The effect of silica oxide support on the catalytic activity of nickel-molybdenum bimetallic catalyst toward ethanol steam reforming for hydrogen production

Elharati, Mohamed A.; Lee, Kyung-Min; Hwang, Sooyeon; Mohammed Hussain, A.; Miura, Yohei; Dong, Song; Fukuyama, Yosuke; Dale, Nilesh; Saunders, Steven; Kim, Taejin; Ha, Su

doi:10.1016/j.cej.2022.135916

Title: The effect of silica oxide support on the catalytic activity of nickel-molybdenum bimetallic catalyst toward ethanol steam reforming for hydrogen production

Journal Article · Tue Mar 22 00:00:00 EDT 2022 · Chemical Engineering Journal

DOI:https://doi.org/10.1016/j.cej.2022.135916· OSTI ID:1873167

Elharati, Mohamed A. ^[1]; Lee, Kyung-Min ^[2]; Hwang, Sooyeon ^[3]; Mohammed Hussain, A. ^[4]; Miura, Yohei ^[5]; Dong, Song ^[5]; Fukuyama, Yosuke ^[5]; Dale, Nilesh ^[4];

^[1]; Kim, Taejin ^[2]; Ha, Su ^[1]

Washington State Univ., Pullman, WA (United States)
Stony Brook Univ., NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Nissan Technical Centre North America, Farmington Hills, MI (United States)
Nissan Research Centre, Kanagawa (Japan)

This work investigates the effects of molybdenum promoter and silica oxide (SiO₂) support morphology on the ethanol steam reforming (ESR) performance of Nickel-Molybdenum (NiMo) bimetallic catalysts. Ordered mesoporous SiO₂ (SBA-15) and commercial SiO₂ supports were used as the oxide support materials. The synthesized catalysts were prepared via the wet impregnation method and characterized via XRD, H₂-TPR, BET, FTIR, and Raman techniques. This study shows that NiMo bimetallic catalyst supported on SBA-15 has superior catalytic activity and better coking resistance at an intermediate temperature of 600 ⁰C than commercial SiO₂ supported catalysts. The presence of a uniform mesoporous structure of SBA-15 with an average pore diameter of ~ 2 nm can obstruct the carbon formation, leading to improved coking resistance. The catalytic enhancement of NiMo bimetallic catalysts toward ESR can also be linked to the ability of Mo promoter in enhancing the interaction between NiMo nanoparticles and SiO₂ support materials and restraining agglomeration of Ni nanoparticles, which results in further improvement of NiMo nanoparticle dispersion and inhibit its sintering. The NiMo bimetallic catalysts supported on SBA-15 illustrated the high H₂ yield of ~ 54% and carbon conversion of ~ 89% with the excellent stability for ESR performed at 600 ⁰C and the steam-to-carbon ratio of 2 over 65 hours.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States); Washington State Univ., Pullman, WA (United States); Stony Brook Univ., NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Science Foundation (NSF)

Grant/Contract Number:: SC0012704; 2050691

OSTI ID:: 1873167

Report Number(s):: BNL-223087-2022-JAAM

Journal Information:: Chemical Engineering Journal, Vol. 441; ISSN 1385-8947

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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25 ENERGY STORAGE
ethanol steam reforming (ESR)
nickel-molybdenum (NiMo)
ordered mesoporous SiO2 (SBA-15)
raman
coke formation
Hydrogen production

Title: The effect of silica oxide support on the catalytic activity of nickel-molybdenum bimetallic catalyst toward ethanol steam reforming for hydrogen production

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