Method and integrated process for the carboxylation of furan derived carboxylic acids to 2,5-furandicarboxylic acid

Kittrell, James R.; Dupre, Carl R.; Kittrell, Keith D.; McDonald, Leonard T.; Kittrell, Jeffrey A.

Title: Method and integrated process for the carboxylation of furan derived carboxylic acids to 2,5-furandicarboxylic acid

Patent · Tue Jul 25 00:00:00 EDT 2023

OSTI ID:2222004

Kittrell, James R.; Dupre, Carl R.; Kittrell, Keith D.; McDonald, Leonard T.; Kittrell, Jeffrey A.

A process for carboxylation of a furoate slurry to produce FDCA, especially 2,5-FDCA, includes the steps of: feeding a slurry containing a suspension fluid, furoate, a surfactant and an alkali metal carbonate to a carboxylation reactor; and feeding a flow of CO₂ to the carboxylation reactor at flow conditions sufficient to suspend the slurry in the reactor and react the furoate with CO₂ to form 2,5-FDCA. A fully integrated process is also disclosed.

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Research Organization:: KSE, Inc., Sunderland, MA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: SC0017219

Assignee:: KSE, Inc. (Sunderland, MA)

Patent Number(s):: 11,708,343

Application Number:: 17/377,851

OSTI ID:: 2222004

Resource Relation:: Patent File Date: 07/16/2021

Country of Publication:: United States

Language:: English

References (12)

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Carbonate-promoted carboxylation reactions for the synthesis of valuable organic compounds Kanan, Matthew W.; Banerjee, Aanindeeta https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/10160740 US Patent Document 10,160,740	patent	December 2018

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