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Optical and infrared spectra of thermally annealed Pb implanted SiO{sub 2} glasses

Conference ·
OSTI ID:10162274
; ;  [1]; ;  [2];  [3];  [4]
  1. Fisk Univ., Nashville, TN (United States). Dept. of Physics
  2. Belmont Univ., Nashville, TN (United States). Dept. of Physics
  3. Vanderbilt Univ., Nashville, TN (United States). Dept. of Materials Science and Engineering
  4. Oak Ridge National Lab., TN (United States)

Infrared reflectance between 4000 and 100 cm{sup {minus}1} and optical spectra between 1.8 and 6.2 eV of high purity silica implanted with nominal doses of 1, 3 and 6 {times} 10{sup 16} Pb ions/cm{sup 2} were recorded before and after annealing at 400, 600, and 800C for 1 hour. Curve resolution analysis of the Si-O stretching region resulted in six peaks which were characterized by their lineshape parameters. The oscillator strength of the ion induced defect peak at 1035 cm{sup {minus}1} was found to depend on ion dose. The defect band at 1035 cm{sup {minus}1} decreased to an intensity comparable to that of the unimplanted glass after thermal annealing for 1 hour at 800C. Far infrared spectra indicated the formation of lead silicate particles after annealing.

Research Organization:
Oak Ridge National Lab., TN (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States); National Aeronautics and Space Administration, Washington, DC (United States); Federal Aviation Administration, Washington, DC (United States)
DOE Contract Number:
AC05-84OR21400
OSTI ID:
10162274
Report Number(s):
CONF-920792--61; ON: DE93015304
Country of Publication:
United States
Language:
English

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