Grafted nickel-promoter catalysts for dry reforming of methane identified through high-throughput experimentation

Ferrandon, Magali S.; Byron, Carly; Celik, Gokhan; Zhang, Yuying; Ni, Chaoying; Sloppy, Jennifer; McCormick, Rachel A.; Booksh, Karl; Teplyakov, Andrew V.; Delferro, Massimiliano

doi:10.1016/j.apcata.2021.118379

Title: Grafted nickel-promoter catalysts for dry reforming of methane identified through high-throughput experimentation

Journal Article · Wed Sep 29 00:00:00 EDT 2021 · Applied Catalysis. A, General

DOI:https://doi.org/10.1016/j.apcata.2021.118379· OSTI ID:1837073

Ferrandon, Magali S. ^[1];

^[2];

^[3]; Zhang, Yuying ^[2];

^[2]; Sloppy, Jennifer ^[2]; McCormick, Rachel A. ^[2]; Booksh, Karl ^[2]; Teplyakov, Andrew V. ^[2];

^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)
Univ. of Delaware, Newark, DE (United States)
Argonne National Lab. (ANL), Argonne, IL (United States); Middle East Technical Univ., Ankara (Turkey)

High-throughput synthesis of a series of monometallic and bimetallic catalysts (45 bimetallic and 50 monometallic samples) consisting of nickel and one of nine different metal promoters (B, Co, Cu, Fe, Mg, Mn, Sn, V and Zn) supported on one of six different metal oxides alumina, ceria, magnesia, silica and titania) is carried out via organometallic grafting using a robotic platform. The catalysts are evaluated for their activity and selectivity for the dry reforming of methane at a feed ratio of CH₄:CO₂ of 1 at 650–800 °C in a parallel flow reactor system. The type of oxide support prevails over the type of additive for both catalyst activity and stability. On Al₂O₃ and MgO, Fe was found to be the best promoter; on SiO₂, Cu is the best promoter at 700 °C and higher, while on TiO₂, Mn is found to enhance the conversion at 800 °C. On CeO₂, all additives except Fe have beneficial effects. Twenty-five catalysts show > 90% methane conversion with ten catalysts showing > 95% conversion at 800 °C with the H₂:CO ratios ranging from 0.8 to 1.2. Amongst the ten highest performers, NiFe/Al₂O₃ and NiFe/MgO are more active than Ni/Al₂O₃ and Ni/MgO, respectively and were stable over a period of 25 h at 800 °C. Characterization on the as-prepared samples reveals highly dispersed phase, while after reduction in H₂, highly dispersed and reduced nickel particles up to 10 nm are formed. The particles do not increase in size under dry reforming reaction conditions at 800 °C. An increased hydrogen consumption observed during H₂-TPR of the nickel particles is positively correlated with methane conversion for Al₂O₃-based catalysts. The resistance to deactivation by coking and variation in coke structure are investigated by spectroscopic and microscopic methods to identify the relationship between metal promoters, alloy formation, and type of surface carbon deposits. Carbon whiskers were observed on the ten selected spent samples and are preferentially deposited on Ni rather than on the promoters. Carbon nanotube formation and metal particle removal from support were not observed to cause deactivation while amorphous carbon formation was clearly linked to catalyst deactivation, as amorphous carbon could encapsulate nickel, either on the support or at the end of the carbon nanotube. Furthermore, the organometallic grafting technique is an efficient and suitable technique for synthesizing highly dispersed and homogeneous phases which lead to high conversion and high durability for dry reforming of methane.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1837073

Journal Information:: Applied Catalysis. A, General, Vol. 629; ISSN 0926-860X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (106)

