Superior CO2/N2 separation performance of highly branched Poly(1,3 dioxolane) plasticized by polyethylene glycol

Guo, Wenji; Tran, Thien N.; Mondal, Himangshu; Schaefer, Skye; Huang, Liang; Lin, Haiqing

doi:10.1016/j.memsci.2022.120352

Title: Superior CO₂/N₂ separation performance of highly branched Poly(1,3 dioxolane) plasticized by polyethylene glycol

Journal Article · Wed Feb 09 00:00:00 EST 2022 · Journal of Membrane Science

DOI:https://doi.org/10.1016/j.memsci.2022.120352· OSTI ID:1865818

^[1];

^[1]; Schaefer, Skye ^[1];

^[1];

^[1]

State Univ. of New York (SUNY) at Buffalo, NY (United States)

With its high content of CO₂-philic ether oxygen groups, poly(1,3-dioxolane) (PDXLA) has emerged as an attractive platform to achieve excellent CO₂/N₂ separation properties for post-combustion carbon capture. Herein we demonstrate that the separation properties of PDXLA can be further enhanced by plasticizing with miscible polyethylene glycol (PEG)-based additives using an integrated experimentation and modeling approach. The effects of the chain end groups and loading level of the additives on the physical properties of the blends are thoroughly investigated, including glass transition temperature (T_g), fractional free volume, and gas transport properties, and the effects can be satisfactorily described using models available for homogeneous blends. Notably, a T_g-integrated free volume model is adapted to successfully interpret the unified effect of the blend composition and temperature on gas diffusivity and permeability. A sample containing 45 mass% PEG dimethyl ether (PEGDME with a molecular mass of 240 g/mol) displays stable mixed-gas CO₂ permeability of 1540 Barrer and CO₂/N₂ selectivity of 40 when challenged with a model flue gas at 60 °C, outperforming Robeson's 2008 upper bound. Elucidating how small plasticizers impact gas transport in homogeneous blends may unravel a facile way to design high-performance membranes for gas separations.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: State Univ. of New York (SUNY) at Buffalo, NY (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE); National Science Foundation (NSF)

Grant/Contract Number:: FE0031736; NSF-1554236

OSTI ID:: 1865818

Alternate ID(s):: OSTI ID: 1845040

Journal Information:: Journal of Membrane Science, Vol. 648; ISSN 0376-7388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (43)

