Effect of Pressure and Thermal Cycling on Long-Term Oxidation in CO2 and Supercritical CO2

Pint, Bruce A.; Pillai, Rishi; Lance, Michael J.; Keiser, Jim R.

doi:10.1007/s11085-020-10004-9

Effect of Pressure and Thermal Cycling on Long-Term Oxidation in CO₂ and Supercritical CO₂

Journal Article · Wed Nov 04 00:00:00 EST 2020 · Oxidation of Metals

DOI:https://doi.org/10.1007/s11085-020-10004-9· OSTI ID:1731056

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Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Concentrating solar power plant designers are interested in supercritical CO₂ (sCO₂) for the power block to achieve > 50% electrical efficiency at > 700 °C. The goal of this project was to develop a long-term (> 100 kh) lifetime model for sCO₂ compatibility using 10–15 kh laboratory exposures. Three Ni-based alloys (625, 282 and 740H) and an advanced austenitic stainless steel were evaluated here in long-term exposures at 700–800 °C using 500-h cycles in laboratory air, 0.1 MPa industrial grade (IG) CO₂ and 30 MPa supercritical IG CO₂ and using 10-h cycles in 0.1 MPa IG CO₂ and O₂. Mass change data and quantification of the oxide scale thickness and depth of internal attack after 1000–10,000 h exposures at 750 °C indicate that these materials are compatible with the sCO₂ environments with modeling used to predict long-term behavior. Comparison of the 0.1 and 30 MPa 500-h cycle results did not show a significant effect of pressure on the reaction, and no significant internal carburization was observed under these conditions, even for the stainless steel, suggesting that chromia scales may be better C diffusion barriers than expected. For the Ni-based alloys, thermal cycling to simulate the solar duty cycle did not result in scale spallation after 15 kh in 10-h cycles or 4 kh in 1-h cycles at 750 °C. However, the stainless steel specimens formed an Fe-rich oxide after ~ 1500-h cumulative exposure time in both 1- and 10-h cycles.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office

Grant/Contract Number:: AC05-00OR22725; EE0001556

OSTI ID:: 1731056

Alternate ID(s):: OSTI ID: 1505321

Journal Information:: Oxidation of Metals, Journal Name: Oxidation of Metals Journal Issue: 5-6 Vol. 94; ISSN 0030-770X

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

References (49)