Catalytic performance of highly dispersed Ni/TiO2 for dry and steam reforming of methane Shinde, Vijay M.; Madras, Giridhar RSC Advances, Vol. 4, Issue 10 https://doi.org/10.1039/c3ra45961f	journal	January 2014
In Situ Raman Study of Nickel Oxide and Gold-Supported Nickel Oxide Catalysts for the Electrochemical Evolution of Oxygen Yeo, Boon Siang; Bell, Alexis T. The Journal of Physical Chemistry C, Vol. 116, Issue 15 https://doi.org/10.1021/jp3007415	journal	April 2012
The metal-alkyl bond energy of the iron(100)-hydrogen-ethyl surface complex Burke, M. L.; Madix, R. J. Journal of the American Chemical Society, Vol. 114, Issue 8 https://doi.org/10.1021/ja00034a002	journal	April 1992
Role of CeO2 in Ni/CeO2–Al2O3 catalysts for carbon dioxide reforming of methane Wang, Shaobin; (Max) Lu, G. Q. Applied Catalysis B: Environmental, Vol. 19, Issue 3-4 https://doi.org/10.1016/S0926-3373(98)00081-2	journal	December 1998
Large enhancement in methane-to-syngas conversion activity of supported Ni catalysts due to precoating of catalyst supports with MgO, CaO or rare-earth oxide Choudhary, V. R.; Uphade, B. S.; Mamman, A. S. Catalysis Letters, Vol. 32, Issue 3-4 https://doi.org/10.1007/BF00813233	journal	January 1995
Raman studies of amorphous carbon thin films Yukhnovets, Olessya I.; Maximov, Alexander I.; Mazing, Dmitry S. 2017 IEEE Conference of Russian Young Researchers in Electrical and Electronic Engineering (EIConRus) https://doi.org/10.1109/EIConRus.2017.7910780	conference	January 2017
Diameter-Controlled Synthesis of Carbon Nanotubes Cheung, Chin Li; Kurtz, Andrea; Park, Hongkun The Journal of Physical Chemistry B, Vol. 106, Issue 10 https://doi.org/10.1021/jp0142278	journal	March 2002
Non-thermal plasma assisted synthesis and physicochemical characterizations of Co and Cu doped Ni/Al2O3 nanocatalysts used for dry reforming of methane Rahemi, Nader; Haghighi, Mohammad; Babaluo, Ali Akbar International Journal of Hydrogen Energy, Vol. 38, Issue 36 https://doi.org/10.1016/j.ijhydene.2013.08.084	journal	December 2013
A Guide to and Review of the Use of Multiwavelength Raman Spectroscopy for Characterizing Defective Aromatic Carbon Solids: from Graphene to Amorphous Carbons Merlen, Alexandre; Buijnsters, Josephus; Pardanaud, Cedric Coatings, Vol. 7, Issue 10 https://doi.org/10.3390/coatings7100153	journal	September 2017
Raman and infrared-active modes in MgO nanotubes Chen, Liang; Xu, Can; Zhang, Xiao-Fang Physica E: Low-dimensional Systems and Nanostructures, Vol. 41, Issue 5 https://doi.org/10.1016/j.physe.2009.01.006	journal	March 2009
Interpretation of Raman spectra of disordered and amorphous carbon Ferrari, A. C.; Robertson, J. Physical Review B, Vol. 61, Issue 20, p. 14095-14107 https://doi.org/10.1103/PhysRevB.61.14095	journal	May 2000
Dry Reforming of Hydrocarbon Feedstocks Shah, Yatish T.; Gardner, Todd H. Catalysis Reviews, Vol. 56, Issue 4 https://doi.org/10.1080/01614940.2014.946848	journal	September 2014
Atomically dispersed nickel as coke-resistant active sites for methane dry reforming Akri, Mohcin; Zhao, Shu; Li, Xiaoyu Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12843-w	journal	November 2019
The mean bond dissociation energy of the carbonmagnesium bond in bis(2,2-dimethylpropyl)magnesium Akkerman, O. S.; Schat, G.; Evers, E. A. I. M. Recueil des Travaux Chimiques des Pays-Bas, Vol. 102, Issue 2 https://doi.org/10.1002/recl.19831020209	journal	January 1983
Effect of potassium content in the activity of K-promoted Ni/Al2O3 catalysts for the dry reforming of methane Juan-Juan, J.; Román-Martínez, M. C.; Illán-Gómez, M. J. Applied Catalysis A: General, Vol. 301, Issue 1 https://doi.org/10.1016/j.apcata.2005.11.006	journal	February 2006
The influence of carbon nanotube (CNT) morphology and diameter on the processing and properties of CNT-reinforced aluminium composites Esawi, A. M. K.; Morsi, K.; Sayed, A. Composites Part A: Applied Science and Manufacturing, Vol. 42, Issue 3 https://doi.org/10.1016/j.compositesa.2010.11.008	journal	March 2011
Boron-modified Ni/Al2O3 catalysts for reduced carbon deposition during dry reforming of methane Fouskas, A.; Kollia, M.; Kambolis, A. Applied Catalysis A: General, Vol. 474 https://doi.org/10.1016/j.apcata.2013.08.016	journal	March 2014
