Initial assessment of Ni-base alloy performance in 0.1&nbsp;MPa and supercritical CO2

Pint, B. A.; Keiser, J. R.

doi:10.1007/s11837-015-1661-8

Initial assessment of Ni-base alloy performance in 0.1 MPa and supercritical CO₂

Journal Article · Fri Sep 25 00:00:00 EDT 2015 · JOM. Journal of the Minerals, Metals & Materials Society

DOI:https://doi.org/10.1007/s11837-015-1661-8· OSTI ID:1225426

Pint, B. A. ^[1]; Keiser, J. R. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

There is considerable interest in increasing the working temperature of both open and closed supercritical CO₂ (sCO₂) cycles to ≥700 °C. At these temperatures, it is unlikely that any Fe-base alloys have suitable strength and therefore the focus is on Ni-base alloys for this application. To begin addressing the lack of compatibility data under these conditions, initial work exposed a wide range of candidate alloys in 500-h exposures at 20 MPa (200 bar) CO₂ at 650 -750 °C in high purity CO₂. In general, the reaction products were thin and protective in these exposures. A smaller group of alloy coupons focusing on chromia- and alumina-forming alloys was exposed for 500h in 0.1 MPa (1bar) air, CO₂, CO₂+O₂ and CO₂+H₂O for comparison. Thus, the thin surface oxides formed were very similar to those formed at high pressure and no clear detrimental effect of CO₂ oxidation or O₂ or H₂O impurities could be observed in these exposures.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1225426

Journal Information:: JOM. Journal of the Minerals, Metals & Materials Society, Journal Name: JOM. Journal of the Minerals, Metals & Materials Society Journal Issue: 11 Vol. 67; ISSN 1047-4838

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
Ni-base alloys
corrosion
supercritical CO2

Initial assessment of Ni-base alloy performance in 0.1 MPa and supercritical CO2

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References (23)

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Initial assessment of Ni-base alloy performance in 0.1 MPa and supercritical CO₂