Recent advances in understanding metal dusting: A review Young, D. J.; Zhang, J.; Geers, C. Materials and Corrosion, Vol. 62, Issue 1 https://doi.org/10.1002/maco.201005675	journal	June 2010
Effect of pressure on supercritical CO ₂ compatibility of structural alloys at 750 °C : Effect of pressure on supercritical CO Pint, B. A.; Brese, R. G.; Keiser, J. R. Materials and Corrosion, Vol. 68, Issue 2 https://doi.org/10.1002/maco.201508783	journal	April 2016
Effect of pressure and impurities on oxidation in supercritical CO ₂ Pint, Bruce A.; Lehmusto, Juho; Lance, Michael J. Materials and Corrosion, Vol. 70, Issue 8 https://doi.org/10.1002/maco.201810652	journal	April 2019
Corrosion of metals and alloys in mixed gas environments at elevated temperatures Giggins, C. S.; Pettit, F. S. Oxidation of Metals, Vol. 14, Issue 5 https://doi.org/10.1007/BF00603609	journal	October 1980
Calculations of parabolic reaction rate constants Pieraggi, B. Oxidation of Metals, Vol. 27, Issue 3-4 https://doi.org/10.1007/BF00667057	journal	April 1987
Corrosion of iron-, nickel-, and cobalt-base alloys in atmospheres containing carbon and oxygen Meier, G. H.; Coons, W. C.; Perkins, R. A. Oxidation of Metals, Vol. 17, Issue 3-4 https://doi.org/10.1007/BF00738385	journal	April 1982
Sub-Scale Depletion and Enrichment Processes During High Temperature Oxidation of the Nickel Base Alloy 625 in the Temperature Range 900–1000 °C Chyrkin, A.; Huczkowski, P.; Shemet, V. Oxidation of Metals, Vol. 75, Issue 3-4 https://doi.org/10.1007/s11085-010-9225-3	journal	December 2010
Alloys SS316 and Hastelloy-C276 in Supercritical CO2 at High Temperature Olivares, R. I.; Young, D. J.; Marvig, P. Oxidation of Metals, Vol. 84, Issue 5-6 https://doi.org/10.1007/s11085-015-9589-5	journal	September 2015
Predicting Oxidation-Limited Lifetime of Thin-Walled Components of NiCrW Alloy 230 Duan, R.; Jalowicka, A.; Unocic, K. Oxidation of Metals, Vol. 87, Issue 1-2 https://doi.org/10.1007/s11085-016-9653-9	journal	October 2016
Effect of Thermal Cycling on Compatibility in CO2 for Concentrated Solar Power Applications Brese, Robert G.; Keiser, James R.; Pint, Bruce A. Oxidation of Metals, Vol. 87, Issue 5-6 https://doi.org/10.1007/s11085-017-9762-0	journal	March 2017
Initial Assessment of Ni-Base Alloy Performance in 0.1 MPa and Supercritical CO2 Pint, B. A.; Keiser, J. R. JOM, Vol. 67, Issue 11 https://doi.org/10.1007/s11837-015-1661-8	journal	September 2015
The Effect of CO2 Pressure on Chromia Scale Microstructure at 750°C Pint, B. A.; Unocic, K. A. JOM, Vol. 70, Issue 8 https://doi.org/10.1007/s11837-018-2963-4	journal	June 2018
The supercritical thermodynamic power cycle Feher, E. G. Energy Conversion, Vol. 8, Issue 2 https://doi.org/10.1016/0013-7480(68)90105-8	journal	September 1968
Influence of chromium content on carburization of chromium-nickel-iron alloys in carbon dioxide Martin, W. R.; Weir, J. R. Journal of Nuclear Materials, Vol. 16, Issue 1 https://doi.org/10.1016/0022-3115(65)90087-5	journal	May 1965
A study on the solubility and distribution of carbon in oxides Wolf, I.; Grabke, H. J. Solid State Communications, Vol. 54, Issue 1 https://doi.org/10.1016/0038-1098(85)91021-X	journal	April 1985
Microstructural stability and mechanical properties of a new nickel-based superalloy Zhao, Shuangqun; Xie, Xishan; Smith, Gaylord D. Materials Science and Engineering: A, Vol. 355, Issue 1-2 https://doi.org/10.1016/S0921-5093(03)00051-0	journal	August 2003
On the breakaway oxidation of Fe9Cr1Mo steel in high pressure CO2 Gong, Y.; Young, D. J.; Kontis, P. Acta Materialia, Vol. 130 https://doi.org/10.1016/j.actamat.2017.02.034	journal	May 2017