A review on coke management during dry reforming of methane: Revisiting coke management in dry reforming of methane Muraza, Oki; Galadima, Ahmad International Journal of Energy Research, Vol. 39, Issue 9 https://doi.org/10.1002/er.3295	journal	January 2015
Carbon deposition on borated alumina supported nano-sized Ni catalysts for dry reforming of CH4 Ni, Jun; Chen, Luwei; Lin, Jianyi Nano Energy, Vol. 1, Issue 5 https://doi.org/10.1016/j.nanoen.2012.07.011	journal	September 2012
First principles calculations and experimental insight into methane steam reforming over transition metal catalysts Jones, G.; Jakobsen, J.; Shim, S. Journal of Catalysis, Vol. 259, Issue 1 https://doi.org/10.1016/j.jcat.2008.08.003	journal	October 2008
Nanoparticle size, oxidation state, and sensing response of tin oxide nanopowders using Raman spectroscopy Vijayarangamuthu, K.; Rath, Shyama Journal of Alloys and Compounds, Vol. 610 https://doi.org/10.1016/j.jallcom.2014.04.187	journal	October 2014
Field emission response from multi-walled carbon nanotubes grown on electrochemically engineered copper foil Tripathi, Amit Kumar; Jain, Vaibhav; Saini, Krishna Materials Chemistry and Physics, Vol. 187 https://doi.org/10.1016/j.matchemphys.2016.11.041	journal	February 2017
Robust mesoporous bimetallic yolk–shell catalysts for chemical CO ₂ upgrading via dry reforming of methane Price, Cameron-Alexander Hurd; Pastor-Pérez, Laura; Ramirez Reina, Tomas Reaction Chemistry & Engineering, Vol. 3, Issue 4 https://doi.org/10.1039/C8RE00058A	journal	January 2018
Cobalt Catalyst Grown Carbon Nanotube/Poly(Vinylidene Fluoride) Nanocomposites: Effect of Synthesis Temperature on Morphology, Electrical Conductivity and Electromagnetic Interference Shielding Keteklahijani, Yalda Zamani; Arjmand, Mohammad; Sundararaj, Uttandaraman ChemistrySelect, Vol. 2, Issue 31 https://doi.org/10.1002/slct.201701929	journal	October 2017
Highly Productive Propane Dehydrogenation Catalyst Using Silica-Supported Ga–Pt Nanoparticles Generated from Single-Sites Searles, Keith; Chan, Ka Wing; Mendes Burak, Jorge Augusto Journal of the American Chemical Society, Vol. 140, Issue 37 https://doi.org/10.1021/jacs.8b05378	journal	August 2018
Water Gas Shift Catalysis Ratnasamy, Chandra; Wagner, Jon P. Catalysis Reviews, Vol. 51, Issue 3 https://doi.org/10.1080/01614940903048661	journal	September 2009
Development of stable bimetallic catalysts for carbon dioxide reforming of methane Zhang, J.; Wang, H.; Dalai, A. Journal of Catalysis, Vol. 249, Issue 2 https://doi.org/10.1016/j.jcat.2007.05.004	journal	July 2007
Micro-Raman investigation of iron oxide films and powders produced by sol-gel syntheses Bersani, D.; Lottici, P. P.; Montenero, A. Journal of Raman Spectroscopy, Vol. 30, Issue 5 https://doi.org/10.1002/(SICI)1097-4555(199905)30:5<355::AID-JRS398>3.0.CO;2-C	journal	May 1999
Effect of synthesis parameters on morphology and activity of bimetallic catalysts in CO 2 –CH 4 reforming Osojnik Črnivec, I. G.; Djinović, P.; Erjavec, B. Chemical Engineering Journal, Vol. 207-208 https://doi.org/10.1016/j.cej.2012.06.107	journal	October 2012
The Fischer–Tropsch process: 1950–2000 Dry, Mark E. Catalysis Today, Vol. 71, Issue 3-4 https://doi.org/10.1016/S0920-5861(01)00453-9	journal	January 2002
Controlling Carbon Surface Chemistry by Alloying: Carbon Tolerant Reforming Catalyst Nikolla, Eranda; Holewinski, Adam; Schwank, Johannes Journal of the American Chemical Society, Vol. 128, Issue 35 https://doi.org/10.1021/ja0638298	journal	September 2006
Alumina coated nickel nanoparticles as a highly active catalyst for dry reforming of methane Baktash, Elham; Littlewood, Patrick; Schomäcker, Reinhard Applied Catalysis B: Environmental, Vol. 179 https://doi.org/10.1016/j.apcatb.2015.05.018	journal	December 2015
Molecular dynamics study of the stability of a carbon nanotube atop a catalytic nanoparticle Verkhovtsev, Alexey V.; Schramm, Stefan; Solov’yov, Andrey V. The European Physical Journal D, Vol. 68, Issue 9 https://doi.org/10.1140/epjd/e2014-50371-4	journal	September 2014
Dry reforming of methane over Ni/dendritic fibrous SBA-15 (Ni/DFSBA-15): Optimization, mechanism, and regeneration studies Chong, Chi Cheng; Cheng, Yoke Wang; Setiabudi, H. D. International Journal of Hydrogen Energy, Vol. 45, Issue 15 https://doi.org/10.1016/j.ijhydene.2020.01.056	journal	March 2020
Synthesis of Nickel‐Doped Ceria Catalysts for Selective Acetylene Hydrogenation Riley, Christopher; De La Riva, Andrew; Zhou, Shulan ChemCatChem, Vol. 11, Issue 5 https://doi.org/10.1002/cctc.201801976	journal	February 2019
