016
Self-Healing Multiphase Polymers via Dynamic Metal–Ligand Interactions Mozhdehi, Davoud; Ayala, Sergio; Cromwell, Olivia R. Journal of the American Chemical Society, Vol. 136, Issue 46 https://doi.org/10.1021/ja5097094	journal	November 2014
Metal–organic frameworks for the control and management of air quality: advances and future direction Kumar, Pawan; Kim, Ki-Hyun; Kwon, Eilhann E. Journal of Materials Chemistry A, Vol. 4, Issue 2 https://doi.org/10.1039/C5TA07068F	journal	January 2016
Disclosing the Complex Structure of UiO-66 Metal Organic Framework: A Synergic Combination of Experiment and Theory Valenzano, Loredana; Civalleri, Bartolomeo; Chavan, Sachin Chemistry of Materials, Vol. 23, Issue 7, p. 1700-1718 https://doi.org/10.1021/cm1022882	journal	April 2011
Biomimetic catalysis of metal–organic frameworks Chen, Yao; Ma, Shengqian Dalton Transactions, Vol. 45, Issue 24 https://doi.org/10.1039/C6DT00325G	journal	January 2016
Inherent anchorages in UiO-66 nanoparticles for efficient capture of alendronate and its mediated release Zhu, Xiangyang; Gu, Jinlou; Wang, Yao Chem. Commun., Vol. 50, Issue 63 https://doi.org/10.1039/C4CC02570A	journal	January 2014
Adsorptive characterization of porous solids: Error analysis guides the way De Lange, Martijn F.; Vlugt, Thijs J. H.; Gascon, Jorge Microporous and Mesoporous Materials, Vol. 200 https://doi.org/10.1016/j.micromeso.2014.08.048	journal	December 2014
polyMOFs: A Class of Interconvertible Polymer-Metal-Organic-Framework Hybrid Materials Zhang, Zhenjie; Nguyen, Ha Thi Hoang; Miller, Stephen A. Angewandte Chemie International Edition, Vol. 54, Issue 21 https://doi.org/10.1002/anie.201502733	journal	April 2015
Acyclic dienemetathesis: a versatile tool for the construction of defined polymer architectures Mutlu, Hatice; de Espinosa, Lucas Montero; Meier, Michael A. R. Chem. Soc. Rev., Vol. 40, Issue 3 https://doi.org/10.1039/B924852H	journal	January 2011
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953	journal	October 2008
Synthesis of mesoporous and tetragonal zirconia with inherited morphology from metal–organic frameworks Yan, Xiaoliang; Lu, Ningyue; Fan, Binbin CrystEngComm, Vol. 17, Issue 33 https://doi.org/10.1039/C5CE00960J	journal	January 2015
A facile synthesis of UiO-66, UiO-67 and their derivatives Katz, Michael J.; Brown, Zachary J.; Colón, Yamil J. Chemical Communications, Vol. 49, Issue 82 https://doi.org/10.1039/c3cc46105j	journal	January 2013
Definitive Molecular Level Characterization of Defects in UiO-66 Crystals Trickett, Christopher A.; Gagnon, Kevin J.; Lee, Seungkyu Angewandte Chemie International Edition, Vol. 54, Issue 38 https://doi.org/10.1002/anie.201505461	journal	August 2015
