Evaluation of coated steels in supercritical CO2

Pint, Bruce A.; Pillai, Rishi; Su, Yi‐Feng; Lance, Michael J.; Keiser, James R.

doi:10.1002/maco.202314271

Evaluation of coated steels in supercritical CO₂

Journal Article · Sun Feb 11 00:00:00 EST 2024 · Materials and Corrosion

DOI:https://doi.org/10.1002/maco.202314271· OSTI ID:2438946

^[1]; ^[1]; Su, Yi‐Feng ^[1]; ^[1]; ^[1]

Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

The carburizing supercritical CO₂ (sCO₂) environment limits the use of lower cost steels in the lower temperature (450–650°C) portions of the sCO₂ Brayton cycle because of concerns about internal carburization and embrittlement. Results on a ferritic–martensitic steel and conventional and advanced austenitic steels at 450–650°C in 30 MPa sCO₂ with and without 1% O₂ and 0.1% H₂O additions have indicated that sCO₂ environments will have lower maximum operating temperatures compared to steam plants. Pack Al and Cr coatings were evaluated at 650°C on T91 and 316H substrates and showed some benefit for up to 2000 h at 650°C, especially without impurities. However, characterization indicated Al₂O₃ was not formed and Cr-rich carbides formed in the Cr coatings. With the addition of impurities in the sCO₂, the coatings were less protective at 650°C. Subsequent exposures at 600°C in sCO₂ showed similar behavior. Postexposure evaluations included measuring the bulk C content and room temperature tensile properties. Finally, improvements were indicated but the tensile results were complicated by the high temperature pack coating process affecting the substrate properties.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Fossil Energy and Carbon Management (FECM); USDOE Office of Nuclear Energy (NE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2438946

Alternate ID(s):: OSTI ID: 2301766

Journal Information:: Materials and Corrosion, Journal Name: Materials and Corrosion Vol. 75; ISSN 0947-5117

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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