Metal oxide (MgO, CaO, and La2O3) promoted Ni-Ce0.8Zr0.2O2 catalysts for H2 and CO production from two major greenhouse gases Jang, Won-Jun; Jeong, Dae-Woon; Shim, Jae-Oh Renewable Energy, Vol. 79 https://doi.org/10.1016/j.renene.2014.08.032	journal	July 2015
Reforming of methane with CO2 over Ni nanoparticle supported on mesoporous ZSM-5 Sarkar, Bipul; Tiwari, Ritesh; Singha, Rajib Kumar Catalysis Today, Vol. 198, Issue 1 https://doi.org/10.1016/j.cattod.2012.04.029	journal	December 2012
Raman scattering in nanosized nickel oxide NiO Mironova-Ulmane, N.; Kuzmin, A.; Steins, I. Journal of Physics: Conference Series, Vol. 93 https://doi.org/10.1088/1742-6596/93/1/012039	journal	December 2007
Silica–Ceria sandwiched Ni core–shell catalyst for low temperature dry reforming of biogas: Coke resistance and mechanistic insights Das, S.; Ashok, J.; Bian, Z. Applied Catalysis B: Environmental, Vol. 230 https://doi.org/10.1016/j.apcatb.2018.02.041	journal	August 2018
Recent advances in dry reforming of methane over Ni-based catalysts Abdullah, Bawadi; Abd Ghani, Nur Azeanni; Vo, Dai-Viet N. Journal of Cleaner Production, Vol. 162 https://doi.org/10.1016/j.jclepro.2017.05.176	journal	September 2017
The length, strength and polarity of metal–carbon bonds: dialkylzinc compounds studied by density functional theory calculations, gas electron diffraction and photoelectron spectroscopy Haaland, Arne; Green, Jennifer C.; McGrady, G. Sean Dalton Trans., Issue 22 https://doi.org/10.1039/B306840B	journal	January 2003
In Situ Stimulated Raman Spectroscopy Reveals the Phosphate Network in the Amorphous Cobalt Oxide Catalyst and Its Role in the Catalyst Formation Eom, C. John; Suntivich, Jin The Journal of Physical Chemistry C, Vol. 123, Issue 48 https://doi.org/10.1021/acs.jpcc.9b10308	journal	November 2019
CO ₂ Reforming of CH ₄ Bradford, M. C. J.; Vannice, M. A. Catalysis Reviews, Vol. 41, Issue 1 https://doi.org/10.1081/CR-100101948	journal	February 1999
Nickel-based tri-reforming catalyst for the production of synthesis gas Kang, Jung Shik; Kim, Dae Hyun; Lee, Sang Deuk Applied Catalysis A: General, Vol. 332, Issue 1 https://doi.org/10.1016/j.apcata.2007.08.017	journal	November 2007
Methanol to Olefins (MTO): From Fundamentals to Commercialization Tian, Peng; Wei, Yingxu; Ye, Mao ACS Catalysis, Vol. 5, Issue 3 https://doi.org/10.1021/acscatal.5b00007	journal	February 2015
Growth of multiwalled carbon nanotube arrays by chemical vapour deposition over iron catalyst and the effect of growth parameters Radhakrishnan, J. K.; Pandian, P. S.; Padaki, V. C. Applied Surface Science, Vol. 255, Issue 12 https://doi.org/10.1016/j.apsusc.2009.02.010	journal	April 2009
Transition metal-hydrogen and metal-carbon bond strengths: the keys to catalysis Simoes, J. A. Martinho; Beauchamp, J. L. Chemical Reviews, Vol. 90, Issue 4 https://doi.org/10.1021/cr00102a004	journal	June 1990
Synthesis strategies of ceria–zirconia doped Ni/SBA-15 catalysts for methane dry reforming Albarazi, Abdulkader; Gálvez, Maria Elena; Da Costa, Patrick Catalysis Communications, Vol. 59 https://doi.org/10.1016/j.catcom.2014.09.050	journal	January 2015
Carbon nanotube growth mechanism switches from tip- to base-growth with decreasing catalyst particle size Gohier, A.; Ewels, C. P.; Minea, T. M. Carbon, Vol. 46, Issue 10, p. 1331-1338 https://doi.org/10.1016/j.carbon.2008.05.016	journal	August 2008
Ni-alumina dry reforming catalysts: Atomic layer deposition and the issue of Ni aluminate Littlewood, Patrick; Liu, Shengsi; Weitz, Eric Catalysis Today, Vol. 343 https://doi.org/10.1016/j.cattod.2019.03.040	journal	March 2020
The deposition of coke from methane on a Ni/MgAl2O4 catalyst Guo, Jianjun; Lou, Hui; Zheng, Xiaoming Carbon, Vol. 45, Issue 6 https://doi.org/10.1016/j.carbon.2007.01.011	journal	May 2007
Electronic Raman Scattering in Copper Oxide Superconductors Einzel, Dietrich; Hackl, Rudi Journal of Raman Spectroscopy, Vol. 27, Issue 3-4 https://doi.org/10.1002/(SICI)1097-4555(199603)27:3/4<307::AID-JRS966>3.0.CO;2-J	journal	March 1996
Pressure dilution, a new method to prepare a stable Ni/fumed silica catalyst for the dry reforming of methane Danghyan, V.; Calderon Novoa, S.; Mukasyan, A. Applied Catalysis B: Environmental, Vol. 234 https://doi.org/10.1016/j.apcatb.2018.04.033	journal	October 2018
