Tailorable multifunctionalities in ultrathin 2D Bi-based layered supercell structures

He, Zihao; Gao, Xingyao; Zhang, Di; Lu, Ping; Wang, Xuejing; Kalaswad, Matias; Rutherford, Bethany X.; Wang, Haiyan

doi:10.1039/d1nr04975e

Title: Tailorable multifunctionalities in ultrathin 2D Bi-based layered supercell structures

Journal Article · Tue Jun 22 00:00:00 EDT 2021 · Nanoscale

DOI:https://doi.org/10.1039/d1nr04975e· OSTI ID:1828785

^[1]; Gao, Xingyao ^[1];

^[1];

^[2]; Wang, Xuejing ^[1]; Kalaswad, Matias ^[1]; Rutherford, Bethany X. ^[1];

^[1]

Purdue Univ., West Lafayette, IN (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Two-dimensional (2D) materials with robust ferromagnetic behavior have attracted great interest because of their potential applications in next-generation nanoelectronic devices. Aside from graphene and transition metal dichalcogenides, Bi-based layered oxide materials are a group of prospective candidates due to their superior room-temperature multiferroic response. In this work, an ultrathin Bi₃Fe₂Mn₂O_10+δ layered supercell (BFMO322 LS) structure was deposited on an LaAlO₃ (LAO) (001) substrate using pulsed laser deposition. Microstructural analysis suggests that a layered supercell (LS) structure consisting of two-layer-thick Bi–O slabs and two-layer-thick Mn/Fe–O octahedra slabs was formed on top of the pseudo-perovskite interlayer (IL). A robust saturation magnetization value of 129 and 96 emu cm^-3 is achieved in a 12.3 nm thick film in the in-plane (IP) and out-of-plane (OP) directions, respectively. The ferromagnetism, dielectric permittivity, and optical bandgap of the ultrathin BFMO films can be effectively tuned by thickness and morphology variation. In addition, the anisotropy of all ultrathin BFMO films switches from OP dominating to IP dominating as the thickness increases. This study demonstrates the ultrathin BFMO film with tunable multifunctionalities as a promising candidate for novel integrated spintronic devices.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); US Department of the Navy, Office of Naval Research (ONR); National Science Foundation (NSF)

Grant/Contract Number:: NA0003525; N00014-1-20-2600; DMR-1809520; DMR-2016453; N00014-17-1-2087; N00014-20-1-2043

OSTI ID:: 1828785

Alternate ID(s):: OSTI ID: 1823180

Report Number(s):: SAND-2021-12554J; 700739

Journal Information:: Nanoscale, Vol. 13, Issue 39; ISSN 2040-3364

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (40)

