Effect of pressure on high-temperature oxidation of Ni alloys in supercritical CO2 containing impurities

Oleksak, Richard P.; Carney, Casey S.; Doğan, Ömer N.

doi:10.1016/j.corsci.2023.111055

Effect of pressure on high-temperature oxidation of Ni alloys in supercritical CO₂ containing impurities

Journal Article · Thu Feb 16 00:00:00 EST 2023 · Corrosion Science

DOI:https://doi.org/10.1016/j.corsci.2023.111055· OSTI ID:1969017

Oleksak, Richard P. ^[1]; Carney, Casey S. ^[2]; Doğan, Ömer N. ^[1]

National Energy Technology Laboratory (NETL), Albany, OR (United States)
National Energy Technology Laboratory (NETL), Albany, OR (United States). Support Contractor

Direct supercritical CO₂ (sCO₂) power cycles require structural materials compatible with hot sCO₂ containing high levels of water and oxygen impurities. Chromia-forming Ni-based superalloys, which are leading candidates at temperatures > 600 °C, have shown good compatibility in pure sCO₂, however potential impurity effects are not well understood. In this report we exposed several commercial Ni-based alloys to 95%CO₂-4%H₂O-(1-3)%O₂ at 750 °C and 0.1 or 20 MPa for 2500 h. Protective chromia scales formed in all cases. Nevertheless, water vapor-assisted oxide volatilization clearly occurred at high pressure. The volatilization rates decreased with time, but still represent a potentially serious compatibility issue in real, high-velocity, sCO₂ systems.

View Accepted Manuscript (DOE)

Research Organization:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV, and Albany, OR (United States)

Sponsoring Organization:: USDOE; USDOE Office of Fossil Energy (FE)

OSTI ID:: 1969017

Alternate ID(s):: OSTI ID: 2000164

Journal Information:: Corrosion Science, Journal Name: Corrosion Science Journal Issue: N/A Vol. 215; ISSN 0010-938X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Effect of pressure on high-temperature oxidation of Ni alloys in supercritical CO2 containing impurities

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