Comparison of structural changes in nitrogen and boron-doped multi-walled carbon nanotubes Koós, Antal A.; Dillon, Frank; Obraztsova, Ekaterina A. Carbon, Vol. 48, Issue 11 https://doi.org/10.1016/j.carbon.2010.04.026	journal	September 2010
An overview on dry reforming of methane: strategies to reduce carbonaceous deactivation of catalysts Arora, Shalini; Prasad, R. RSC Advances, Vol. 6, Issue 110 https://doi.org/10.1039/C6RA20450C	journal	January 2016
Industrial scale experience on steam reforming of CO 2 -rich gas Mortensen, Peter Mølgaard; Dybkjær, Ib Applied Catalysis A: General, Vol. 495 https://doi.org/10.1016/j.apcata.2015.02.022	journal	April 2015
Yolk–Satellite–Shell Structured Ni–Yolk@Ni@SiO ₂ Nanocomposite: Superb Catalyst toward Methane CO ₂ Reforming Reaction Li, Ziwei; Mo, Liuye; Kathiraser, Yasotha ACS Catalysis, Vol. 4, Issue 5 https://doi.org/10.1021/cs401027p	journal	April 2014
The Properties of Individual Carbon Residuals and Their Influence on The Deactivation of Ni-CaO-ZrO ₂ Catalysts in CH ₄ Dry Reforming Wang, Changzhen; Sun, Nannan; Zhao, Ning ChemCatChem, Vol. 6, Issue 2 https://doi.org/10.1002/cctc.201300754	journal	January 2014
Coke formation and deactivation during catalytic reforming of biomass and waste pyrolysis products: A review Ochoa, Aitor; Bilbao, Javier; Gayubo, Ana G. Renewable and Sustainable Energy Reviews, Vol. 119 https://doi.org/10.1016/j.rser.2019.109600	journal	March 2020
Development of Ni–Al Catalysts for Hydrogen and Carbon Nanofibre Production by Catalytic Decomposition of Methane. Effect of MgO Addition Latorre, N.; Villacampa, J. I.; Ubieto, T. Topics in Catalysis, Vol. 51, Issue 1-4 https://doi.org/10.1007/s11244-008-9124-x	journal	October 2008
TEM evidence for factors affecting the genesis of carbon species on bare and K-promoted Ni/MgO catalysts during the dry reforming of methane Frusteri, F.; Spadaro, L.; Arena, F. Carbon, Vol. 40, Issue 7 https://doi.org/10.1016/S0008-6223(01)00243-3	journal	June 2002
In Situ Raman Spectroscopy of Copper and Copper Oxide Surfaces during Electrochemical Oxygen Evolution Reaction: Identification of Cu ^III Oxides as Catalytically Active Species Deng, Yilin; Handoko, Albertus D.; Du, Yonghua ACS Catalysis, Vol. 6, Issue 4 https://doi.org/10.1021/acscatal.6b00205	journal	March 2016
A low temperature reaction sequence for methane conversion Koerts, Tijs; van Santen, Rutger A. Journal of the Chemical Society, Chemical Communications, Issue 18 https://doi.org/10.1039/c39910001281	journal	January 1991
Diameter-Controlled Carbon Nanotubes Grown from Lithographically Defined Nanoparticles Ishida, Masahiko; Hongo, Hiroo; Nihey, Fumiyuki Japanese Journal of Applied Physics, Vol. 43, Issue No. 10B https://doi.org/10.1143/JJAP.43.L1356	journal	September 2004
Carbon dioxide reforming of methane over a metal modified Ni-Al2O3 catalyst Castro Luna, Adolfo E.; Iriarte, María E. Applied Catalysis A: General, Vol. 343, Issue 1-2 https://doi.org/10.1016/j.apcata.2007.11.041	journal	July 2008
Carbon nanotube growth on cobalt-sprayed substrates by thermal CVD Terrado, E.; Redrado, M.; Muñoz, E. Materials Science and Engineering: C, Vol. 26, Issue 5-7 https://doi.org/10.1016/j.msec.2005.09.054	journal	July 2006
Coke study on MgO-promoted Ni/Al2O3 catalyst in combined H2O and CO2 reforming of methane for gas to liquid (GTL) process Koo, Kee Young; Roh, Hyun-Seog; Seo, Yu Taek Applied Catalysis A: General, Vol. 340, Issue 2 https://doi.org/10.1016/j.apcata.2008.02.009	journal	June 2008
Raman Spectrum of Graphite Tuinstra, F.; Koenig, J. L. The Journal of Chemical Physics, Vol. 53, Issue 3 https://doi.org/10.1063/1.1674108	journal	August 1970
Effects of Selected Promoters on Ni/Y-Al2O3 Catalyst Performance in Methane Dry Reforming Al-Fatesh, Ahmed. S. A.; Fakeeha, Anis. H.; Abasaeed, Ahmed. E. Chinese Journal of Catalysis, Vol. 32, Issue 9-10 https://doi.org/10.1016/S1872-2067(10)60267-7	journal	September 2011
Multi-wavelength Raman scattering of nanostructured Al-doped zinc oxide Russo, V.; Ghidelli, M.; Gondoni, P. Journal of Applied Physics, Vol. 115, Issue 7 https://doi.org/10.1063/1.4866322	journal	February 2014
Direct synthesis of graphene/carbon nanotube hybrid films from multiwalled carbon nanotubes on copper Li, Li; Li, Hongbian; Guo, Yichuan Carbon, Vol. 118 https://doi.org/10.1016/j.carbon.2017.03.078	journal	July 2017