Novel Layered Supercell Structure from Bi ₂ AlMnO ₆ for Multifunctionalities Li, Leigang; Boullay, Philippe; Lu, Ping Nano Letters, Vol. 17, Issue 11 https://doi.org/10.1021/acs.nanolett.7b02284	journal	October 2017
Recent Progress in Two-Dimensional Oxide Photocatalysts for Water Splitting Ida, Shintaro; Ishihara, Tatsumi The Journal of Physical Chemistry Letters, Vol. 5, Issue 15 https://doi.org/10.1021/jz5010957	journal	July 2014
Searching for Magnetism in Hydrogenated Graphene: Using Highly Hydrogenated Graphene Prepared via Birch Reduction of Graphite Oxides Eng, Alex Yong Sheng; Poh, Hwee Ling; Šaněk, Filip ACS Nano, Vol. 7, Issue 7 https://doi.org/10.1021/nn4016289	journal	June 2013
Interfacial Engineering Enabled Novel Bi-Based Layered Oxide Supercells with Modulated Microstructures and Tunable Physical Properties Li, Leigang; Cheng, Jianli; Wang, Hua Crystal Growth & Design, Vol. 19, Issue 12 https://doi.org/10.1021/acs.cgd.9b00938	journal	November 2019
Strain relaxation and Sn segregation in GeSn epilayers under thermal treatment Li, H.; Cui, Y. X.; Wu, K. Y. Applied Physics Letters, Vol. 102, Issue 25 https://doi.org/10.1063/1.4812490	journal	June 2013
Thickness effect on the band gap and optical properties of germanium thin films Goh, Eunice S. M.; Chen, T. P.; Sun, C. Q. Journal of Applied Physics, Vol. 107, Issue 2 https://doi.org/10.1063/1.3291103	journal	January 2010
Effect of coherency strain and misfit dislocations on the mode of growth of thin films Matthews, J. W.; Jackson, D. C.; Chambers, A. Thin Solid Films, Vol. 26, Issue 1 https://doi.org/10.1016/0040-6090(75)90172-8	journal	March 1975
Visualizing the Role of Bi 6s “Lone Pairs” in the Off-Center Distortion in Ferromagnetic BiMnO ₃ Seshadri, Ram; Hill, Nicola A. Chemistry of Materials, Vol. 13, Issue 9 https://doi.org/10.1021/cm010090m	journal	September 2001
Effect of Mechanical Boundary Conditions on Phase Diagrams of Epitaxial Ferroelectric Thin Films Pertsev, N. A.; Zembilgotov, A. G.; Tagantsev, A. K. Physical Review Letters, Vol. 80, Issue 9 https://doi.org/10.1103/PhysRevLett.80.1988	journal	March 1998
Research Updates: Epitaxial strain relaxation and associated interfacial reconstructions: The driving force for creating new structures with integrated functionality Zhu, Yuanyuan; Chen, Aiping; Zhou, Honghui APL Materials, Vol. 1, Issue 5 https://doi.org/10.1063/1.4828936	journal	November 2013
Structural, magnetic, and optical properties of ${BiFeO}_{3}$ and ${Bi}_{2} {FeMnO}_{6}$ epitaxial thin films: An experimental and first-principles study Bi, Lei; Taussig, Alexander R.; Kim, Hyun-Suk Physical Review B, Vol. 78, Issue 10 https://doi.org/10.1103/PhysRevB.78.104106	journal	September 2008
Temperature and thickness dependent permittivity of (Ba,Sr)TiO3 thin films Parker, C. B.; Maria, J. -P.; Kingon, A. I. Applied Physics Letters, Vol. 81, Issue 2 https://doi.org/10.1063/1.1490148	journal	July 2002
Self-assembled two-dimensional layered oxide supercells with modulated layer stacking and tunable physical properties Li, L.; Boullay, P.; Cheng, J. Materials Today Nano, Vol. 6 https://doi.org/10.1016/j.mtnano.2019.100037	journal	June 2019
Ultrathin nanosheets of feroxyhyte: a new two-dimensional material with robust ferromagnetic behavior Chen, Pengzuo; Xu, Kun; Li, Xiuling Chem. Sci., Vol. 5, Issue 6 https://doi.org/10.1039/C3SC53303D	journal	January 2014
Electronics and optoelectronics of two-dimensional transition metal dichalcogenides Wang, Qing Hua; Kalantar-Zadeh, Kourosh; Kis, Andras Nature Nanotechnology, Vol. 7, Issue 11, p. 699-712 https://doi.org/10.1038/nnano.2012.193	journal	November 2012
Why Are There so Few Magnetic Ferroelectrics? Hill, Nicola A. The Journal of Physical Chemistry B, Vol. 104, Issue 29 https://doi.org/10.1021/jp000114x	journal	July 2000
Photonics and optoelectronics of 2D semiconductor transition metal dichalcogenides Mak, Kin Fai; Shan, Jie Nature Photonics, Vol. 10, Issue 4 https://doi.org/10.1038/nphoton.2015.282	journal	March 2016
2D transition metal dichalcogenides Manzeli, Sajedeh; Ovchinnikov, Dmitry; Pasquier, Diego Nature Reviews Materials, Vol. 2, Issue 8 https://doi.org/10.1038/natrevmats.2017.33	journal	June 2017
Large-scale, 2D arrays of magnetic nanoparticles Rybczynski, J.; Ebels, U.; Giersig, M. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 219, Issue 1-3 https://doi.org/10.1016/S0927-7757(03)00011-6	journal	June 2003
A New Class of Room-Temperature Multiferroic Thin Films with Bismuth-Based Supercell Structure Chen, Aiping; Zhou, Honghui; Bi, Zhenxing Advanced Materials, Vol. 25, Issue 7 https://doi.org/10.1002/adma.201203051	journal	November 2012