Supercritical CO2 Brayton cycles for solar-thermal energy Iverson, Brian D.; Conboy, Thomas M.; Pasch, James J. Applied Energy, Vol. 111 https://doi.org/10.1016/j.apenergy.2013.06.020	journal	November 2013
Carburisation of ferritic Fe–Cr alloys by low carbon activity gases Gheno, Thomas; Monceau, Daniel; Zhang, Jianqiang Corrosion Science, Vol. 53, Issue 9 https://doi.org/10.1016/j.corsci.2011.05.013	journal	September 2011
Corrosion of austenitic and ferritic-martensitic steels exposed to supercritical carbon dioxide Tan, L.; Anderson, M.; Taylor, D. Corrosion Science, Vol. 53, Issue 10 https://doi.org/10.1016/j.corsci.2011.06.002	journal	October 2011
Corrosion of austenitic alloys in high temperature supercritical carbon dioxide Cao, G.; Firouzdor, V.; Sridharan, K. Corrosion Science, Vol. 60 https://doi.org/10.1016/j.corsci.2012.03.029	journal	July 2012
Predicting the depletion of chromium in two high temperature Ni alloys Pillai, R.; Ackermann, H.; Lucka, K. Corrosion Science, Vol. 69 https://doi.org/10.1016/j.corsci.2012.11.040	journal	April 2013
Corrosion of a stainless steel and nickel-based alloys in high temperature supercritical carbon dioxide environment Firouzdor, V.; Sridharan, K.; Cao, G. Corrosion Science, Vol. 69 https://doi.org/10.1016/j.corsci.2012.11.041	journal	April 2013
Kinetics of breakaway oxidation of Fe–Cr and Fe–Cr–Ni alloys in dry and wet carbon dioxide Gheno, Thomas; Monceau, Daniel; Young, David J. Corrosion Science, Vol. 77 https://doi.org/10.1016/j.corsci.2013.08.008	journal	December 2013
Modeling carbide dissolution in alloy 602 CA during high temperature oxidation Chyrkin, A.; Pillai, R.; Ackermann, H. Corrosion Science, Vol. 96 https://doi.org/10.1016/j.corsci.2015.03.019	journal	July 2015
Corrosion and carburization behavior of chromia-forming heat resistant alloys in a high-temperature supercritical-carbon dioxide environment Lee, Ho Jung; Kim, Hyunmyung; Kim, Sung Hwan Corrosion Science, Vol. 99 https://doi.org/10.1016/j.corsci.2015.07.007	journal	October 2015
High Efficiency and Low Cost of Electricity Generation from Fossil Fuels While Eliminating Atmospheric Emissions, Including Carbon Dioxide Allam, R. J.; Palmer, Miles R.; Brown, G. William Energy Procedia, Vol. 37 https://doi.org/10.1016/j.egypro.2013.05.211	journal	January 2013
Compatibility of FBR structural materials with supercritical carbon dioxide Furukawa, T.; Inagaki, Y.; Aritomi, M. Progress in Nuclear Energy, Vol. 53, Issue 7 https://doi.org/10.1016/j.pnucene.2011.04.030	journal	September 2011
A review of thermodynamic cycles and working fluids for the conversion of low-grade heat Chen, Huijuan; Goswami, D. Yogi; Stefanakos, Elias K. Renewable and Sustainable Energy Reviews, Vol. 14, Issue 9, p. 3059-3067 https://doi.org/10.1016/j.rser.2010.07.006	journal	December 2010
Penetration of protective chromia scales by carbon Young, David J.; Nguyen, Thuan Dinh; Felfer, Peter Scripta Materialia, Vol. 77 https://doi.org/10.1016/j.scriptamat.2014.01.009	journal	April 2014
Benchmarking supercritical carbon dioxide cycles against steam Rankine cycles for Concentrated Solar Power Cheang, V. T.; Hedderwick, R. A.; McGregor, C. Solar Energy, Vol. 113 https://doi.org/10.1016/j.solener.2014.12.016	journal	March 2015
Overview on corrosion in supercritical fluids Sarrade, Stéphane; Féron, Damien; Rouillard, Fabien The Journal of Supercritical Fluids, Vol. 120 https://doi.org/10.1016/j.supflu.2016.07.022	journal	February 2017
Corrosion resistance of chromised and aluminised coatings in wet CO 2 gas at 650 °C Nguyen, Thuan Dinh; Peng, Xiao; Zhang, Jianqiang Surface and Coatings Technology, Vol. 316 https://doi.org/10.1016/j.surfcoat.2017.03.028	journal	April 2017