Homolytic bond-dissociation enthalpies of tin bonds and tin–ligand bond strengths — A computational study Whittleton, Sarah R.; Boyd, Russell J.; Grindley, T. Bruce Canadian Journal of Chemistry, Vol. 87, Issue 7 https://doi.org/10.1139/V09-033	journal	July 2009
Structural and optical properties of nanophase zinc oxide Du, Y.; Zhang, M. -S.; Hong, J. Applied Physics A: Materials Science & Processing, Vol. 76, Issue 2 https://doi.org/10.1007/s003390201404	journal	February 2003
Small and Narrowly Distributed Copper Nanoparticles Supported on Carbon Prepared by Surface Organometallic Chemistry for Selective Hydrogenation and CO ₂ Electroconversion Processes Mavrokefalos, Christos K.; Kaeffer, Nicolas; Liu, Hsueh‐Ju ChemCatChem, Vol. 12, Issue 1 https://doi.org/10.1002/cctc.201901414	journal	October 2019
Mechanisms of catalyst deactivation Bartholomew, Calvin H. Applied Catalysis A: General, Vol. 212, Issue 1-2 https://doi.org/10.1016/S0926-860X(00)00843-7	journal	April 2001
Synthesis of carbon nanofibers: effects of Ni crystal size during methane decomposition Chen, D.; Christensen, K.; Ochoafernandez, E. Journal of Catalysis, Vol. 229, Issue 1 https://doi.org/10.1016/j.jcat.2004.10.017	journal	January 2005
Potassium-enhanced stability of Ni/MgO catalysts in the dry-reforming of methane Frusteri, F.; Arena, F.; Calogero, G. Catalysis Communications, Vol. 2, Issue 2 https://doi.org/10.1016/S1566-7367(01)00008-5	journal	May 2001
Diameter-specific growth of single-walled carbon nanotubes using tungsten supported nickel catalysts Li, Meihui; Yang, Feng; Ding, Li Carbon, Vol. 118 https://doi.org/10.1016/j.carbon.2017.03.083	journal	July 2017
Studies on coke formation and coke species of nickel-based catalysts in CO2 reforming of CH4 Xiancai, Li; Shuigen, Li; Yifeng, Yang Catalysis Letters, Vol. 118, Issue 1-2 https://doi.org/10.1007/s10562-007-9140-7	journal	June 2007
Effect of Crystallographic Orientation on the Corrosion of Magnesium: Comparison of Film Forming and Bare Crystal Facets using Electrochemical Impedance and Raman Spectroscopy Bland, Leslie G.; Gusieva, K.; Scully, J. R. Electrochimica Acta, Vol. 227 https://doi.org/10.1016/j.electacta.2016.12.107	journal	February 2017
High Capacity and Excellent Stability of Lithium Ion Battery Anode Using Interface-Controlled Binder-Free Multiwall Carbon Nanotubes Grown on Copper Lahiri, Indranil; Oh, Sung-Woo; Hwang, Jun Y. ACS Nano, Vol. 4, Issue 6 https://doi.org/10.1021/nn100400r	journal	May 2010
Hexagonal boron nitride supported mesoSiO ₂ -confined Ni catalysts for dry reforming of methane Cao, Yang; Lu, Meirong; Fang, Jianhui Chemical Communications, Vol. 53, Issue 54 https://doi.org/10.1039/C7CC02007D	journal	January 2017
Production of synthesis gas Rostrup-Nielsen, J. R. Catalysis Today, Vol. 18, Issue 4 https://doi.org/10.1016/0920-5861(93)80059-A	journal	December 1993
Surface properties of a coke-free Sn doped nickel catalyst for the CO2 reforming of methane Hou, Zhaoyin; Yokota, Osamu; Tanaka, Takumi Applied Surface Science, Vol. 233, Issue 1-4 https://doi.org/10.1016/j.apsusc.2004.03.223	journal	June 2004
Influence of particle size on the activity and stability in steam methane reforming of supported Rh nanoparticles Ligthart, D. A. J. M.; van Santen, R. A.; Hensen, E. J. M. Journal of Catalysis, Vol. 280, Issue 2 https://doi.org/10.1016/j.jcat.2011.03.015	journal	June 2011
Ni–Sn-Supported ZrO ₂ Catalysts Modified by Indium for Selective CO ₂ Hydrogenation to Methanol Hengne, Amol M.; Samal, Akshaya K.; Enakonda, Linga Reddy ACS Omega, Vol. 3, Issue 4 https://doi.org/10.1021/acsomega.8b00211	journal	April 2018
Carbon dioxide reforming of methane over promoted NixMg1−xO (111) platelet catalyst derived from solvothermal synthesis Yu, Mingjue; Zhu, Kake; Liu, Zhicheng Applied Catalysis B: Environmental, Vol. 148-149 https://doi.org/10.1016/j.apcatb.2013.10.046	journal	April 2014
The influence of high dielectric constant aluminum oxide sputter deposition on the structure and properties of multilayer epitaxial graphene Maneshian, Mohammad H.; Kuo, Fang-Ling; Mahdak, Kristopher Nanotechnology, Vol. 22, Issue 20 https://doi.org/10.1088/0957-4484/22/20/205703	journal	March 2011
On the stability of copper(II) organic compounds with the σ bond Cu-C: A quantum-chemical study Golubeva, E. N.; Zhidomirov, G. M.; Kokorin, A. I. Doklady Chemistry, Vol. 426, Issue 2 https://doi.org/10.1134/S0012500809060081	journal	June 2009