Novel layered Bi ₃ MoM _T O ₉ (M _T = Mn, Fe, Co and Ni) thin films with tunable multifunctionalities Gao, Xingyao; Li, Leigang; Zhang, Di Nanoscale, Vol. 12, Issue 10 https://doi.org/10.1039/D0NR00083C	journal	January 2020
In Situ Growth of 2D Perovskite Capping Layer for Stable and Efficient Perovskite Solar Cells Chen, Peng; Bai, Yang; Wang, Songcan Advanced Functional Materials, Vol. 28, Issue 17 https://doi.org/10.1002/adfm.201706923	journal	February 2018
Superconductivity at 93 K in a new mixed-phase Y-Ba-Cu-O compound system at ambient pressure Wu, M. K.; Ashburn, J. R.; Torng, C. J. Physical Review Letters, Vol. 58, Issue 9 https://doi.org/10.1103/PhysRevLett.58.908	journal	March 1987
Dielectric and piezoelectric properties of barium-modified Aurivillius-type Na0.5Bi4.5Ti4O15 Du, Huiling; Shi, Xiang Journal of Physics and Chemistry of Solids, Vol. 72, Issue 11 https://doi.org/10.1016/j.jpcs.2011.07.023	journal	November 2011
Epitaxial growth of ferromagnetic ultrathin MnGa films with perpendicular magnetization on GaAs Tanaka, M.; Harbison, J. P.; DeBoeck, J. Applied Physics Letters, Vol. 62, Issue 13 https://doi.org/10.1063/1.108642	journal	March 1993
2D Ruddlesden-Popper Perovskites for Optoelectronics Chen, Yani; Sun, Yong; Peng, Jiajun Advanced Materials, Vol. 30, Issue 2 https://doi.org/10.1002/adma.201703487	journal	October 2017
Strong room temperature magnetism in highly resistive strained thin films of BiFe0.5Mn0.5O3 Choi, E. -M.; Patnaik, S.; Weal, E. Applied Physics Letters, Vol. 98, Issue 1 https://doi.org/10.1063/1.3540683	journal	January 2011
Quantum spin Hall effect in two-dimensional transition metal dichalcogenides Qian, X.; Liu, J.; Fu, L. Science, Vol. 346, Issue 6215 https://doi.org/10.1126/science.1256815	journal	November 2014
Ultrathin 2D Metal-Organic Framework Nanosheets Zhao, Meiting; Wang, Yixian; Ma, Qinglang Advanced Materials, Vol. 27, Issue 45 https://doi.org/10.1002/adma.201503648	journal	October 2015
Magnetism of Phthalocyanine-Based Organometallic Single Porous Sheet Zhou, Jian; Sun, Qiang Journal of the American Chemical Society, Vol. 133, Issue 38 https://doi.org/10.1021/ja204990j	journal	September 2011
The rise of graphene Geim, A. K.; Novoselov, K. S. Nature Materials, Vol. 6, Issue 3, p. 183-191 https://doi.org/10.1038/nmat1849	journal	March 2007
Temperature- and roughness-dependent permittivity of annealed/unannealed gold films Shen, Po-Ting; Sivan, Yonatan; Lin, Cheng-Wei Optics Express, Vol. 24, Issue 17 https://doi.org/10.1364/OE.24.019254	journal	January 2016
Graphene spintronics: the European Flagship perspective Roche, Stephan; Åkerman, Johan; Beschoten, Bernd 2D Materials, Vol. 2, Issue 3 https://doi.org/10.1088/2053-1583/2/3/030202	journal	July 2015
Perovskites by Design: A Toolbox of Solid-State Reactions Schaak, Raymond E.; Mallouk, Thomas E. Chemistry of Materials, Vol. 14, Issue 4, p. 1455-1471 https://doi.org/10.1021/cm010689m	journal	April 2002
Strain and Interface Effects in a Novel Bismuth-Based Self-Assembled Supercell Structure Li, Leigang; Zhang, Wenrui; Khatkhatay, Fauzia ACS Applied Materials & Interfaces, Vol. 7, Issue 21 https://doi.org/10.1021/acsami.5b02699	journal	May 2015
Magnetic 2D materials and heterostructures Gibertini, M.; Koperski, M.; Morpurgo, A. F. Nature Nanotechnology, Vol. 14, Issue 5 https://doi.org/10.1038/s41565-019-0438-6	journal	May 2019
Two-Dimensional Layered Oxide Structures Tailored by Self-Assembled Layer Stacking via Interfacial Strain Zhang, Wenrui; Li, Mingtao; Chen, Aiping ACS Applied Materials & Interfaces, Vol. 8, Issue 26 https://doi.org/10.1021/acsami.6b03773	journal	June 2016
Effects of thickness on the cation segregation in epitaxial (001) and (110) La2/3Ca1/3MnO3 thin films Estradé, S.; Rebled, J. M.; Arbiol, J. Applied Physics Letters, Vol. 95, Issue 7 https://doi.org/10.1063/1.3211130	journal	August 2009
Recent Developments in Oxide Ion Conductors: Aurivillius Phases Kendall, Kurt R.; Navas, Carlos; Thomas, Julie K. Chemistry of Materials, Vol. 8, Issue 3 https://doi.org/10.1021/cm9503083	journal	January 1996
Ferromagnetism in Semihydrogenated Graphene Sheet Zhou, J.; Wang, Q.; Sun, Q. Nano Letters, Vol. 9, Issue 11 https://doi.org/10.1021/nl9020733	journal	November 2009

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77 NANOSCIENCE AND NANOTECHNOLOGY
ultrathin layered oxide
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anisotropy
multiferroics

Title: Tailorable multifunctionalities in ultrathin 2D Bi-based layered supercell structures

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