Poly(isophthalic acid)(ethylene oxide) as a Macromolecular Modulator for Metal–Organic Polyhedra Chen, Teng-Hao; Wang, Le; Trueblood, Jonathan V. Journal of the American Chemical Society, Vol. 138, Issue 30 https://doi.org/10.1021/jacs.6b04971	journal	July 2016
Facile synthesis of morphology and size-controlled zirconium metal–organic framework UiO-66: the role of hydrofluoric acid in crystallization Han, Yitong; Liu, Min; Li, Keyan CrystEngComm, Vol. 17, Issue 33 https://doi.org/10.1039/C5CE00729A	journal	January 2015
A Breathing Zirconium Metal-Organic Framework with Reversible Loss of Crystallinity by Correlated Nanodomain Formation Bueken, Bart; Vermoortele, Frederik; Cliffe, Matthew J. Chemistry - A European Journal, Vol. 22, Issue 10 https://doi.org/10.1002/chem.201600330	journal	February 2016
Transformation of Metal–Organic Framework to Polymer Gel by Cross-Linking the Organic Ligands Preorganized in Metal–Organic Framework Ishiwata, Takumi; Furukawa, Yuki; Sugikawa, Kouta Journal of the American Chemical Society, Vol. 135, Issue 14 https://doi.org/10.1021/ja3125614	journal	March 2013
Highly branched and loop-rich gels via formation of metal–organic cages linked by polymers Zhukhovitskiy, Aleksandr V.; Zhong, Mingjiang; Keeler, Eric G. Nature Chemistry, Vol. 8, Issue 1 https://doi.org/10.1038/nchem.2390	journal	November 2015
Block Co-PolyMOCs by Stepwise Self-Assembly Wang, Yufeng; Zhong, Mingjiang; Park, Jiwon V. Journal of the American Chemical Society, Vol. 138, Issue 33 https://doi.org/10.1021/jacs.6b06712	journal	August 2016
Tuning Dynamic Mechanical Response in Metallopolymer Networks through Simultaneous Control of Structural and Temporal Properties of the Networks Mozhdehi, Davoud; Neal, James A.; Grindy, Scott C. Macromolecules, Vol. 49, Issue 17 https://doi.org/10.1021/acs.macromol.6b01626	journal	August 2016
Metallopolymers: New Multifunctional Materials Whittell, G. R.; Manners, I. Advanced Materials, Vol. 19, Issue 21 https://doi.org/10.1002/adma.200702876	journal	November 2007
Tuned to Perfection: Ironing Out the Defects in Metal–Organic Framework UiO-66 Shearer, Greig C.; Chavan, Sachin; Ethiraj, Jayashree Chemistry of Materials, Vol. 26, Issue 14 https://doi.org/10.1021/cm501859p	journal	July 2014
In Situ Modification of Metal-Organic Frameworks in Mixed-Matrix Membranes Denny, Michael S.; Cohen, Seth M. Angewandte Chemie International Edition, Vol. 54, Issue 31 https://doi.org/10.1002/anie.201504077	journal	June 2015
A review of how to do an acyclic diene metathesis reaction: A review of how to do an ADMET reaction Li, Hong; Caire da Silva, Lucas; Schulz, Michael D. Polymer International, Vol. 66, Issue 1 https://doi.org/10.1002/pi.5188	journal	July 2016