Characterization of chromia scales formed in supercritical carbon dioxide Pint, B. A.; Unocic, K. A.; Brese, R. G. Materials at High Temperatures, Vol. 35, Issue 1-3 https://doi.org/10.1080/09603409.2017.1389371	journal	October 2017
The Effect of Oxide Volatilization on the Oxidation Kinetics of Cr and Fe-Cr Alloys Tedmon, C. S. Journal of The Electrochemical Society, Vol. 113, Issue 8 https://doi.org/10.1149/1.2424115	journal	January 1966
Carburization of Fe-Cr Alloys During Oxidation in Dry Carbon Dioxide Fujii, C. T.; Meussner, R. A. Journal of The Electrochemical Society, Vol. 114, Issue 5 https://doi.org/10.1149/1.2426622	journal	January 1967
Theoretical Analysis of the Diffusion Processes Determining the Oxidation Rate of Alloys Wagner, Carl Journal of The Electrochemical Society, Vol. 99, Issue 10 https://doi.org/10.1149/1.2779605	journal	January 1952
Diffusion of chromium in ferritic and austenitic 9–20 wt-%chromium steels Tőkei, Z.; Hennesen, K.; Viefhaus, H. Materials Science and Technology, Vol. 16, Issue 10 https://doi.org/10.1179/026708300101507055	journal	October 2000
A new computational approach for modelling the microstructural evolution and residual lifetime assessment of MCrAlY coatings Pillai, R.; Sloof, W. G.; Chyrkin, A. Materials at High Temperatures, Vol. 32, Issue 1-2 https://doi.org/10.1179/0960340914Z.00000000063	journal	January 2015
Oxidation behaviour of cast Ni–Cr alloys in steam at 800°C Essuman, E.; Walker, L. R.; Maziasz, P. J. Materials Science and Technology, Vol. 29, Issue 7 https://doi.org/10.1179/1743284712Y.0000000103	journal	July 2013
Stress effects in high temperature oxidation of metals Evans, H. E. International Materials Reviews, Vol. 40, Issue 1 https://doi.org/10.1179/imr.1995.40.1.1	journal	January 1995
Oxidation induced lifetime limits of thin walled, iron based, alumina forming, oxide dispersion strengthened alloy components Quadakkers, w. J.; Bennett, M. J. Materials Science and Technology, Vol. 10, Issue 2 https://doi.org/10.1179/mst.1994.10.2.126	journal	February 1994
The Supercritical Carbon Dioxide Power Cycle: Comparison to Other Advanced Power Cycles Dostal, Vaclav; Hejzlar, Pavel; Driscoll, Michael J. Nuclear Technology, Vol. 154, Issue 3 https://doi.org/10.13182/NT06-A3734	journal	June 2006
U.S. Program on Materials Technology for Ultra-Supercritical Coal Power Plants Viswanathan, R.; Henry, J. F.; Tanzosh, J. Journal of Materials Engineering and Performance, Vol. 14, Issue 3 https://doi.org/10.1361/10599490524039	journal	June 2005
Effect of impurities on supercritical CO2 compatibility Pint, Bruce A.; Unocic, Kinga A.; Keiser, James R. DuEPublico: Duisburg-Essen Publications online, University of Duisburg-Essen, Germany https://doi.org/10.17185/duepublico/48899	text	January 2019
The oxidation behaviour of the 9 % Cr steel P92in CO ₂ - and H ₂ O-rich gases relevant to oxyfuel environments Abellán, Javier Pirón; Olszewski, Tomasz; Meier, Gerald H. International Journal of Materials Research, Vol. 101, Issue 2 https://doi.org/10.3139/146.110271	journal	February 2010
The Future of Alumina-Forming Alloys: Challenges and Applications for Power Generation Pint, Bruce A. Materials Science Forum, Vol. 696 https://doi.org/10.4028/www.scientific.net/MSF.696.57	journal	September 2011
Type 304 Stainless Steel vs Flowing CO ₂ At Atmospheric Pressure and 1100-1800F McCOY, H. E. CORROSION, Vol. 21, Issue 3 https://doi.org/10.5006/0010-9312-21.3.84	journal	March 1965
Corrosion Behavior of Different Metallic Materials in Supercritical Carbon Dioxide at 550°C and 250 bars Rouillard, F.; Charton, F.; Moine, G. CORROSION, Vol. 67, Issue 9 https://doi.org/10.5006/1.3628683	journal	September 2011

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