Polymeric membranes for CO2 separation and capture Han, Yang; Ho, W. S. Winston Journal of Membrane Science, Vol. 628 https://doi.org/10.1016/j.memsci.2021.119244	journal	June 2021
Mixed matrix membranes for post-combustion carbon capture: From materials design to membrane engineering Hu, Leiqing; Clark, Krysta; Alebrahim, Taliehsadat Journal of Membrane Science, Vol. 644 https://doi.org/10.1016/j.memsci.2021.120140	journal	February 2022
50th Anniversary Perspective : Polymers and Mixed Matrix Membranes for Gas and Vapor Separation: A Review and Prospective Opportunities Galizia, Michele; Chi, Won Seok; Smith, Zachary P. Macromolecules, Vol. 50, Issue 20 https://doi.org/10.1021/acs.macromol.7b01718	journal	October 2017
Membrane properties required for post-combustion CO2 capture at coal-fired power plants Roussanaly, Simon; Anantharaman, Rahul; Lindqvist, Karl Journal of Membrane Science, Vol. 511 https://doi.org/10.1016/j.memsci.2016.03.035	journal	August 2016
Rational design of poly(ethylene oxide) based membranes for sustainable CO ₂ capture Zhu, Bin; Jiang, Xu; He, Shanshan Journal of Materials Chemistry A, Vol. 8, Issue 46 https://doi.org/10.1039/D0TA08806D	journal	January 2020
High-Performance Polymers for Membrane CO ₂ /N ₂ Separation Liu, Junyi; Hou, Xianda; Park, Ho Bum Chemistry - A European Journal, Vol. 22, Issue 45 https://doi.org/10.1002/chem.201603002	journal	August 2016
Compositionally Controlled Polyether Membranes via Mono(μ-alkoxo)bis(alkylaluminum)-Initiated Chain-Growth Network Epoxide Polymerization: Synthesis and Transport Properties Rodriguez, Christina G.; Chwatko, Malgorzata; Park, Jaesung Macromolecules, Vol. 53, Issue 4 https://doi.org/10.1021/acs.macromol.9b02318	journal	February 2020
Influence of chemical structure of short chain pendant groups on gas transport properties of cross-linked poly(ethylene oxide) copolymers Kusuma, Victor A.; Freeman, Benny D.; Borns, Matthew A. Journal of Membrane Science, Vol. 327, Issue 1-2 https://doi.org/10.1016/j.memsci.2008.11.022	journal	February 2009
Transport and structural characteristics of crosslinked poly(ethylene oxide) rubbers Lin, H.; Wagner, E.; Swinnea, J. Journal of Membrane Science, Vol. 276, Issue 1-2 https://doi.org/10.1016/j.memsci.2005.09.040	journal	May 2006
Permeation properties to CO2 and N2 of poly(ethylene oxide)-containing and crosslinked polymer films Hirayama, Yusei; Kase, Yoji; Tanihara, Nozomu Journal of Membrane Science, Vol. 160, Issue 1 https://doi.org/10.1016/S0376-7388(99)00080-0	journal	July 1999
Peculiarity of a CO2-philic block copolymer confined in thin films with constrained thickness: “a super membrane for CO2-capture” Yave, Wilfredo; Huth, Heiko; Car, Anja Energy & Environmental Science, Vol. 4, Issue 11 https://doi.org/10.1039/c1ee02139g	journal	January 2011
Poly(ethylene glycol) and poly(dimethyl siloxane): Combining their advantages into efficient CO2 gas separation membranes Reijerkerk, Sander R.; Knoef, Michel H.; Nijmeijer, Kitty Journal of Membrane Science, Vol. 352, Issue 1-2 https://doi.org/10.1016/j.memsci.2010.02.008	journal	April 2010
Gas transport properties of poly(ether-b-amide) segmented block copolymers Bondar, V. I.; Freeman, B. D.; Pinnau, I. Journal of Polymer Science Part B: Polymer Physics, Vol. 38, Issue 15 https://doi.org/10.1002/1099-0488(20000801)38:15<2051::AID-POLB100>3.0.CO;2-D	journal	January 2000
Modification of CO2-selective mixed matrix membranes by a binary composition of poly(ethylene glycol)/NaY zeolite Zhang, Bing; Yang, Chen; Zheng, Yingfei Journal of Membrane Science, Vol. 627 https://doi.org/10.1016/j.memsci.2021.119239	journal	June 2021
Interpenetrating networks of mixed matrix materials comprising metal-organic polyhedra for membrane CO2 capture Liu, Junyi; Fulong, Cressa Ria P.; Hu, Leiqing Journal of Membrane Science, Vol. 606 https://doi.org/10.1016/j.memsci.2020.118122	journal	July 2020
Highly permeable mixed matrix materials comprising ZIF-8 nanoparticles in rubbery amorphous poly(ethylene oxide) for CO2 capture Hu, Leiqing; Liu, Junyi; Zhu, Lingxiang Separation and Purification Technology, Vol. 205 https://doi.org/10.1016/j.seppur.2018.05.012	journal	October 2018
Pushing CO ₂ -philic membrane performance to the limit by designing semi-interpenetrating networks (SIPN) for sustainable CO ₂ separations Jiang, Xu; Li, Songwei; Shao, Lu Energy & Environmental Science, Vol. 10, Issue 6 https://doi.org/10.1039/C6EE03566C	journal	January 2017
Membranes with Fast and Selective Gas-Transport Channels of Laminar Graphene Oxide for Efficient CO ₂ Capture Shen, Jie; Liu, Gongping; Huang, Kang Angewandte Chemie, Vol. 127, Issue 2 https://doi.org/10.1002/ange.201409563	journal	November 2014
CO2-philic mixed matrix membranes based on low-molecular-weight polyethylene glycol and porous organic polymers He, Rongrong; Cong, Shenzhen; Xu, Shuainan Journal of Membrane Science, Vol. 624 https://doi.org/10.1016/j.memsci.2021.119081	journal	April 2021
Nanostructured membrane material designed for carbon dioxide separation Yave, Wilfredo; Car, Anja; Peinemann, Klaus-Viktor Journal of Membrane Science, Vol. 350, Issue 1-2 https://doi.org/10.1016/j.memsci.2009.12.019	journal	March 2010
PEG modified poly(amide-b-ethylene oxide) membranes for CO2 separation Car, Anja.; Stropnik, Chrtomir.; Yave, Wilfredo Journal of Membrane Science, Vol. 307, Issue 1 https://doi.org/10.1016/j.memsci.2007.09.023	journal	January 2008