Cited By (18)

Metal‐Organic Frameworks in Polymer Science: Polymerization Catalysis, Polymerization Environment, and Hybrid Materials Schmidt, Bernhard V. K. J. Macromolecular Rapid Communications, Vol. 41, Issue 1 https://doi.org/10.1002/marc.201900333	journal	August 2019
polyMOF Formation from Kinked Polymer Ligands via ortho -Substitution Palomba, Joseph M.; Ayala, Sergio; Cohen, Seth M. Israel Journal of Chemistry, Vol. 58, Issue 9-10 https://doi.org/10.1002/ijch.201800094	journal	September 2018
Engineering new defective phases of UiO family metal–organic frameworks with water Firth, Francesca C. N.; Cliffe, Matthew J.; Vulpe, Diana Journal of Materials Chemistry A, Vol. 7, Issue 13 https://doi.org/10.1039/c8ta10682g	journal	January 2019
Nylon–MOF Composites through Postsynthetic Polymerization Kalaj, Mark; Denny, Michael S.; Bentz, Kyle C. Angewandte Chemie International Edition, Vol. 58, Issue 8 https://doi.org/10.1002/anie.201812655	journal	February 2019
Fabrication of WO _2.72 /UiO-66 nanocomposites and effects of WO _2.72 ratio on photocatalytic performance: judgement of the optimal content and mechanism study: UiO-66 supported highly-dispersed WO _2.72 nanorods Zhang, Qingsong; Yang, Jinghua; Xu, Min Journal of Chemical Technology & Biotechnology, Vol. 93, Issue 9 https://doi.org/10.1002/jctb.5627	journal	April 2018
Synthesis, structures and magnetic properties of two chiral mixed-valence iron( ii , iii ) coordination networks Xue, Yun-Shan; Tan, Xu; Zhou, Mengjie Dalton Transactions, Vol. 46, Issue 47 https://doi.org/10.1039/c7dt03411c	journal	January 2017
High-throughput screening of solid-state catalysts for nerve agent degradation Palomba, Joseph M.; Credille, Cy V.; Kalaj, Mark Chemical Communications, Vol. 54, Issue 45 https://doi.org/10.1039/c8cc03255f	journal	January 2018
Supramolekulare Metallopolymere: Von linearen Materialien zu infiniten Netzwerken Bentz, Kyle C.; Cohen, Seth M. Angewandte Chemie, Vol. 130, Issue 46 https://doi.org/10.1002/ange.201806912	journal	October 2018
Isoreticular expansion of polyMOFs achieves high surface area materials Schukraft, Giulia E. M.; Ayala, Sergio; Dick, Benjamin L. Chemical Communications, Vol. 53, Issue 77 https://doi.org/10.1039/c7cc04222a	journal	January 2017
Hydrophobic Metal–Organic Frameworks: Assessment, Construction, and Diverse Applications Xie, Lin‐Hua; Xu, Ming‐Ming; Liu, Xiao‐Min Advanced Science, Vol. 7, Issue 4 https://doi.org/10.1002/advs.201901758	journal	January 2020
From fundamentals to applications: a toolbox for robust and multifunctional MOF materials Kirchon, Angelo; Feng, Liang; Drake, Hannah F. Chemical Society Reviews, Vol. 47, Issue 23 https://doi.org/10.1039/c8cs00688a	journal	January 2018
Polymer in MOF Nanospace: from Controlled Chain Assembly to New Functional Materials Le Ouay, Benjamin; Uemura, Takashi Israel Journal of Chemistry, Vol. 58, Issue 9-10 https://doi.org/10.1002/ijch.201800074	journal	September 2018
Hollow polymer nanocapsules: synthesis, properties, and applications Bentz, Kyle C.; Savin, Daniel A. Polymer Chemistry, Vol. 9, Issue 16 https://doi.org/10.1039/c8py00142a	journal	January 2018
Block co-polyMOFs: morphology control of polymer–MOF hybrid materials Ayala, Sergio; Bentz, Kyle C.; Cohen, Seth M. Chemical Science, Vol. 10, Issue 6 https://doi.org/10.1039/c8sc04250k	journal	January 2019
Supramolecular Metallopolymers: From Linear Materials to Infinite Networks Bentz, Kyle C.; Cohen, Seth M. Angewandte Chemie International Edition, Vol. 57, Issue 46 https://doi.org/10.1002/anie.201806912	journal	October 2018
Nylon-MOF Composites through Postsynthetic Polymerization Kalaj, Mark; Denny, Michael S.; Bentz, Kyle C. Angewandte Chemie, Vol. 131, Issue 8 https://doi.org/10.1002/ange.201812655	journal	January 2019
A gel-like/freeze-drying strategy to construct hierarchically porous polyoxometalate-based metal–organic framework catalysts Li, Xiao-Hui; Liu, Yi-Wei; Liu, Shu-Mei Journal of Materials Chemistry A, Vol. 6, Issue 11 https://doi.org/10.1039/c7ta10334d	journal	January 2018
Hierarchical Porous Zr-Based MOFs Synthesized by a Facile Monocarboxylic Acid Etching Strategy Yang, Pengfei; Mao, Fangxin; Li, Yongsheng Chemistry - A European Journal, Vol. 24, Issue 12 https://doi.org/10.1002/chem.201705020	journal	February 2018

Similar Records

Hierarchical structure and porosity in UiO-66 polyMOFs

Journal Article · Mon Feb 20 23:00:00 EST 2017 · ChemComm · OSTI ID:1780606

Structure of the Polymer Backbones in polyMOF Materials

Journal Article · Mon May 25 00:00:00 EDT 2020 · Journal of the American Chemical Society · OSTI ID:1779734

polyMOF Formation from Kinked Polymer Ligands via ortho -Substitution

Journal Article · Thu Sep 20 00:00:00 EDT 2018 · Israel Journal of Chemistry · OSTI ID:1780602

Related Subjects

Chemistry

Hierarchical structure and porosity in UiO-66 polyMOFs

Citation Formats

References (29)

Cited By (18)

Similar Records

Related Subjects