Isoreticular expansion of polyMOFs achieves high surface area materials

Schukraft, Giulia E. M.; Ayala, Jr., Sergio; Dick, Benjamin L.; Cohen, Seth M.

doi:10.1039/c7cc04222a

Isoreticular expansion of polyMOFs achieves high surface area materials

Journal Article · Mon Sep 11 00:00:00 EDT 2017 · ChemComm

DOI:https://doi.org/10.1039/c7cc04222a· OSTI ID:1780607

Schukraft, Giulia E. M. ^[1]; Ayala, Jr., Sergio ^[2]; Dick, Benjamin L. ^[2]; ^[2]

Univ. of California, San Diego, La Jolla, CA (United States); U.C. San Diego
Univ. of California, San Diego, La Jolla, CA (United States)

The concept of isoreticular chemistry has become a core principle in metal–organic framework (MOF) materials. Isoreticular chemistry has shown that organic ligands of different sizes, but with a common geometry/symmetry can be used to generate MOFs of related topologies, but with expanded pore sizes and volumes. In this study, polymer–MOF hybrid materials (polyMOFs) with a UiO (UiO = University of Oslo) architecture are shown to adhere to the principle of isoreticular expansion, generating polyMOFs with large surface areas and enhanced stability.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, San Diego, La Jolla, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: FG02-08ER46519

OSTI ID:: 1780607

Alternate ID(s):: OSTI ID: 1539863

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 77 Vol. 53; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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