Mesoblends of Polyether Block Copolymers with Poly(ethylene glycol) Patel, Nikunj P.; Spontak, Richard J. Macromolecules, Vol. 37, Issue 4 https://doi.org/10.1021/ma0356257	journal	February 2004
Green Techniques for Rapid Fabrication of Unprecedentedly High-Performance PEO Membranes for CO ₂ Capture Sun, Wei-Shi; Yin, Ming-Jie; Zhang, Wen-Hai ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 30 https://doi.org/10.1021/acssuschemeng.1c02308	journal	July 2021
Nanoporous framework “reservoir” maximizing low-molecular-weight enhancer impregnation into CO2-philic membranes for highly-efficient CO2 capture Li, Songwei; Jiang, Xu; Yang, Xiaobin Journal of Membrane Science, Vol. 570-571 https://doi.org/10.1016/j.memsci.2018.10.068	journal	January 2019
Improving CO ₂ permeability of ceramic hollow fibre-supported composite membranes by blending an ionic liquid in the Pebax/PEGDME selective layer Cheng, Jun; Hu, Leiqing; Li, Yannan RSC Advances, Vol. 6, Issue 3 https://doi.org/10.1039/C5RA22544B	journal	January 2016
A bio-inspired CO ₂ -philic network membrane for enhanced sustainable gas separation Quan, Shuai; Li, Songwei; Wang, Zhenxing Journal of Materials Chemistry A, Vol. 3, Issue 26 https://doi.org/10.1039/C5TA03232F	journal	January 2015
CO ₂ -Philic Polymer Membrane with Extremely High Separation Performance Yave, Wilfredo; Car, Anja; Funari, Sergio S. Macromolecules, Vol. 43, Issue 1 https://doi.org/10.1021/ma901950u	journal	January 2010
Thermally stable, homogeneous blends of cross-linked poly(ethylene oxide) and crown ethers with enhanced CO2 permeability Huang, Liang; Liu, Junyi; Lin, Haiqing Journal of Membrane Science, Vol. 610 https://doi.org/10.1016/j.memsci.2020.118253	journal	September 2020
Gas transport characteristics of supramolecular networks of metal-coordinated highly branched Poly(ethylene oxide) Alebrahim, Taliehsadat; Chakraborty, Alisa; Hu, Leiqing Journal of Membrane Science, Vol. 644 https://doi.org/10.1016/j.memsci.2021.120063	journal	February 2022
Enhancing CO2 separation performance of Pebax® MH-1657 with aromatic carboxylic acids Meshkat, Shadi; Kaliaguine, Serge; Rodrigue, Denis Separation and Purification Technology, Vol. 212 https://doi.org/10.1016/j.seppur.2018.12.008	journal	April 2019
Highly Polar but Amorphous Polymers with Robust Membrane CO2/N2 Separation Performance Liu, Junyi; Zhang, Shaoze; Jiang, De-en Joule, Vol. 3, Issue 8 https://doi.org/10.1016/j.joule.2019.07.003	journal	August 2019
Effect of Branch Length on the Structural and Separation Properties of Hyperbranched Poly(1,3-dioxolane) Huang, Liang; Guo, Wenji; Mondal, Himangshu Macromolecules, Vol. 55, Issue 1 https://doi.org/10.1021/acs.macromol.1c02045	journal	December 2021
Maximizing Ether Oxygen Content in Polymers for Membrane CO ₂ Removal from Natural Gas Liu, Junyi; Zhang, Gengyi; Clark, Krysta ACS Applied Materials & Interfaces, Vol. 11, Issue 11 https://doi.org/10.1021/acsami.9b01079	journal	February 2019
Prediction of glass transition temperatures: Binary blends and copolymers Brostow, Witold; Chiu, Rachel; Kalogeras, Ioannis M. Materials Letters, Vol. 62, Issue 17-18 https://doi.org/10.1016/j.matlet.2008.02.008	journal	June 2008
Upper bound of polymeric membranes for mixed-gas CO2/CH4 separations Lin, Haiqing; Yavari, Milad Journal of Membrane Science, Vol. 475 https://doi.org/10.1016/j.memsci.2014.10.007	journal	February 2015
Effect of copolymer composition, temperature, and carbon dioxide fugacity on pure- and mixed-gas permeability in poly(ethylene glycol)-based materials: Free volume interpretation Lin, Haiqing; Freeman, Benny D.; Kalakkunnath, Sumod Journal of Membrane Science, Vol. 291, Issue 1-2 https://doi.org/10.1016/j.memsci.2007.01.001	journal	March 2007
Gas transport in homogeneous multicomponent polymers Paul, D. R. Journal of Membrane Science, Vol. 18 https://doi.org/10.1016/S0376-7388(00)85026-7	journal	January 1984
Nafion/PEG hybrid membrane for CO2 separation: Effect of PEG on membrane micro-structure and performance Dai, Zhongde; Aboukeila, Hesham; Ansaloni, Luca Separation and Purification Technology, Vol. 214 https://doi.org/10.1016/j.seppur.2018.03.062	journal	May 2019
Correlation and prediction of gas permeability in glassy polymer membrane materials via a modified free volume based group contribution method Park, J. Y.; Paul, D. R. Journal of Membrane Science, Vol. 125, Issue 1 https://doi.org/10.1016/S0376-7388(96)00061-0	journal	March 1997
Cross-Linked Polyphosphazene Blends as Robust CO ₂ Separation Membranes Kusuma, Victor A.; McNally, Joshua S.; Baker, James S. ACS Applied Materials & Interfaces, Vol. 12, Issue 27 https://doi.org/10.1021/acsami.0c06795	journal	June 2020
Synthesis and Modeling of Polysiloxane-Based Salt-in-Polymer Electrolytes with Various Additives Karatas, Y.; Banhatti, Radha D.; Kaskhedikar, N. The Journal of Physical Chemistry B, Vol. 113, Issue 47 https://doi.org/10.1021/jp907832q	journal	October 2009
Redefining the Robeson upper bounds for CO ₂ /CH ₄ and CO ₂ /N ₂ separations using a series of ultrapermeable benzotriptycene-based polymers of intrinsic microporosity Comesaña-Gándara, Bibiana; Chen, Jie; Bezzu, C. Grazia Energy & Environmental Science, Vol. 12, Issue 9 https://doi.org/10.1039/C9EE01384A	journal	January 2019
Boosting CO2 transport of poly (ethylene oxide) membranes by hollow Rubik-like “expressway” channels with anion pillared hybrid ultramicroporous materials Liu, Niu; Cheng, Jun; Hu, Leiqing Chemical Engineering Journal, Vol. 427 https://doi.org/10.1016/j.cej.2021.130845	journal	January 2022

