High-Temperature Compatibility of Structural Alloys with Supercritical and Subcritical CO2
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
In searching for new working fluids for power generation, supercritical CO2 (sCO2) offers some attractive features for efficient cycles. However, compatibility with structural alloys is a concern. NiCr-based alloys have excellent compatibility at 600°-800°C at 20-30 MPa sCO2. However, conventional steels have restrictions in temperature because of carburization and accelerated oxidation in sCO2, similar to observations in CO2. To assess the impact of carburization on steel mechanical properties, small (25mm long) dogbone tensile bars are being exposed and tested after exposure at 450°-650°C. Only highly alloyed advanced austenitic steels are resistant to carburization at 650°-750°C, suggesting that Crrich oxide scales are good barriers to C ingress. Above 800°C, it is only possible to conduct subcritical evaluations at this time, but initial results suggest most conventional high-temperature Fe- and Ni-based alloys are more rapidly degraded by CO2 at higher temperatures. Coatings are a potential solution that require more study.
- Research Organization:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Organization:
- USDOE Office of Fossil Energy (FE); USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- Grant/Contract Number:
- AC05-00OR22725; EE0001556
- OSTI ID:
- 1807235
- Journal Information:
- Interface Magazine, Journal Name: Interface Magazine Journal Issue: 2 Vol. 30; ISSN 1064-8208
- Publisher:
- The Electrochemical SocietyCopyright Statement
- Country of Publication:
- United States
- Language:
- English
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