Experimental studies of the formation process and morphologies of carbon nanotubes with bamboo mode structures Wang, Y. Y.; Tang, G. Y.; Koeck, F. A. M. Diamond and Related Materials, Vol. 13, Issue 4-8 https://doi.org/10.1016/j.diamond.2004.01.009	journal	April 2004
Synthesis of Multiwalled Carbon Nanotubes by Catalytic Combustion of Polypropylene Tang, Tao; Chen, Xuecheng; Meng, Xiaoyu Angewandte Chemie International Edition, Vol. 44, Issue 10 https://doi.org/10.1002/anie.200461506	journal	February 2005
Utilization of Greenhouse Gases through Dry Reforming: Screening of Nickel-Based Bimetallic Catalysts and Kinetic Studies Fan, Mun-Sing; Abdullah, Ahmad Zuhairi; Bhatia, Subhash ChemSusChem, Vol. 4, Issue 11 https://doi.org/10.1002/cssc.201100113	journal	October 2011
Effect of alkaline earth promoters (MgO, CaO, and BaO) on the activity and coke formation of Ni catalysts supported on nanocrystalline Al2O3 in dry reforming of methane Alipour, Zahra; Rezaei, Mehran; Meshkani, Fereshteh Journal of Industrial and Engineering Chemistry, Vol. 20, Issue 5 https://doi.org/10.1016/j.jiec.2013.11.018	journal	September 2014
A review on dry reforming of methane in aspect of catalytic properties Jang, Won-Jun; Shim, Jae-Oh; Kim, Hak-Min Catalysis Today, Vol. 324 https://doi.org/10.1016/j.cattod.2018.07.032	journal	March 2019
Purity assessment of multiwalled carbon nanotubes by Raman spectroscopy DiLeo, Roberta A.; Landi, Brian J.; Raffaelle, Ryne P. Journal of Applied Physics, Vol. 101, Issue 6 https://doi.org/10.1063/1.2712152	journal	March 2007
Experimental comparison of N(1s) X-ray photoelectron spectroscopy binding energies of hard and elastic amorphous carbon nitride films with reference organic compounds Gammon, W. J.; Kraft, O.; Reilly, A. C. Carbon, Vol. 41, Issue 10 https://doi.org/10.1016/S0008-6223(03)00170-2	journal	January 2003
Fast and easy preparation of few-layered-graphene/magnesia powders for strong, hard and electrically conducting composites Weibel, Alicia; Mesguich, David; Chevallier, Geoffroy Carbon, Vol. 136 https://doi.org/10.1016/j.carbon.2018.04.085	journal	September 2018
Thermal Decomposition of Nickel Oxalate Dihydrate: A Detailed XPS Insight Chenakin, Sergey; Kruse, Norbert The Journal of Physical Chemistry C, Vol. 123, Issue 51 https://doi.org/10.1021/acs.jpcc.9b07879	journal	December 2019
Dynamics of the rutile structure. III. Lattice dynamics, infrared and Raman spectra of SnO ₂ Katiyar, R. S.; Dawson, P.; Hargreave, M. M. Journal of Physics C: Solid State Physics, Vol. 4, Issue 15 https://doi.org/10.1088/0022-3719/4/15/027	journal	October 1971
Characterization of cobalt oxides studied by FT-IR, Raman, TPR and TG-MS Tang, Chih-Wei; Wang, Chen-Bin; Chien, Shu-Hua Thermochimica Acta, Vol. 473, Issue 1-2, p. 68-73 https://doi.org/10.1016/j.tca.2008.04.015	journal	July 2008
Determination of Co–C bond dissociation energies for organocobalt complexes related to coenzyme B12 using photoacoustic calorimetry Li, Gang; Zhang, Fei Fei; Chen, Hao Journal of the Chemical Society, Dalton Transactions, Issue 1 https://doi.org/10.1039/b102173g	journal	November 2001
Methane dry reforming over Ni/fibrous SBA-15 catalysts: Effects of support morphology (rod-liked F-SBA-15 and dendritic DFSBA-15) Chong, Chi Cheng; Cheng, Yoke Wang; Bukhari, Syahida Nasuha Catalysis Today, Vol. 375 https://doi.org/10.1016/j.cattod.2020.06.073	journal	September 2021
Production of hydrogen peroxide from carbon monoxide, water and oxygen over alumina-supported Ni catalysts Ma, Zhong-Long; Jia, Rong-Li; Liu, Chang-Jun Journal of Molecular Catalysis A: Chemical, Vol. 210, Issue 1-2 https://doi.org/10.1016/j.molcata.2003.09.021	journal	March 2004
Design of active and stable NiCeO2ZrO2MgAl2O4 dry reforming catalysts Corthals, Steven; Van Nederkassel, Joris; De Winne, Hendrik Applied Catalysis B: Environmental, Vol. 105, Issue 3-4 https://doi.org/10.1016/j.apcatb.2011.04.008	journal	June 2011
A review of dry (CO ₂ ) reforming of methane over noble metal catalysts Pakhare, Devendra; Spivey, James Chem. Soc. Rev., Vol. 43, Issue 22 https://doi.org/10.1039/C3CS60395D	journal	January 2014
Elimination of D-band in Raman spectra of double-wall carbon nanotubes by oxidation Osswald, S.; Flahaut, E.; Ye, H. Chemical Physics Letters, Vol. 402, Issue 4-6 https://doi.org/10.1016/j.cplett.2004.12.066	journal	February 2005