Similar Records

Effect of Branch Length on the Structural and Separation Properties of Hyperbranched Poly(1,3-dioxolane)

Journal Article · Tue Dec 21 00:00:00 EST 2021 · Macromolecules · OSTI ID:1865818

Huang, Liang; Guo, Wenji; Mondal, Himangshu; +5 more

Thermally stable cross-linked P84 with superior membrane H₂/CO₂ separation properties at 100 °C

Journal Article · Sun Jan 06 00:00:00 EST 2019 · Journal of Membrane Science · OSTI ID:1865818

Omidvar, Maryam; Stafford, Christopher M.; Lin, Haiqing

The CO₂ permeability and mixed gas CO₂/H₂ selectivity of membranes composed of CO₂-philic polymers

Journal Article · Fri Apr 01 00:00:00 EDT 2011 · Journal of Membrane Science · OSTI ID:1865818

Barillas, Mary Katharine; Enick, Robert M.; O’Brien, Michael; +3 more

Related Subjects

59 BASIC BIOLOGICAL SCIENCES
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
poly(1
3-dioxolane)
CO2/N2 separation membranes
Tg-integrated free volume model
polyethylene glycol dimethyl ether
plasticizer

Title: Superior CO2/N2 separation performance of highly branched Poly(1,3 dioxolane) plasticized by polyethylene glycol

Citation Formats

References (43)

Similar Records

Related Subjects

Title: Superior CO₂/N₂ separation performance of highly branched Poly(1,3 dioxolane) plasticized by polyethylene glycol