Effect of Branch Length on the Structural and Separation Properties of Hyperbranched Poly(1,3-dioxolane)

Huang, Liang; Guo, Wenji; Mondal, Himangshu; Schaefer, Skye; Tran, Thien N.; Fan, Shouhong; Ding, Yifu; Lin, Haiqing

doi:10.1021/acs.macromol.1c02045

Effect of Branch Length on the Structural and Separation Properties of Hyperbranched Poly(1,3-dioxolane)

Journal Article · Tue Dec 21 00:00:00 EST 2021 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.1c02045· OSTI ID:1865820

Huang, Liang ^[1]; Guo, Wenji ^[2]; Mondal, Himangshu ^[2]; Schaefer, Skye ^[2]; Tran, Thien N. ^[3]; Fan, Shouhong ^[4]; ^[4]; ^[2]

State Univ. of New York at Buffalo, NY (United States); University at Buffalo
State Univ. of New York at Buffalo, NY (United States)
Department of Chemical and Biological Engineering, University at Buffalo, The State University of New York, Buffalo, New York 14260, United States
Univ. of Colorado, Boulder, CO (United States)

Polymers containing poly(ethylene oxide) (PEO) demonstrate superior membrane CO₂/N₂ separation properties owing to their polar ether oxygen groups exhibiting strong affinity toward CO2. Poly(1,3-dioxolane) (PDXL) shows an ether oxygen content higher than PEO and is expected to have higher CO₂/N₂ solubility selectivity. However, similar to PEO, the high crystallinity of PDXL greatly reduces its gas permeability. Herein, amorphous PDXL-based hyperbranched polymers were synthesized by ring opening of 1,3-dioxolane (DXL) to form poly(1,3-dioxolane) acrylate (DXLAn) followed by photopolymerization. The repeating unit of DXL (n) or branch length was systematically varied from 4 to 12 to yield amorphous polymers. The chemical and physical properties of the obtained polymers (PDXLAn) were thoroughly evaluated and used to interpret pure- and mixed-gas transport characteristics. The polymers exhibit attractive CO₂/N₂ and CO₂/CH₄ separation properties. For example, PDXLA8 exhibits a CO₂ permeability of 220 Barrer and CO₂/N₂ selectivity of 56 at 35 °C, surpassing Robeson’s 2008 upper bound, and it shows robust separation performance when evaluated with simulated flue gas at 60 °C. This study demonstrates that hyperbranched structures are an effective route to construct amorphous yet highly polar polymers and that chain end groups are instrumental in determining the structural and gas transport characteristics.

View Accepted Manuscript (DOE)

Research Organization:: State Univ. of New York at Buffalo, NY (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Fossil Energy (FE)

Grant/Contract Number:: FE0031736

OSTI ID:: 1865820

Journal Information:: Macromolecules, Journal Name: Macromolecules Journal Issue: 1 Vol. 55; ISSN 0024-9297

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Effect of Branch Length on the Structural and Separation Properties of Hyperbranched Poly(1,3-dioxolane)

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