Similar Records

Utilizing bimetallic catalysts to mitigate coke formation in dry reforming of methane

Journal Article · Mon Dec 06 00:00:00 EST 2021 · Journal of Energy Chemistry · OSTI ID:1837073

Sasson Bitters, Jaylin; He, Tina; Nestler, Elizabeth; +3 more

Sulfur poisoning of CeO[subscript 2]-Al[subscript 2]O[subscript 3]-supported mono- and bi-metallic Ni and Rh catalysts in steam reforming of liquid hydrocarbons at low and high temperatures

Journal Article · Wed Dec 01 00:00:00 EST 2010 · Appl. Catal. A-Gen. · OSTI ID:1837073

Xie, Chao; Chen, Yongsheng; Li, Yan; +2 more

Nanowire-Based Materials as Coke-Resistant Catalyst Supports for Dry Methane Reforming

Journal Article · Thu Jan 28 00:00:00 EST 2021 · Catalysts · OSTI ID:1837073

Nambo, Apolo; Atla, Veerendra; Vasireddy, Sivakumar; +4 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CO2
dry reforming
high throughput
methane
nickel
promoter
deactivitation
coke
Raman
XPS
XRD
SEM
TEM
TPR

Title: Grafted nickel-promoter catalysts for dry reforming of methane identified through high-throughput experimentation

Citation Formats

References (106)

Similar Records

Related Subjects